FERRIERITE-Mg Mineral Details

Complete mineralogical data for FERRIERITE-Mg. Chemical Formula: (K,Na)2Ca0.5Mg2[Si29Al7O72]·18H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

FERRIERITE-Mg

(K,Na)2Ca0.5Mg2[Si29Al7O72]·18H2O

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Immm

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O, with chains of 5-membered rings // [010] connected into framework of 5-, 6-, 8-, 10-membered rings with channels // [001] that contain Mg(H2O)62+ ions.2 Large rings composed of 10 (Al,Si)O4 tetrahedra, prp to c axis; also smaller rings with 8-, 6-, 5- members; open channels along c axis run thru large rings, these being elliptical; these rings contain randomly placed Na ions & H2O modules; holes formed by 6-sided rings contain Mg surrounded by 6 H2O; weakest bonds in structure lie along b axis, which is resposible for tabular habit & prf (010) cleavage & being platy zeolite.3 Ferrierite may be orthorhombic, s.g. Immm, which agrees with max symmetry of framework topology (Vaughn (1966), Gramlich-Meier et al (1984 & 1985)) refined structure of ferrierite-Na in s.g. P21/n; in contrast to orhorhombic structure, monoclinic ferrierite-Na has no T-O-T angles of 180o; in light of discussion on mordenite, dachiardite & epistilbite structure, it may be speculated that lower symmetry is gen feature of all ferrierite (Alberti (1986), Alberti & Sabelli (1987); Alberti & Sabelli (1987) refined structure of ferrierite-Mg from Monastir, Sardinia, in s.g. Immm but provided strong evidence, based on disorder of Mg(H2O)62+ non-framework complex, that true s.g. is Pnnm, which leads to relaxation of 180o T-O-T angle.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; ferrierite framework of Si,Al is partially ordered; K is most abundant single extra-framework cation.6 See “Additional Structures” tab for entry(s). 5,7,8

Cell Data

a=19.23Å, b=14.14Å, c=7.50Å, Z=1

Geology & Identification

Geologic Occurrence

In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sedimentsFERRIERITE-MgFERRIERITE-Mg

Habit

Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family, ferrierite subgroup

If you are fascinated by the hidden structures of our planet, you have likely come across FERRIERITE-Mg. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about FERRIERITE-Mg. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, FERRIERITE-Mg is defined by the chemical formula (K,Na)2Ca0.5Mg2[Si29Al7O72]·18H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. FERRIERITE-Mg crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Immm
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For FERRIERITE-Mg, the dimensions of this microscopic building block are:
a=19.23Å, b=14.14Å, c=7.50Å, Z=1
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O, with chains of 5-membered rings // [010] connected into framework of 5-, 6-, 8-, 10-membered rings with channels // [001] that contain Mg(H2O)62+ ions.2 Large rings composed of 10 (Al,Si)O4 tetrahedra, prp to c axis; also smaller rings with 8-, 6-, 5- members; open channels along c axis run thru large rings, these being elliptical; these rings contain randomly placed Na ions & H2O modules; holes formed by 6-sided rings contain Mg surrounded by 6 H2O; weakest bonds in structure lie along b axis, which is resposible for tabular habit & prf (010) cleavage & being platy zeolite.3 Ferrierite may be orthorhombic, s.g. Immm, which agrees with max symmetry of framework topology (Vaughn (1966), Gramlich-Meier et al (1984 & 1985)) refined structure of ferrierite-Na in s.g. P21/n; in contrast to orhorhombic structure, monoclinic ferrierite-Na has no T-O-T angles of 180o; in light of discussion on mordenite, dachiardite & epistilbite structure, it may be speculated that lower symmetry is gen feature of all ferrierite (Alberti (1986), Alberti & Sabelli (1987); Alberti & Sabelli (1987) refined structure of ferrierite-Mg from Monastir, Sardinia, in s.g. Immm but provided strong evidence, based on disorder of Mg(H2O)62+ non-framework complex, that true s.g. is Pnnm, which leads to relaxation of 180o T-O-T angle.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; ferrierite framework of Si,Al is partially ordered; K is most abundant single extra-framework cation.6 See “Additional Structures” tab for entry(s). 5,7,8This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find FERRIERITE-Mg in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If FERRIERITE-Mg exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sedimentsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. FERRIERITE-Mg is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family, ferrierite subgroupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of FERRIERITE-Mg?The standard chemical formula for FERRIERITE-Mg is (K,Na)2Ca0.5Mg2[Si29Al7O72]·18H2O. This defines its elemental composition.
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2. Which crystal system does FERRIERITE-Mg belong to?FERRIERITE-Mg crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is FERRIERITE-Mg typically found in nature?The “habit” or typical appearance of FERRIERITE-Mg is described as Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does FERRIERITE-Mg form?FERRIERITE-Mg is typically found in environments described as: In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sediments. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to FERRIERITE-Mg?Yes, it is often associated with or related to other minerals such as: Zeolite family, ferrierite subgroup.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of FERRIERITE-Mg, we recommend checking high-authority databases:

Final Thoughts

FERRIERITE-Mg is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of (K,Na)2Ca0.5Mg2[Si29Al7O72]·18H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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