ADAMITE Mineral Details

Complete mineralogical data for ADAMITE. Chemical Formula: Zn2(AsO4)(OH). Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

ADAMITE

Zn2(AsO4)(OH)

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pnnm

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations; chains // [001] of edge-sharing MO4 (OH)2 octahedra flanked by RO4 tetrahedra that cross-link adjacent chains to form open framework; channels in framework contain dimers of edge-sharing MO3O(OH) trig di-∆ that share corners with octahedra & tetrahedra of framework; andalusite structure type.2 Isostructural with andalusite, which is homostructural with olivenite; Cu & Zn have CN of 5 & 6.3 Edge-sharing chains of ZnO4(OH)2 octahedra extend || to c-axis, & are linked by As tetrahedra to form channels || to c; pairs of edge-sharing ZnO4OH trig di-∆ occur in these channels; structure is similar to that of andalusite; both bond-strength considerations & infrared spectrum indicate presence of weak H—bonding.4 Isotypy with andalusite & members of olivenite grp of minerals is confirmed, Zn atoms occuring in both [6]- & [5]- coordination; ZnO4 (OH)2 octahedra share edges to produce chans || to c axis, & share corners with edge-sharing ZnO4(OH) trig bi-∆ in a- & b-axis directions; AsO4 grp connect 2 Zn polyhedron types to produce dense framework structure in which all O atoms & OH grp are trig coordinated.5

Cell Data

a=8.30Å, b=8.51Å, c=6.04Å, Z=4

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zone of Cu-depositsADAMITEADAMITE

Habit

As wedge-topped prismatic macro crystals, elongated or equant, striated; sprays bladed to acicular, druses

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Olivenite group, forms series with olivenite; andalusite type structure; dimorphous with paradamite

If you are fascinated by the hidden structures of our planet, you have likely come across ADAMITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about ADAMITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, ADAMITE is defined by the chemical formula Zn2(AsO4)(OH).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. ADAMITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pnnm
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For ADAMITE, the dimensions of this microscopic building block are:
a=8.30Å, b=8.51Å, c=6.04Å, Z=4
The internal arrangement of these atoms is described as:
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Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions w/o H2O with medium-sized cations; chains // [001] of edge-sharing MO4 (OH)2 octahedra flanked by RO4 tetrahedra that cross-link adjacent chains to form open framework; channels in framework contain dimers of edge-sharing MO3O(OH) trig di-∆ that share corners with octahedra & tetrahedra of framework; andalusite structure type.2 Isostructural with andalusite, which is homostructural with olivenite; Cu & Zn have CN of 5 & 6.3 Edge-sharing chains of ZnO4(OH)2 octahedra extend || to c-axis, & are linked by As tetrahedra to form channels || to c; pairs of edge-sharing ZnO4OH trig di-∆ occur in these channels; structure is similar to that of andalusite; both bond-strength considerations & infrared spectrum indicate presence of weak H—bonding.4 Isotypy with andalusite & members of olivenite grp of minerals is confirmed, Zn atoms occuring in both [6]- & [5]- coordination; ZnO4 (OH)2 octahedra share edges to produce chans || to c axis, & share corners with edge-sharing ZnO4(OH) trig bi-∆ in a- & b-axis directions; AsO4 grp connect 2 Zn polyhedron types to produce dense framework structure in which all O atoms & OH grp are trig coordinated.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find ADAMITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As wedge-topped prismatic macro crystals, elongated or equant, striated; sprays bladed to acicular, druses
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If ADAMITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zone of Cu-depositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. ADAMITE is often related to other species, either through similar chemistry or structure.Relationship Data: Olivenite group, forms series with olivenite; andalusite type structure; dimorphous with paradamiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of ADAMITE?The standard chemical formula for ADAMITE is Zn2(AsO4)(OH). This defines its elemental composition.
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2. Which crystal system does ADAMITE belong to?ADAMITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is ADAMITE typically found in nature?The “habit” or typical appearance of ADAMITE is described as As wedge-topped prismatic macro crystals, elongated or equant, striated; sprays bladed to acicular, druses. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does ADAMITE form?ADAMITE is typically found in environments described as: Secondary mineral in oxidized zone of Cu-deposits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to ADAMITE?Yes, it is often associated with or related to other minerals such as: Olivenite group, forms series with olivenite; andalusite type structure; dimorphous with paradamite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of ADAMITE, we recommend checking high-authority databases:

Final Thoughts

ADAMITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Zn2(AsO4)(OH) and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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