BARIOPHARMACOALUMITE Mineral Details

Complete mineralogical data for BARIOPHARMACOALUMITE. Chemical Formula: Ba0.5Al4(AsO4)3(OH)4·4H2O. Crystal System: Isometric. Learn about its geologic occurrence, habit, and identification.

BARIOPHARMACOALUMITE

Ba0.5Al4(AsO4)3(OH)4·4H2O

Crystal System

Isometric

Crystal Class

Cubic hextetrahedral

Space Group

P43m

Point Group

4 3 m

Structure & Data

Crystal Structure

1 Framework of grp of 4 FeO3(OH)3 octahedra (centers of grp at vertices of cubic cell), are linked to AsO4 tetrahedra at centers of edges of cell; octahedra share edges with each other, & vertices with tetrahedra; large holes contain zeolitic H2O & K ions, which are easily repl by oxonium, thus continuous K—H3O isomorphism bariumaluminumpharmacosiderite).2 Bariopharmaco-alumite – Q2a2b2c, I-centered tetragonal superstructure of basic pharmacosiderite-type structure; cell parameters are a = 15.405(2) Å & c = 15.553(3) Å; origin of superlattice cell doubling was determined to be due predominantly to ordering of Ba atoms in ½ of [0 0 1] channels, centered at (0,0,0) & (½,½,0); other channels, centered at (½,0,0) & (0,½,0) were found to be occupied by corner-connected chains of Cu/Zn-centered □ planar units.3

Cell Data

a=7.742Å, Z=1

Geology & Identification

Geologic Occurrence

Secondary mineral of As-bearing sulfidesBARIOPHARMACOALUMITEBARIOPHARMACOALUMITE

Habit

As interpenetrating micro cubes

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Pharmacosiderite supergroup, pharmacoalumite group

If you are fascinated by the hidden structures of our planet, you have likely come across BARIOPHARMACOALUMITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BARIOPHARMACOALUMITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BARIOPHARMACOALUMITE is defined by the chemical formula Ba0.5Al4(AsO4)3(OH)4·4H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BARIOPHARMACOALUMITE crystallizes in the Isometric system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Cubic hextetrahedral.
  • Point Group: 4 3 m
  • Space Group: P43m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BARIOPHARMACOALUMITE, the dimensions of this microscopic building block are:
a=7.742Å, Z=1
The internal arrangement of these atoms is described as:1 Framework of grp of 4 FeO3(OH)3 octahedra (centers of grp at vertices of cubic cell), are linked to AsO4 tetrahedra at centers of edges of cell; octahedra share edges with each other, & vertices with tetrahedra; large holes contain zeolitic H2O & K ions, which are easily repl by oxonium, thus continuous K—H3O isomorphism bariumaluminumpharmacosiderite).2 Bariopharmaco-alumite – Q2a2b2c, I-centered tetragonal superstructure of basic pharmacosiderite-type structure; cell parameters are a = 15.405(2) Å & c = 15.553(3) Å; origin of superlattice cell doubling was determined to be due predominantly to ordering of Ba atoms in ½ of [0 0 1] channels, centered at (0,0,0) & (½,½,0); other channels, centered at (½,0,0) & (0,½,0) were found to be occupied by corner-connected chains of Cu/Zn-centered □ planar units.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find BARIOPHARMACOALUMITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As interpenetrating micro cubes
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BARIOPHARMACOALUMITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral of As-bearing sulfidesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BARIOPHARMACOALUMITE is often related to other species, either through similar chemistry or structure.Relationship Data: Pharmacosiderite supergroup, pharmacoalumite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of BARIOPHARMACOALUMITE?The standard chemical formula for BARIOPHARMACOALUMITE is Ba0.5Al4(AsO4)3(OH)4·4H2O. This defines its elemental composition.2. Which crystal system does BARIOPHARMACOALUMITE belong to?BARIOPHARMACOALUMITE crystallizes in the Isometric system. Its internal symmetry is further classified under the Cubic hextetrahedral class.
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3. How is BARIOPHARMACOALUMITE typically found in nature?The “habit” or typical appearance of BARIOPHARMACOALUMITE is described as As interpenetrating micro cubes. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BARIOPHARMACOALUMITE form?BARIOPHARMACOALUMITE is typically found in environments described as: Secondary mineral of As-bearing sulfides. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BARIOPHARMACOALUMITE?Yes, it is often associated with or related to other minerals such as: Pharmacosiderite supergroup, pharmacoalumite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BARIOPHARMACOALUMITE, we recommend checking high-authority databases:

Final Thoughts

BARIOPHARMACOALUMITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ba0.5Al4(AsO4)3(OH)4·4H2O and a structure defined by the Isometric system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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