BIKITAITE Mineral Details

Complete mineralogical data for BIKITAITE. Chemical Formula: Li[Si2AlO6]·H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

BIKITAITE

Li[Si2AlO6]·H2O

Crystal System

Monoclinic

Crystal Class

Sphenoidal

Space Group

P21

Point Group

2

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of 5-membered rings // [001] linked into framework with 6- & 8-membered rings, & channels // [010] containing LiO3(H2O) tetrahedra.2 Framework of Al & Si tetrahedra, holes filled by large atoms; if smaller atoms repl these, i.e. Cs by Na, holes also lodge H2O in proportional amt; 1 molecule per Li atom.3 Framework can be constructed from puckered 6-membered ring sheets of tridymite-type, where up & down tetahedra alternate; these sheets || to (001) have pyroxene tetrahedral type chains above & below extending || to b-axis, connecting 2 neighboring sheets; orientation of sheets agrees with observed morphology & prf cleavage; structure is typified by channels || to b-axis delimited by deformed 8-membered rings; ½ of tetrahedra in 6-membered ring sheets are occupied by Al, well ordered in triclinic & disordered in monoclinic bikitaite, whereas tetrahedra in pyroxene type chains are only occupied by Si; it is not understood as yet whether short range (Si,Al) ordering is preserved within sheets of monoclinic bikitaite (Bissert & Liebau, 1986); Li is close to walls of b-extended channels & bonds to 3 framework O of Al tetrahedra & to 1 H2O molecule; array of H2O molecules forming H—bonded H2O molecules forming H—bonded H2O chains || to b-axis was investigated by Stahl et al (1989) & Quartieri et al (1999).4 Zeolites are aluminosilicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; bikitaite molecules of H2O occupy extra-framework positions; framework consists of 5-membered rings linked by add’l tetrahedra; partly ordered Si,Al distribution.5 See “Additional Structures” tab for entry(s).6

Cell Data

a=8.61Å, b=4.96Å, c=7.60Å, ß=114.4o, Z=2

Geology & Identification

Geologic Occurrence

In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sedimentsBIKITAITEBIKITAITE

Habit

Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family

If you are fascinated by the hidden structures of our planet, you have likely come across BIKITAITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BIKITAITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BIKITAITE is defined by the chemical formula Li[Si2AlO6]·H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BIKITAITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Sphenoidal.
  • Point Group: 2
  • Space Group: P21
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BIKITAITE, the dimensions of this microscopic building block are:
a=8.61Å, b=4.96Å, c=7.60Å, ß=114.4o, Z=2
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of 5-membered rings // [001] linked into framework with 6- & 8-membered rings, & channels // [010] containing LiO3(H2O) tetrahedra.2 Framework of Al & Si tetrahedra, holes filled by large atoms; if smaller atoms repl these, i.e. Cs by Na, holes also lodge H2O in proportional amt; 1 molecule per Li atom.3 Framework can be constructed from puckered 6-membered ring sheets of tridymite-type, where up & down tetahedra alternate; these sheets || to (001) have pyroxene tetrahedral type chains above & below extending || to b-axis, connecting 2 neighboring sheets; orientation of sheets agrees with observed morphology & prf cleavage; structure is typified by channels || to b-axis delimited by deformed 8-membered rings; ½ of tetrahedra in 6-membered ring sheets are occupied by Al, well ordered in triclinic & disordered in monoclinic bikitaite, whereas tetrahedra in pyroxene type chains are only occupied by Si; it is not understood as yet whether short range (Si,Al) ordering is preserved within sheets of monoclinic bikitaite (Bissert & Liebau, 1986); Li is close to walls of b-extended channels & bonds to 3 framework O of Al tetrahedra & to 1 H2O molecule; array of H2O molecules forming H—bonded H2O molecules forming H—bonded H2O chains || to b-axis was investigated by Stahl et al (1989) & Quartieri et al (1999).4 Zeolites are aluminosilicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; bikitaite molecules of H2O occupy extra-framework positions; framework consists of 5-membered rings linked by add’l tetrahedra; partly ordered Si,Al distribution.5 See “Additional Structures” tab for entry(s).6This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find BIKITAITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BIKITAITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sedimentsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BIKITAITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite familyUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of BIKITAITE?The standard chemical formula for BIKITAITE is Li[Si2AlO6]·H2O. This defines its elemental composition.
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2. Which crystal system does BIKITAITE belong to?BIKITAITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Sphenoidal class.3. How is BIKITAITE typically found in nature?The “habit” or typical appearance of BIKITAITE is described as Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BIKITAITE form?BIKITAITE is typically found in environments described as: In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sediments. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BIKITAITE?Yes, it is often associated with or related to other minerals such as: Zeolite family.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BIKITAITE, we recommend checking high-authority databases:

Final Thoughts

BIKITAITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Li[Si2AlO6]·H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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