BERNARLOTTIITE Mineral Details

Complete mineralogical data for BERNARLOTTIITE. Chemical Formula: Pb12(As10Sb6)S36. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

BERNARLOTTIITE

Pb12(As10Sb6)S36

Crystal System

Triclinic

Crystal Class

Pedial

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Structure can be described as being formed by 1:1 alternation of sartorite-type (N = 3) & dufrenoysite type (N = 4) layers along c, connected by Pb atoms with tricapped trig prismatic coordination; each layer results from stacking of 2 types of ribbons along a, centrosymmetric 1 alternating with 2 acentric 1; 3 main bldg operations of structure are (1) interlayers As- vs -Pb crossed substitution, stabilizing combined N = (3,4) baumhauerite homologue, (2) inter-ribbon Sb partitioning in sartorite-type layer with “symmetrization” of Sb-rich ribbon, that induces 3a superstructure, & (3) common (As,Sb) polymerization thru short (As,Sb)—S bonds.2 New members of sartorite homologus series, bernarlottiite, écrinsite, heptasartorite, enneasartorite, hendekasartorite & polloneite, (Makovicky 1985, 1997), which have 2 known slab types based on SnS arche-type (N = 3 & N = 4, representing # of polyhedra across each of them); variety of species is created by combo of these 2-unit homologue slabs (i.e., N1-2 = 3,4 = 3.5) in diff ratios; bernarlottiite & écrinsite have N1.2 = 3,4, i.e., N = 3.5, & share same N value with baumhauerite, argentobaumhauerite & boscardinite; polloneite is N = 4 member with substantial Sb & small, but major Ag content; heptasartorite, enneasartor-ite, & hendekasartorite belong to lower most members of series (all slabs with N = 3); species are S-omission series with perodicity imperfections expressed as non-commensurate structures, & are referred to as “M-sartorites” where M stands for hepta-, ennea, & hendeka (7,9,11) or to AOD; in “M-sartorites”, Sb does not exceed 1-2 wt %; Ag is absent in them in agreement with N = 3.3

Cell Data

a=23.704Å, b=8.386Å, c=23.501Å, α=89.91o, ß=102.93o, γ=89.88o, Z=3

Geology & Identification

Geologic Occurrence

MarbleBERNARLOTTIITEBERNARLOTTIITE

Habit

As acicular crystals

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Sartorite homologous series

If you are fascinated by the hidden structures of our planet, you have likely come across BERNARLOTTIITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BERNARLOTTIITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BERNARLOTTIITE is defined by the chemical formula Pb12(As10Sb6)S36.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BERNARLOTTIITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pedial.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BERNARLOTTIITE, the dimensions of this microscopic building block are:
a=23.704Å, b=8.386Å, c=23.501Å, α=89.91o, ß=102.93o, γ=89.88o, Z=3
The internal arrangement of these atoms is described as:
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Structure can be described as being formed by 1:1 alternation of sartorite-type (N = 3) & dufrenoysite type (N = 4) layers along c, connected by Pb atoms with tricapped trig prismatic coordination; each layer results from stacking of 2 types of ribbons along a, centrosymmetric 1 alternating with 2 acentric 1; 3 main bldg operations of structure are (1) interlayers As- vs -Pb crossed substitution, stabilizing combined N = (3,4) baumhauerite homologue, (2) inter-ribbon Sb partitioning in sartorite-type layer with “symmetrization” of Sb-rich ribbon, that induces 3a superstructure, & (3) common (As,Sb) polymerization thru short (As,Sb)—S bonds.2 New members of sartorite homologus series, bernarlottiite, écrinsite, heptasartorite, enneasartorite, hendekasartorite & polloneite, (Makovicky 1985, 1997), which have 2 known slab types based on SnS arche-type (N = 3 & N = 4, representing # of polyhedra across each of them); variety of species is created by combo of these 2-unit homologue slabs (i.e., N1-2 = 3,4 = 3.5) in diff ratios; bernarlottiite & écrinsite have N1.2 = 3,4, i.e., N = 3.5, & share same N value with baumhauerite, argentobaumhauerite & boscardinite; polloneite is N = 4 member with substantial Sb & small, but major Ag content; heptasartorite, enneasartor-ite, & hendekasartorite belong to lower most members of series (all slabs with N = 3); species are S-omission series with perodicity imperfections expressed as non-commensurate structures, & are referred to as “M-sartorites” where M stands for hepta-, ennea, & hendeka (7,9,11) or to AOD; in “M-sartorites”, Sb does not exceed 1-2 wt %; Ag is absent in them in agreement with N = 3.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find BERNARLOTTIITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As acicular crystals
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BERNARLOTTIITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: MarbleKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BERNARLOTTIITE is often related to other species, either through similar chemistry or structure.Relationship Data: Sartorite homologous seriesUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of BERNARLOTTIITE?The standard chemical formula for BERNARLOTTIITE is Pb12(As10Sb6)S36. This defines its elemental composition.
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2. Which crystal system does BERNARLOTTIITE belong to?BERNARLOTTIITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pedial class.3. How is BERNARLOTTIITE typically found in nature?The “habit” or typical appearance of BERNARLOTTIITE is described as As acicular crystals. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BERNARLOTTIITE form?BERNARLOTTIITE is typically found in environments described as: Marble. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BERNARLOTTIITE?Yes, it is often associated with or related to other minerals such as: Sartorite homologous series.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BERNARLOTTIITE, we recommend checking high-authority databases:

Final Thoughts

BERNARLOTTIITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb12(As10Sb6)S36 and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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