BOURNONITE Mineral Details

Complete mineralogical data for BOURNONITE. Chemical Formula: PbCuSbS3. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

BOURNONITE

PbCuSbS3

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Pn21m

Point Group

m m 2

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb or Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; Pb[7,8] polyhedra, (As,Sb) S3 ∆ & CuS4 tetrahedra share corners & edges to form 3-D framework; Cu4 tetrahedra share corners to form chains // [001].2 Isotypical with seligmannite; their structures are sub-framework in which CuS4 tetrahedra are connected at vertices with AsS2 (SbS3) ∆ & along edges with Pb— polyhedra in which Pb atoms have CN 7 & 8; interatomic distances are: Cu—S4 = 2.29—2.41 Å; Pb—S7 = 2.82—3.33 Å; Pb—S8 = 2.83—3.58 Å; Sb—S2 = 2.39—2.52 Å.3 2 sulfosalt structures are isotypic; Pb(1) atoms are surrounded by 8 S atoms, Pb(2) atoms by 7 S atoms; Sb resp As atoms have trig ∆ coordination by S atoms; SbS3 resp AsS3 ∆ are isolated; Sb—S resp As—S distances are in good agreement with Sb—S resp As—S covalent—bond length; Cu atoms are slightly deformed tetrahedrally coordinated by 4 S atoms; Cu tetrahedra are sharing corners || to c axis.4

Cell Data

a=8.15Å, b=8.69Å, c=7.79Å, Z=4

Geology & Identification

Geologic Occurrence

In hydrothermal veins formed at moderate temperaturesBOURNONITEBOURNONITE

Habit

Short prismatic to tabular, striated macro crystals; massive, granular, compact

Twinning

On {110} commonly forming cross or cogwheel aggregates

Relationships

RELATIONSHIP TO OTHER MINERALS

Bournonite group; forms series with seligmannite

If you are fascinated by the hidden structures of our planet, you have likely come across BOURNONITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BOURNONITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BOURNONITE is defined by the chemical formula PbCuSbS3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BOURNONITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Pn21m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BOURNONITE, the dimensions of this microscopic building block are:
a=8.15Å, b=8.69Å, c=7.79Å, Z=4
The internal arrangement of these atoms is described as:Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb or Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; Pb[7,8] polyhedra, (As,Sb) S3 ∆ & CuS4 tetrahedra share corners & edges to form 3-D framework; Cu4 tetrahedra share corners to form chains // [001].2 Isotypical with seligmannite; their structures are sub-framework in which CuS4 tetrahedra are connected at vertices with AsS2 (SbS3) ∆ & along edges with Pb— polyhedra in which Pb atoms have CN 7 & 8; interatomic distances are: Cu—S4 = 2.29—2.41 Å; Pb—S7 = 2.82—3.33 Å; Pb—S8 = 2.83—3.58 Å; Sb—S2 = 2.39—2.52 Å.3 2 sulfosalt structures are isotypic; Pb(1) atoms are surrounded by 8 S atoms, Pb(2) atoms by 7 S atoms; Sb resp As atoms have trig ∆ coordination by S atoms; SbS3 resp AsS3 ∆ are isolated; Sb—S resp As—S distances are in good agreement with Sb—S resp As—S covalent—bond length; Cu atoms are slightly deformed tetrahedrally coordinated by 4 S atoms; Cu tetrahedra are sharing corners || to c axis.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find BOURNONITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short prismatic to tabular, striated macro crystals; massive, granular, compact
  • Twinning: On {110} commonly forming cross or cogwheel aggregates
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BOURNONITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In hydrothermal veins formed at moderate temperaturesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BOURNONITE is often related to other species, either through similar chemistry or structure.Relationship Data: Bournonite group; forms series with seligmanniteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of BOURNONITE?The standard chemical formula for BOURNONITE is PbCuSbS3. This defines its elemental composition.
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2. Which crystal system does BOURNONITE belong to?BOURNONITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is BOURNONITE typically found in nature?The “habit” or typical appearance of BOURNONITE is described as Short prismatic to tabular, striated macro crystals; massive, granular, compact. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BOURNONITE form?BOURNONITE is typically found in environments described as: In hydrothermal veins formed at moderate temperatures. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BOURNONITE?Yes, it is often associated with or related to other minerals such as: Bournonite group; forms series with seligmannite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BOURNONITE, we recommend checking high-authority databases:

Final Thoughts

BOURNONITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbCuSbS3 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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