AMICITE Mineral Details

Complete mineralogical data for AMICITE. Chemical Formula: K4Na4[Si8Al8O32]·5H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

AMICITE

K4Na4[Si8Al8O32]·5H2O

Crystal System

Monoclinic

Crystal Class

Sphenoidal

Space Group

I2

Point Group

2

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of doubly-connected 4-membered rings into crankshaft-type chains with channels // [010] & [001]; M(H2O)4 polyhedra loc in cages of 8-membered rings at channel intersections.2 Amicite framework topology consists of 2 sets of interesting, doubly connected 4-membered rings linked into double crankshaft chains; these sets of double crankshaft chains that run || to a-axis & to b-axis are related by 41 axis forming GIS framework; where there is (Si,Al) disorder in tetrahedra, topological symmetry is I41/amd; in amicite ordering of framework & restrictions caused by distribution of channel cations & H2O molecules lower symmetry to I2; thru this framework, channels confined by 8-membered rings; Na & K are well ordered in 2 completely occupied sites; Na is [6]-coordinated by 3 O atoms & 3 H2O molecules; in amicite, 2 of gismondine Ca sites are occupied by Na with 2 add’l Na sites; K sites in amicite are occupied in gismondine by H2O; 3 filled H2O sites are bonded to channel cations; 1 add’l H2O site is only ½ occupied & with long distance to Na; amcite can be completely dehydrated w/o destruction of framework (Vezzalini et al 1999).3 Topology of its framework is same as that of garronite, gismondine, synthetic zeolite P & structure can be described as formed by 2 untwisted double-crankshaft chains developed in 2 prp directions; Si/Al & Na/K distributions are ordered & consequently symmetry is lowered from topological symmetry of I41/amd to real symmetry I2.4 Zeolites are aluminosilicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; amicite molecules of H2O occupy extra-framework positions; same framework topology as gismodine; Si, Al & Na, K distributions are ordered.5

Cell Data

a=10.23Å, b=10.42Å, c=9.88Å, ß=88.3o, Z=1

Geology & Identification

Geologic Occurrence

In cavities in nepheline and olivine basalt and leucite tephriteAMICITEAMICITE

Habit

Bipyramidal macro crystals; in stellate or radiating spherulitic aggregates; powdery

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family

If you are fascinated by the hidden structures of our planet, you have likely come across AMICITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about AMICITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, AMICITE is defined by the chemical formula K4Na4[Si8Al8O32]·5H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. AMICITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Sphenoidal.
  • Point Group: 2
  • Space Group: I2
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For AMICITE, the dimensions of this microscopic building block are:
a=10.23Å, b=10.42Å, c=9.88Å, ß=88.3o, Z=1
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of doubly-connected 4-membered rings into crankshaft-type chains with channels // [010] & [001]; M(H2O)4 polyhedra loc in cages of 8-membered rings at channel intersections.2 Amicite framework topology consists of 2 sets of interesting, doubly connected 4-membered rings linked into double crankshaft chains; these sets of double crankshaft chains that run || to a-axis & to b-axis are related by 41 axis forming GIS framework; where there is (Si,Al) disorder in tetrahedra, topological symmetry is I41/amd; in amicite ordering of framework & restrictions caused by distribution of channel cations & H2O molecules lower symmetry to I2; thru this framework, channels confined by 8-membered rings; Na & K are well ordered in 2 completely occupied sites; Na is [6]-coordinated by 3 O atoms & 3 H2O molecules; in amicite, 2 of gismondine Ca sites are occupied by Na with 2 add’l Na sites; K sites in amicite are occupied in gismondine by H2O; 3 filled H2O sites are bonded to channel cations; 1 add’l H2O site is only ½ occupied & with long distance to Na; amcite can be completely dehydrated w/o destruction of framework (Vezzalini et al 1999).3 Topology of its framework is same as that of garronite, gismondine, synthetic zeolite P & structure can be described as formed by 2 untwisted double-crankshaft chains developed in 2 prp directions; Si/Al & Na/K distributions are ordered & consequently symmetry is lowered from topological symmetry of I41/amd to real symmetry I2.4 Zeolites are aluminosilicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; amicite molecules of H2O occupy extra-framework positions; same framework topology as gismodine; Si, Al & Na, K distributions are ordered.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find AMICITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Bipyramidal macro crystals; in stellate or radiating spherulitic aggregates; powdery
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If AMICITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In cavities in nepheline and olivine basalt and leucite tephriteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. AMICITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite familyUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of AMICITE?The standard chemical formula for AMICITE is K4Na4[Si8Al8O32]·5H2O. This defines its elemental composition.2. Which crystal system does AMICITE belong to?AMICITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Sphenoidal class.3. How is AMICITE typically found in nature?The “habit” or typical appearance of AMICITE is described as Bipyramidal macro crystals; in stellate or radiating spherulitic aggregates; powdery. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does AMICITE form?AMICITE is typically found in environments described as: In cavities in nepheline and olivine basalt and leucite tephrite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to AMICITE?Yes, it is often associated with or related to other minerals such as: Zeolite family.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of AMICITE, we recommend checking high-authority databases:

Final Thoughts

AMICITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of K4Na4[Si8Al8O32]·5H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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