FERRARISITE Mineral Details

Complete mineralogical data for FERRARISITE. Chemical Formula: Ca5(AsO3OH)2(AsO4)2(H2O)5·4H2O. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

FERRARISITE

Ca5(AsO3OH)2(AsO4)2(H2O)5·4H2O

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with only large cations; 2 Ca[7] polyhedra share edges & corners with AsO4 tetrahedra to form sheets // (001); Ca[8] lodged btw sheets, forming channels // [010] & [100] that contain H2O molecules.1 1 Ca atom & 3 H2O molecules are disordered over centrosymmetrically-related positions; isostructural (001) layers of Ca & As coordination polyhedra are observed in structures of both nona- & penta-hydrated phases; they diff by relative shift, sandwich ordered & disordered Ca octahedra, resp in 2 cases; dehydration involves loss of interlayer H2O molecules alternativedly from either set of centro-symmetrically-related positions, while layers slide approach one another; sandwiched Ca atoms are left attached alternatively to either side of facing layers, & repl their broken coordination bonds by new ones on side of shifted layer; this random character of dehydration reaction is cause of disorder in penta-hydrated phase.2

Cell Data

a=8.29Å, b=6.72Å, c=11.20Å, α=106.2o, ß=92.9o, γ=99.2o, Z=1

Geology & Identification

Geologic Occurrence

Post mine, low-temperature reation product to carbonate gangue with arsenical solutions derived from arsenicFERRARISITEFERRARISITE

Habit

Flattened submicro crystals, slightly elongated, with pseudohexagonal outline

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorphous with guérinite; polymorph of vladimirite

If you are fascinated by the hidden structures of our planet, you have likely come across FERRARISITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about FERRARISITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, FERRARISITE is defined by the chemical formula Ca5(AsO3OH)2(AsO4)2(H2O)5·4H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. FERRARISITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For FERRARISITE, the dimensions of this microscopic building block are:
a=8.29Å, b=6.72Å, c=11.20Å, α=106.2o, ß=92.9o, γ=99.2o, Z=1
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with only large cations; 2 Ca[7] polyhedra share edges & corners with AsO4 tetrahedra to form sheets // (001); Ca[8] lodged btw sheets, forming channels // [010] & [100] that contain H2O molecules.1 1 Ca atom & 3 H2O molecules are disordered over centrosymmetrically-related positions; isostructural (001) layers of Ca & As coordination polyhedra are observed in structures of both nona- & penta-hydrated phases; they diff by relative shift, sandwich ordered & disordered Ca octahedra, resp in 2 cases; dehydration involves loss of interlayer H2O molecules alternativedly from either set of centro-symmetrically-related positions, while layers slide approach one another; sandwiched Ca atoms are left attached alternatively to either side of facing layers, & repl their broken coordination bonds by new ones on side of shifted layer; this random character of dehydration reaction is cause of disorder in penta-hydrated phase.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find FERRARISITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Flattened submicro crystals, slightly elongated, with pseudohexagonal outline
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If FERRARISITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Post mine, low-temperature reation product to carbonate gangue with arsenical solutions derived from arsenicKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. FERRARISITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorphous with guérinite; polymorph of vladimiriteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of FERRARISITE?The standard chemical formula for FERRARISITE is Ca5(AsO3OH)2(AsO4)2(H2O)5·4H2O. This defines its elemental composition.
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2. Which crystal system does FERRARISITE belong to?FERRARISITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.3. How is FERRARISITE typically found in nature?The “habit” or typical appearance of FERRARISITE is described as Flattened submicro crystals, slightly elongated, with pseudohexagonal outline. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does FERRARISITE form?FERRARISITE is typically found in environments described as: Post mine, low-temperature reation product to carbonate gangue with arsenical solutions derived from arsenic. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to FERRARISITE?Yes, it is often associated with or related to other minerals such as: Dimorphous with guérinite; polymorph of vladimirite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of FERRARISITE, we recommend checking high-authority databases:

Final Thoughts

FERRARISITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca5(AsO3OH)2(AsO4)2(H2O)5·4H2O and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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