DIXENITE Mineral Details

Complete mineralogical data for DIXENITE. Chemical Formula: Cu1+Mn2+14Fe3+(As3+O3)5(As5+O4)[SiO4]2(OH)6. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

DIXENITE

Cu1+Mn2+14Fe3+(As3+O3)5(As5+O4)[SiO4]2(OH)6

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal pyramidal

Space Group

R3

Point Group

3

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations, (OH, etc.):RO4 > 2:1; similar structure to hematolite.1 28 atoms occur in asymmetric unit incl 2 disordered Cu1+ cations; structure is related to but distinct from that of hematolite; 3 kinds of anionic radical occur: (As3+O3) trig ∆; & (SiO4) & (As5+O4) tetrahedra; 3 of 5 nonequivalent layers along [001] are similar in hematolite & dixenite; 1 layer in dixenite contains disordered cluster, idealized as (Cu1+As3+4) where tetrahedron of As3+ ions surround Cu1+ ion; all lone pair electrons from As3+ point into central cavity which houses Cu1+ (d10) & this cluster is believed to be stabilized by 18-electron rule where Cu1+As3+4 forms closed argon core.2 Structure consists of layers of (Mn2+,Fe3+)(O,OH)6 octahedra; there are 5 distinct layers in repeat unit of cell, 4 of which are very similar to layers in mcgovernite; unusual aspect of 1 of trimers of octahedra is that there is triangular-prismatic hole thru center of cluster; (Cu+As3+4) tetrahedra are parts of larger clusters: [Cu+(As3+O3)4] in which 4 (As3+O) grp link to central Cu+ that occupies positions normally taken by steroactive lone-pairs of electrons that gen typify As3+ in triangular-∆ coordination by O; thus, stereoative lone-pair behavior that is feature of (As3+O3) trig ∆ is suppressed by coordination of Cu+ by 4 As3+ ions.3

Cell Data

a=8.23Å, c=37.50Å, Z=3

Geology & Identification

Geologic Occurrence

Vein filling in massive zinc ore in a metamorphosed stratiform Zn-Mn depositDIXENITEDIXENITE

Habit

Coarse cleavable, granular, massive

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across DIXENITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about DIXENITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, DIXENITE is defined by the chemical formula Cu1+Mn2+14Fe3+(As3+O3)5(As5+O4)[SiO4]2(OH)6.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. DIXENITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal pyramidal.
  • Point Group: 3
  • Space Group: R3
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For DIXENITE, the dimensions of this microscopic building block are:
a=8.23Å, c=37.50Å, Z=3
The internal arrangement of these atoms is described as:
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Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations, (OH, etc.):RO4 > 2:1; similar structure to hematolite.1 28 atoms occur in asymmetric unit incl 2 disordered Cu1+ cations; structure is related to but distinct from that of hematolite; 3 kinds of anionic radical occur: (As3+O3) trig ∆; & (SiO4) & (As5+O4) tetrahedra; 3 of 5 nonequivalent layers along [001] are similar in hematolite & dixenite; 1 layer in dixenite contains disordered cluster, idealized as (Cu1+As3+4) where tetrahedron of As3+ ions surround Cu1+ ion; all lone pair electrons from As3+ point into central cavity which houses Cu1+ (d10) & this cluster is believed to be stabilized by 18-electron rule where Cu1+As3+4 forms closed argon core.2 Structure consists of layers of (Mn2+,Fe3+)(O,OH)6 octahedra; there are 5 distinct layers in repeat unit of cell, 4 of which are very similar to layers in mcgovernite; unusual aspect of 1 of trimers of octahedra is that there is triangular-prismatic hole thru center of cluster; (Cu+As3+4) tetrahedra are parts of larger clusters: [Cu+(As3+O3)4] in which 4 (As3+O) grp link to central Cu+ that occupies positions normally taken by steroactive lone-pairs of electrons that gen typify As3+ in triangular-∆ coordination by O; thus, stereoative lone-pair behavior that is feature of (As3+O3) trig ∆ is suppressed by coordination of Cu+ by 4 As3+ ions.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find DIXENITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Coarse cleavable, granular, massive
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If DIXENITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Vein filling in massive zinc ore in a metamorphosed stratiform Zn-Mn depositKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. DIXENITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of DIXENITE?The standard chemical formula for DIXENITE is Cu1+Mn2+14Fe3+(As3+O3)5(As5+O4)[SiO4]2(OH)6. This defines its elemental composition.
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2. Which crystal system does DIXENITE belong to?DIXENITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal pyramidal class.3. How is DIXENITE typically found in nature?The “habit” or typical appearance of DIXENITE is described as Coarse cleavable, granular, massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does DIXENITE form?DIXENITE is typically found in environments described as: Vein filling in massive zinc ore in a metamorphosed stratiform Zn-Mn deposit. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to DIXENITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of DIXENITE, we recommend checking high-authority databases:

Final Thoughts

DIXENITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Cu1+Mn2+14Fe3+(As3+O3)5(As5+O4)[SiO4]2(OH)6 and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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