ASISITE Mineral Details

Complete mineralogical data for ASISITE. Chemical Formula: Pb7Cl2O4[SiO4]. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

ASISITE

Pb7Cl2O4[SiO4]

Crystal System

Tetragonal

Crystal Class

Ditetragonal dipyramidal

Space Group

I4/mmm

Point Group

4/m 2/m 2/m

Structure & Data

Crystal Structure

Halides are ionically bonded compounds of cations Na1+, Ca2+, etc. & halogen anions F1-, Cl1-, Br1-, I1-; oxy-halides, hydroxyhalides & related double halides with Pb, Cu, etc.; sheet structures consisting of 2 types of layers // (001); layer, PbO4Cl4 antiprisms share edges with PbO4 ∆; in 2nd layer shares faces along (001) mirror planes, similar antiprisms, Si positions unknown; stereochemistry of Pb2+ is commonly influenced by lone-electron-pair effect, where-by electron pair on ion effectively prevents bonding in that direction, with result that near neighbors of Pb2+ are all on 1 side of ion.1 Consists of layers of tetragonal PbO structure alternating with single sheets of Cl- ions, all arranged in layers normal to c; Si could not be loc experimentally, & its structural role is uncertain; asisite is naturally occuring member of large family of nonstoichiometric Pb-transition element & post-transition element oxyhalides.2 Structure of tetragonal sub-cell has been redetermined here: R=5.6% for 178 unique Fo>4δFo & anisotropic model; significantly reduced 72% occupancy of Pb(2) site was found that implies normal formula Pb7SiO8Cl2, thus confirming previous findings; comparisons with kombatite & symesite support asgmt of Si to Pb(2) & imply that Si in asisite is also likely to be in tetrahedral coordination, with apical O cross-linking PbO sheets; because most of key info relating to loc of Si is provided by super-lattice reflections, inability of X-ray diffraction to register these reflections introduces significant ambiguity into interpretation of Pb/Si ordering behaviour in this mineral.3

Cell Data

a=3.89Å, c=22.80Å, Z=8

Geology & Identification

Geologic Occurrence

In manganese silicate lenses nearby a sulfide ore bodyASISITEASISITE

Habit

Platy, micro

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across ASISITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about ASISITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, ASISITE is defined by the chemical formula Pb7Cl2O4[SiO4].This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. ASISITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Ditetragonal dipyramidal.
  • Point Group: 4/m 2/m 2/m
  • Space Group: I4/mmm
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For ASISITE, the dimensions of this microscopic building block are:
a=3.89Å, c=22.80Å, Z=8
The internal arrangement of these atoms is described as:
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Halides are ionically bonded compounds of cations Na1+, Ca2+, etc. & halogen anions F1-, Cl1-, Br1-, I1-; oxy-halides, hydroxyhalides & related double halides with Pb, Cu, etc.; sheet structures consisting of 2 types of layers // (001); layer, PbO4Cl4 antiprisms share edges with PbO4 ∆; in 2nd layer shares faces along (001) mirror planes, similar antiprisms, Si positions unknown; stereochemistry of Pb2+ is commonly influenced by lone-electron-pair effect, where-by electron pair on ion effectively prevents bonding in that direction, with result that near neighbors of Pb2+ are all on 1 side of ion.1 Consists of layers of tetragonal PbO structure alternating with single sheets of Cl- ions, all arranged in layers normal to c; Si could not be loc experimentally, & its structural role is uncertain; asisite is naturally occuring member of large family of nonstoichiometric Pb-transition element & post-transition element oxyhalides.2 Structure of tetragonal sub-cell has been redetermined here: R=5.6% for 178 unique Fo>4δFo & anisotropic model; significantly reduced 72% occupancy of Pb(2) site was found that implies normal formula Pb7SiO8Cl2, thus confirming previous findings; comparisons with kombatite & symesite support asgmt of Si to Pb(2) & imply that Si in asisite is also likely to be in tetrahedral coordination, with apical O cross-linking PbO sheets; because most of key info relating to loc of Si is provided by super-lattice reflections, inability of X-ray diffraction to register these reflections introduces significant ambiguity into interpretation of Pb/Si ordering behaviour in this mineral.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find ASISITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Platy, micro
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If ASISITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In manganese silicate lenses nearby a sulfide ore bodyKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. ASISITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of ASISITE?The standard chemical formula for ASISITE is Pb7Cl2O4[SiO4]. This defines its elemental composition.
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2. Which crystal system does ASISITE belong to?ASISITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Ditetragonal dipyramidal class.3. How is ASISITE typically found in nature?The “habit” or typical appearance of ASISITE is described as Platy, micro. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does ASISITE form?ASISITE is typically found in environments described as: In manganese silicate lenses nearby a sulfide ore body. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to ASISITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of ASISITE, we recommend checking high-authority databases:

Final Thoughts

ASISITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb7Cl2O4[SiO4] and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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