CRYOLITHIONITE Mineral Details

Complete mineralogical data for CRYOLITHIONITE. Chemical Formula: Na3Li3Al2F12. Crystal System: Isometric. Learn about its geologic occurrence, habit, and identification.

CRYOLITHIONITE

Na3Li3Al2F12

Crystal System

Isometric

Crystal Class

Cubic hexoctahedral

Space Group

Ia3d

Point Group

4/m 3 2/m

Structure & Data

Crystal Structure

Halides are ionically bonded compounds of cations Na1+, Ca2+, etc. & halogen anions F1-, Cl1-, Br1-, I1-; complex halides, neso-aluminofluorides; garnet structure type.2 Garnet type; AlF6 octahedra linked via common vertices to LiF4 tetrahedra to form framework whose holes contain Na (CN = 8); bonds in framework polyhedra appreciably stronger than those in NaF8 poyhedra.3 Only known garnet in which tetrahedral cation-anion (Li+—F-) distance, 1.846Å, is longer than octahedral cation-anion (Al3+—F-) distance, 1.807Å; Na+—F- distances are 2.351Å & 2.544Å.4

Cell Data

a=12.12Å, Z=8

Geology & Identification

Geologic Occurrence

In some granite pegmatitesCRYOLITHIONITECRYOLITHIONITE

Habit

As macro dodecahedra crystals; commonly as coarse granular aggregates

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Garnet supergroup, unnamed group

If you are fascinated by the hidden structures of our planet, you have likely come across CRYOLITHIONITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about CRYOLITHIONITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, CRYOLITHIONITE is defined by the chemical formula Na3Li3Al2F12.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. CRYOLITHIONITE crystallizes in the Isometric system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Cubic hexoctahedral.
  • Point Group: 4/m 3 2/m
  • Space Group: Ia3d
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Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For CRYOLITHIONITE, the dimensions of this microscopic building block are:
a=12.12Å, Z=8
The internal arrangement of these atoms is described as:Halides are ionically bonded compounds of cations Na1+, Ca2+, etc. & halogen anions F1-, Cl1-, Br1-, I1-; complex halides, neso-aluminofluorides; garnet structure type.2 Garnet type; AlF6 octahedra linked via common vertices to LiF4 tetrahedra to form framework whose holes contain Na (CN = 8); bonds in framework polyhedra appreciably stronger than those in NaF8 poyhedra.3 Only known garnet in which tetrahedral cation-anion (Li+—F-) distance, 1.846Å, is longer than octahedral cation-anion (Al3+—F-) distance, 1.807Å; Na+—F- distances are 2.351Å & 2.544Å.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find CRYOLITHIONITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As macro dodecahedra crystals; commonly as coarse granular aggregates
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If CRYOLITHIONITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In some granite pegmatitesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. CRYOLITHIONITE is often related to other species, either through similar chemistry or structure.Relationship Data: Garnet supergroup, unnamed groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of CRYOLITHIONITE?The standard chemical formula for CRYOLITHIONITE is Na3Li3Al2F12. This defines its elemental composition.2. Which crystal system does CRYOLITHIONITE belong to?CRYOLITHIONITE crystallizes in the Isometric system. Its internal symmetry is further classified under the Cubic hexoctahedral class.
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3. How is CRYOLITHIONITE typically found in nature?The “habit” or typical appearance of CRYOLITHIONITE is described as As macro dodecahedra crystals; commonly as coarse granular aggregates. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does CRYOLITHIONITE form?CRYOLITHIONITE is typically found in environments described as: In some granite pegmatites. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to CRYOLITHIONITE?Yes, it is often associated with or related to other minerals such as: Garnet supergroup, unnamed group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of CRYOLITHIONITE, we recommend checking high-authority databases:

Final Thoughts

CRYOLITHIONITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na3Li3Al2F12 and a structure defined by the Isometric system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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