BULTFONTEINITE Mineral Details

Complete mineralogical data for BULTFONTEINITE. Chemical Formula: Ca2[SiO3(OH)]F(H2O). Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

BULTFONTEINITE

Ca2[SiO3(OH)]F(H2O)

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Nesosilicates: insular SiO4 tetrahedra with add’l anions; cations in [6] & >[6] coordination; double chains similar to those in afwillite run along [001] linked by Si—O—Ca bonds, F atoms & H2O molecules.1 Columns of Ca & Si polyhedra linked by edges & joined into strips of composition [Ca4 Si2O4]8+, which run along c axis in rows || to (100), being linked together via Ca polyhedra, F atoms & H2O molecules; Ca has CN = 7, but in diff positions, in some of which 7th member is F, while in others it is OH or H2O.2 Structure presents 4 independent Ca sites & 2 independent Si sites; Ca sites have [7] coordination with avg bond distance around 2.40 Å; Ca—O distances range from 2.304(6) Å (Ca3—O7 bond) to 2.560(7) Å (Ca3—O8 distance); these bond lengths agree with those given by McIver (1963), ranging from 2.31(2) to 2.59(2) Å; coordination polyhedra of Ca sites can be described as monocapped trig prism; capping ligands are O9, O10, O5, & O6 for 4 independent Ca sites, resp; avg Si—O distance is 1.632 & 1.631 Å for Si1 & Si2 sites, resp; bond lengths range from 1.596(6) to 1.654(7) Å; xl structure can be described as formed by 2 kinds of layers, stacked along [010]; 1st layer is composed by Ca1, Ca2, Si1, & Si2 polyhedra; Ca1 & Ca2 share edges, forming ribbons running along [001] with alternation of Ca1 & Ca2 sites; every ribbon has anionic sites O9 & O10 (capping ligands of Ca polyhedra) pointing in same direction; adjacent ribbons have these sites pointing in opposite direction; layer assumes wavy character; every ribbon is connected to adjacent ones by Si tetrahedra & H—bonds; 2nd layer is formed by Ca3 & Ca4 polyhedra; they form ribbons running along [001] with alternation of Ca3 & Ca4; as observed in layer A, ribbons with capping ligands (O5 & O6) pointing in direction are linked by edge-sharing to ribbons having these sites pointing in opposite direction; ininite 2-D wavy layer is formed; connection btw layer A & B is achieved thru edge-sharing btw Ca polyhedra belonging to 2 layers & thru sharing of edge of Si tetrahedron.3,4

Cell Data

a=10.99Å, b=8.18Å, c=5.67Å, α=93.9o, ß=91.3o, γ=89.8o, Z=4

Geology & Identification

Geologic Occurrence

In diabase and shale fragments in a kimberlite pipe; in thermally metamorphosed limestoneBULTFONTEINITEBULTFONTEINITE

Habit

As radiating prismatic acicular macro crystals and radial spherules

Twinning

Interpenetrating on {100} and {010}; polysynthetic

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across BULTFONTEINITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about BULTFONTEINITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, BULTFONTEINITE is defined by the chemical formula Ca2[SiO3(OH)]F(H2O).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. BULTFONTEINITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For BULTFONTEINITE, the dimensions of this microscopic building block are:
a=10.99Å, b=8.18Å, c=5.67Å, α=93.9o, ß=91.3o, γ=89.8o, Z=4
The internal arrangement of these atoms is described as:
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Nesosilicates: insular SiO4 tetrahedra with add’l anions; cations in [6] & >[6] coordination; double chains similar to those in afwillite run along [001] linked by Si—O—Ca bonds, F atoms & H2O molecules.1 Columns of Ca & Si polyhedra linked by edges & joined into strips of composition [Ca4 Si2O4]8+, which run along c axis in rows || to (100), being linked together via Ca polyhedra, F atoms & H2O molecules; Ca has CN = 7, but in diff positions, in some of which 7th member is F, while in others it is OH or H2O.2 Structure presents 4 independent Ca sites & 2 independent Si sites; Ca sites have [7] coordination with avg bond distance around 2.40 Å; Ca—O distances range from 2.304(6) Å (Ca3—O7 bond) to 2.560(7) Å (Ca3—O8 distance); these bond lengths agree with those given by McIver (1963), ranging from 2.31(2) to 2.59(2) Å; coordination polyhedra of Ca sites can be described as monocapped trig prism; capping ligands are O9, O10, O5, & O6 for 4 independent Ca sites, resp; avg Si—O distance is 1.632 & 1.631 Å for Si1 & Si2 sites, resp; bond lengths range from 1.596(6) to 1.654(7) Å; xl structure can be described as formed by 2 kinds of layers, stacked along [010]; 1st layer is composed by Ca1, Ca2, Si1, & Si2 polyhedra; Ca1 & Ca2 share edges, forming ribbons running along [001] with alternation of Ca1 & Ca2 sites; every ribbon has anionic sites O9 & O10 (capping ligands of Ca polyhedra) pointing in same direction; adjacent ribbons have these sites pointing in opposite direction; layer assumes wavy character; every ribbon is connected to adjacent ones by Si tetrahedra & H—bonds; 2nd layer is formed by Ca3 & Ca4 polyhedra; they form ribbons running along [001] with alternation of Ca3 & Ca4; as observed in layer A, ribbons with capping ligands (O5 & O6) pointing in direction are linked by edge-sharing to ribbons having these sites pointing in opposite direction; ininite 2-D wavy layer is formed; connection btw layer A & B is achieved thru edge-sharing btw Ca polyhedra belonging to 2 layers & thru sharing of edge of Si tetrahedron.3,4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find BULTFONTEINITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As radiating prismatic acicular macro crystals and radial spherules
  • Twinning: Interpenetrating on {100} and {010}; polysynthetic
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If BULTFONTEINITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In diabase and shale fragments in a kimberlite pipe; in thermally metamorphosed limestoneKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. BULTFONTEINITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of BULTFONTEINITE?The standard chemical formula for BULTFONTEINITE is Ca2[SiO3(OH)]F(H2O). This defines its elemental composition.2. Which crystal system does BULTFONTEINITE belong to?BULTFONTEINITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.3. How is BULTFONTEINITE typically found in nature?The “habit” or typical appearance of BULTFONTEINITE is described as As radiating prismatic acicular macro crystals and radial spherules. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does BULTFONTEINITE form?BULTFONTEINITE is typically found in environments described as: In diabase and shale fragments in a kimberlite pipe; in thermally metamorphosed limestone. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to BULTFONTEINITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of BULTFONTEINITE, we recommend checking high-authority databases:

Final Thoughts

BULTFONTEINITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca2[SiO3(OH)]F(H2O) and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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