COQUIMBITE Mineral Details

Complete mineralogical data for COQUIMBITE. Chemical Formula: AlFe3+3(SO4)6(H2O)12·6H2O. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

COQUIMBITE

AlFe3+3(SO4)6(H2O)12·6H2O

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal scalenohedral

Space Group

P31c

Point Group

3 2/m

Structure & Data

Crystal Structure

Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing w/o add’l anions with H2O with medium-sized cations; clusters of 3 corner-sharing octahedra & 6 tetrahedra, insular Fe(H2O)6 octahedron & 3 free H2O molecules.1 Subchain of chains composed of alternating Fe octahedra & SO4 tetrahedra ranging || to c axis; Fe segments of chains are linked thru H—bonds; in holes btw chains are placed H2O molecules also linked to chains by H—bonds.2 Among 3 cation positions, isolated octahedral 1 is dominantly occupied by Al; avg Al-O interatomic distance is 1.9155 Å, smaller than Fe-O distances, 2.002 Å for Fe(1) & 1.989 Å for Fe(2).3 Both minerals are typified by complex system of H—bonds involving 3 types of H2O molecules, resp: those of [Fe3(SO4)6(H2O)6]3- clusters of isolated [Fe(H2O)6]3+ or [Al(H2O)6]3+ octahedra & further interstitial (H2O) grp; interstitial H2O molecules resemble cyclohexane-like chair & are held in structure solely by H—bonding; in coquimbite H2OW(2) is disordered with 2 alternative orientations (H2B1 & H2B2), in paracoquimbite interstitial H2O consists of 2 H2O molecules; H2OW(3) & H2OW(4).4 Al occupies distinct site in xl structure.5

Cell Data

a=10.92Å, c=17.08Å, Z=2

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized portions of weathering iron sulfide deposits in arid regions; fumarolicCOQUIMBITECOQUIMBITE

Habit

Short prismatic to pyramidal macro crystals; massive, granular

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorphous with paracoquimbite; Structurally related to aluminocoquimbite

If you are fascinated by the hidden structures of our planet, you have likely come across COQUIMBITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about COQUIMBITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, COQUIMBITE is defined by the chemical formula AlFe3+3(SO4)6(H2O)12·6H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. COQUIMBITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal scalenohedral.
  • Point Group: 3 2/m
  • Space Group: P31c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For COQUIMBITE, the dimensions of this microscopic building block are:
a=10.92Å, c=17.08Å, Z=2
The internal arrangement of these atoms is described as:Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing w/o add’l anions with H2O with medium-sized cations; clusters of 3 corner-sharing octahedra & 6 tetrahedra, insular Fe(H2O)6 octahedron & 3 free H2O molecules.1 Subchain of chains composed of alternating Fe octahedra & SO4 tetrahedra ranging || to c axis; Fe segments of chains are linked thru H—bonds; in holes btw chains are placed H2O molecules also linked to chains by H—bonds.2 Among 3 cation positions, isolated octahedral 1 is dominantly occupied by Al; avg Al-O interatomic distance is 1.9155 Å, smaller than Fe-O distances, 2.002 Å for Fe(1) & 1.989 Å for Fe(2).3 Both minerals are typified by complex system of H—bonds involving 3 types of H2O molecules, resp: those of [Fe3(SO4)6(H2O)6]3- clusters of isolated [Fe(H2O)6]3+ or [Al(H2O)6]3+ octahedra & further interstitial (H2O) grp; interstitial H2O molecules resemble cyclohexane-like chair & are held in structure solely by H—bonding; in coquimbite H2OW(2) is disordered with 2 alternative orientations (H2B1 & H2B2), in paracoquimbite interstitial H2O consists of 2 H2O molecules; H2OW(3) & H2OW(4).4 Al occupies distinct site in xl structure.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find COQUIMBITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short prismatic to pyramidal macro crystals; massive, granular
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If COQUIMBITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized portions of weathering iron sulfide deposits in arid regions; fumarolicKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. COQUIMBITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorphous with paracoquimbite; Structurally related to aluminocoquimbiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of COQUIMBITE?The standard chemical formula for COQUIMBITE is AlFe3+3(SO4)6(H2O)12·6H2O. This defines its elemental composition.2. Which crystal system does COQUIMBITE belong to?COQUIMBITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal scalenohedral class.
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3. How is COQUIMBITE typically found in nature?The “habit” or typical appearance of COQUIMBITE is described as Short prismatic to pyramidal macro crystals; massive, granular. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does COQUIMBITE form?COQUIMBITE is typically found in environments described as: Secondary mineral in oxidized portions of weathering iron sulfide deposits in arid regions; fumarolic. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to COQUIMBITE?Yes, it is often associated with or related to other minerals such as: Dimorphous with paracoquimbite; Structurally related to aluminocoquimbite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of COQUIMBITE, we recommend checking high-authority databases:

Final Thoughts

COQUIMBITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of AlFe3+3(SO4)6(H2O)12·6H2O and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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