AIKINITE Mineral Details

Complete mineralogical data for AIKINITE. Chemical Formula: PbCuBiS3. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

AIKINITE

PbCuBiS3

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pnma

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb or Bi represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb or Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; SnS archetype, deformed (As,Sb,Bi)S6 octahedra with distinct (As,Sb,Bi)S3 ∆; (501) or (501) slices of SnS-like structure; slice surfaces form wavy composition planes; 2 adjacent slices face each other, mutually related by n-glide plane // to (010), tetrahedral coordination sites in wavy interfaces can be occupied by Cu atoms Cu+Pb vacancy + Bi.3 Structure of aikinite is very similar to that of stibnite, Sb sites in latter being filled alternately by Pb & Bi; Cu atoms lie in holes with tetrahedral coordinations, which balances replcmnt of 1 Sb atom by Pb, main peculiarity of aikinite structure is infinite chains of Cu tetrahedra & Bi ∆ (CuBiS3) along c axis; they are bound by Pb atoms which form distorted trig prisms with S atoms; CN of Pb & Bi atoms is 7.4 Asymmetric unit of structure contains Pb, Cu, Bi and 3S; Pb atom is coordinated by 5 S atoms at distances ranging from 2.84 to 2.98 Å in loc close to octahedral environment; 2 add’l S neighbors are loc at 3.24 Å; Bi atom has 3 S neighbors at 2.66 & 2.73 Å, 3 more distant S atoms at 2.97 to 3.12 Å; & 7th S neighbor at 3.53 Å; Cu atom has distorted tetrahedral coordination, & all 3 types of S atoms have octahedral coordination.5

Cell Data

a=11.608Å, b=4.028Å, c=11.275Å, Z=4

Geology & Identification

Geologic Occurrence

In hydrothermal veins and contact metasomatic depositsAIKINITEAIKINITE

Habit

Crystals are slender prismatic and striated; also massive, fibrous to compact

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Aikinite group

If you are fascinated by the hidden structures of our planet, you have likely come across AIKINITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about AIKINITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, AIKINITE is defined by the chemical formula PbCuBiS3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. AIKINITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pnma
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For AIKINITE, the dimensions of this microscopic building block are:
a=11.608Å, b=4.028Å, c=11.275Å, Z=4
The internal arrangement of these atoms is described as:
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Typified by presence of trig ∆ of As, Sb or Bi represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb or Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; SnS archetype, deformed (As,Sb,Bi)S6 octahedra with distinct (As,Sb,Bi)S3 ∆; (501) or (501) slices of SnS-like structure; slice surfaces form wavy composition planes; 2 adjacent slices face each other, mutually related by n-glide plane // to (010), tetrahedral coordination sites in wavy interfaces can be occupied by Cu atoms Cu+Pb <=> vacancy + Bi.3 Structure of aikinite is very similar to that of stibnite, Sb sites in latter being filled alternately by Pb & Bi; Cu atoms lie in holes with tetrahedral coordinations, which balances replcmnt of 1 Sb atom by Pb, main peculiarity of aikinite structure is infinite chains of Cu tetrahedra & Bi ∆ (CuBiS3) along c axis; they are bound by Pb atoms which form distorted trig prisms with S atoms; CN of Pb & Bi atoms is 7.4 Asymmetric unit of structure contains Pb, Cu, Bi and 3S; Pb atom is coordinated by 5 S atoms at distances ranging from 2.84 to 2.98 Å in loc close to octahedral environment; 2 add’l S neighbors are loc at 3.24 Å; Bi atom has 3 S neighbors at 2.66 & 2.73 Å, 3 more distant S atoms at 2.97 to 3.12 Å; & 7th S neighbor at 3.53 Å; Cu atom has distorted tetrahedral coordination, & all 3 types of S atoms have octahedral coordination.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find AIKINITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals are slender prismatic and striated; also massive, fibrous to compact
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If AIKINITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In hydrothermal veins and contact metasomatic depositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. AIKINITE is often related to other species, either through similar chemistry or structure.Relationship Data: Aikinite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of AIKINITE?The standard chemical formula for AIKINITE is PbCuBiS3. This defines its elemental composition.2. Which crystal system does AIKINITE belong to?AIKINITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is AIKINITE typically found in nature?The “habit” or typical appearance of AIKINITE is described as Crystals are slender prismatic and striated; also massive, fibrous to compact. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does AIKINITE form?AIKINITE is typically found in environments described as: In hydrothermal veins and contact metasomatic deposits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to AIKINITE?Yes, it is often associated with or related to other minerals such as: Aikinite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of AIKINITE, we recommend checking high-authority databases:

Final Thoughts

AIKINITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbCuBiS3 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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