BARTONITE Mineral Details

Complete mineralogical data for BARTONITE. Chemical Formula: K6Fe20S26S. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

BARTONITE

K6Fe20S26S

Crystal System

Tetragonal

Crystal Class

Ditetragonal dipyramidal

Space Group

I4/mmm

Point Group

4/m 2/m 2/m

Structure & Data

Crystal Structure

Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); metal sulfides with halides; similar structure to owensite.2 Structure is closely related to those of cubic minerals pentlandite & djerfisherite; all 3 minerals have cubic close-packed S layers, which with 8 Fe atoms in edge-shared FeS4 tetrahedra form Fe8S14 cube clusters; substitutions of K for S in close-packed layers, staking sequence of cube clusters, & variations in kinds of atoms & vacancies occupying octahedral & tetrahedral sites explain structural diff among 3 minerals; avg bond distances in bartonite are: Fe—S, 2.289 Å; Fe—Fe, 2.724 Å; & K—S, 3.369 Å.3

Cell Data

a=10.42Å, c=20.63Å, Z=2

Geology & Identification

Geologic Occurrence

In clots with sulfides-silicates in an alkalic diatreme which intrudes Franciscan rocksBARTONITEBARTONITE

Habit

Anhedral masses, intergrown with pyrrhotite, submicro crystals

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

S – dominant analog of chlorbartonite

If you are fascinated by the hidden structures of our planet, you have likely come across BARTONITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BARTONITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BARTONITE is defined by the chemical formula K6Fe20S26S.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BARTONITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Ditetragonal dipyramidal.
  • Point Group: 4/m 2/m 2/m
  • Space Group: I4/mmm
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BARTONITE, the dimensions of this microscopic building block are:
a=10.42Å, c=20.63Å, Z=2
The internal arrangement of these atoms is described as:Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); metal sulfides with halides; similar structure to owensite.2 Structure is closely related to those of cubic minerals pentlandite & djerfisherite; all 3 minerals have cubic close-packed S layers, which with 8 Fe atoms in edge-shared FeS4 tetrahedra form Fe8S14 cube clusters; substitutions of K for S in close-packed layers, staking sequence of cube clusters, & variations in kinds of atoms & vacancies occupying octahedral & tetrahedral sites explain structural diff among 3 minerals; avg bond distances in bartonite are: Fe—S, 2.289 Å; Fe—Fe, 2.724 Å; & K—S, 3.369 Å.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find BARTONITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Anhedral masses, intergrown with pyrrhotite, submicro crystals
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BARTONITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In clots with sulfides-silicates in an alkalic diatreme which intrudes Franciscan rocksKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BARTONITE is often related to other species, either through similar chemistry or structure.Relationship Data: S – dominant analog of chlorbartoniteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of BARTONITE?The standard chemical formula for BARTONITE is K6Fe20S26S. This defines its elemental composition.2. Which crystal system does BARTONITE belong to?BARTONITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Ditetragonal dipyramidal class.
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3. How is BARTONITE typically found in nature?The “habit” or typical appearance of BARTONITE is described as Anhedral masses, intergrown with pyrrhotite, submicro crystals. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BARTONITE form?BARTONITE is typically found in environments described as: In clots with sulfides-silicates in an alkalic diatreme which intrudes Franciscan rocks. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BARTONITE?Yes, it is often associated with or related to other minerals such as: S – dominant analog of chlorbartonite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BARTONITE, we recommend checking high-authority databases:

Final Thoughts

BARTONITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of K6Fe20S26S and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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