THOMSONITE-Ca Mineral Details

Complete mineralogical data for THOMSONITE-Ca. Chemical Formula: NaCa2[Si5Al5O20]·6H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

THOMSONITE-Ca

NaCa2[Si5Al5O20]·6H2O

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pbmn

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of 4-membered rings, Al2Si2O10, connected by 5th Si; corner-sharing tetrahedra form chains // [001] spirally linked by extra SiO4 tetrahedra to form 3-D framework of 4- & 8-membered rings with large channels that lodge Na & H2O.2 Al-Si framework consists of □-ring chains along c axis, which are linked via outer tetrahedra of rings to other chains; along chains run channels containing cations & H2O molecules.3 Structure was 1st determined by Taylor et al (1933), & solved in s.g. Pbmn; doubling of c (Alberti et al (1981), Ståhl et al (1990)) is result (Si,Al) ordering in T5O10 chains, which are || to c-axis (THO); Gottardi & Galli (1985) & Tschernich (1992) gave Pcnn as s.g. setting; Pcnn & Pncn diff by choice of a- & b-axes; for Pcnn, ab; framework of thomsonite-Ca consists of Al5Si5O20 chains, that if ordered, have repeat distance of 13.2 Å.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; thomsonite has chains with repeat unit of 5 tetrahedra which occur as in NAT structure type, but they are cross-linked in diff way; Si,Al are highly ordered, but disorder increases with increasing Si:Al.6 Si/Al-distribution in tetrahedral framework is fully “disordered” giving rise to halving of c axis relative to that found in “ordered” thomsonites; extra-framework population consists of: (1) site about 50% occupied by Ca; (2) site occupied by Na (~70%) & Ca(~30%); (3) 3 H2O molecule sites; refinements allowed loc of all proton sites & H-bonding scheme in structure provided.7 See “Additional Structures” tab for entry(s).5,8a,8b,9,10a,10b

Cell Data

a=13.07Å, b=13.09Å, c=6.61Å, Z=2

Geology & Identification

Geologic Occurrence

In cavities in amygdaloidal basalts, related igneous rocks, late forming; in granite, gneiss, syeniteTHOMSONITE-CaTHOMSONITE-Ca

Habit

Short to long prismatic macro crystals, striated; in stellate, interlacing groups; radiating fibrous, granular

Twinning

On {110}, {011}, {031}

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family, thomsonite subgroup; Ca – dominant analog of thomsenite-Sr

If you are fascinated by the hidden structures of our planet, you have likely come across THOMSONITE-Ca. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about THOMSONITE-Ca. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, THOMSONITE-Ca is defined by the chemical formula NaCa2[Si5Al5O20]·6H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. THOMSONITE-Ca crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pbmn
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For THOMSONITE-Ca, the dimensions of this microscopic building block are:
a=13.07Å, b=13.09Å, c=6.61Å, Z=2
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of 4-membered rings, Al2Si2O10, connected by 5th Si; corner-sharing tetrahedra form chains // [001] spirally linked by extra SiO4 tetrahedra to form 3-D framework of 4- & 8-membered rings with large channels that lodge Na & H2O.2 Al-Si framework consists of □-ring chains along c axis, which are linked via outer tetrahedra of rings to other chains; along chains run channels containing cations & H2O molecules.3 Structure was 1st determined by Taylor et al (1933), & solved in s.g. Pbmn; doubling of c (Alberti et al (1981), Ståhl et al (1990)) is result (Si,Al) ordering in T5O10 chains, which are || to c-axis (THO); Gottardi & Galli (1985) & Tschernich (1992) gave Pcnn as s.g. setting; Pcnn & Pncn diff by choice of a- & b-axes; for Pcnn, ab; framework of thomsonite-Ca consists of Al5Si5O20 chains, that if ordered, have repeat distance of 13.2 Å.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; thomsonite has chains with repeat unit of 5 tetrahedra which occur as in NAT structure type, but they are cross-linked in diff way; Si,Al are highly ordered, but disorder increases with increasing Si:Al.6 Si/Al-distribution in tetrahedral framework is fully “disordered” giving rise to halving of c axis relative to that found in “ordered” thomsonites; extra-framework population consists of: (1) site about 50% occupied by Ca; (2) site occupied by Na (~70%) & Ca(~30%); (3) 3 H2O molecule sites; refinements allowed loc of all proton sites & H-bonding scheme in structure provided.7 See “Additional Structures” tab for entry(s).5,8a,8b,9,10a,10bThis internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find THOMSONITE-Ca in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short to long prismatic macro crystals, striated; in stellate, interlacing groups; radiating fibrous, granular
  • Twinning: On {110}, {011}, {031}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If THOMSONITE-Ca exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In cavities in amygdaloidal basalts, related igneous rocks, late forming; in granite, gneiss, syeniteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. THOMSONITE-Ca is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family, thomsonite subgroup; Ca – dominant analog of thomsenite-SrUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of THOMSONITE-Ca?The standard chemical formula for THOMSONITE-Ca is NaCa2[Si5Al5O20]·6H2O. This defines its elemental composition.2. Which crystal system does THOMSONITE-Ca belong to?THOMSONITE-Ca crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is THOMSONITE-Ca typically found in nature?The “habit” or typical appearance of THOMSONITE-Ca is described as Short to long prismatic macro crystals, striated; in stellate, interlacing groups; radiating fibrous, granular. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does THOMSONITE-Ca form?THOMSONITE-Ca is typically found in environments described as: In cavities in amygdaloidal basalts, related igneous rocks, late forming; in granite, gneiss, syenite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to THOMSONITE-Ca?Yes, it is often associated with or related to other minerals such as: Zeolite family, thomsonite subgroup; Ca – dominant analog of thomsenite-Sr.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of THOMSONITE-Ca, we recommend checking high-authority databases:

Final Thoughts

THOMSONITE-Ca is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of NaCa2[Si5Al5O20]·6H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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