FERROWYLLIEITE Mineral Details

Complete mineralogical data for FERROWYLLIEITE. Chemical Formula: Na2Fe2+(Fe2+Al)(PO4)3. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

FERROWYLLIEITE

Na2Fe2+(Fe2+Al)(PO4)3

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/n

Point Group

2/m

Structure & Data

Crystal Structure

Phosphates, arsenate, vanadate: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with medium-sized & large cations; stepped chains of edge-sharing M22+M3+ octahedra // [101] share corners with PO4 or AsO4 tetrahedra to give pleated sheets // (010); chains of M[8] polyhedra // [001] interlink sheets.2 Ordered couple, Fe2+Al, occurs in xl & results in degradation of alluaudite symmetry; SF can be written X(1a)2X(1b)2X(2)4M(1)4M(2a)4M(2b)4[PO4]12 with following ± site occupancies: X(1a) = 1.82 Na + 0.18 hole, X(1b) = 1.0 Ca + 1.0 Mn2+, X(2) = 2.78 Na + 1.22 hole, M(1) = 3.0 Fe2+ + 1.0 Mg, M(2a) = 4.0 Fe2+, M(2b) = 3.0 Al + 1.0 Fe2+; avg polyhedral distances are X(1a)[8]—O 2.53, P(1)—O 2.21, X(2)[6]—O 2.72, M(1)[8]—O 2.23, M(2a)[6]—O 2.10, M(2b)[6]—O 1.97, P(1)— O 1.54, P(2a)—O 1.53, P(2b)— O 1.53; X(1) polyhedra are distorted cubes, X(2) distorted □ antiprism, M(1) bifurcated □∆, & M(2) are octahedra; conclusions drawn: that primary pegmatite phosphates xllize with Fe2+ valence state, that wyllieite (alluaudite) structure type is high temp dimorph of certain phospate analogs of garnet structure type, & that griphite is metasomatic product.

Cell Data

a=11.87Å, b=12.38Å, c=6.35Å, ß=114.5o, Z=4

Geology & Identification

Geologic Occurrence

In zoned complex granite pegmatitesFERROWYLLIEITEFERROWYLLIEITE

Habit

Macro granular

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Wyllieite group; forms series with wyllieite, rosemaryite

If you are fascinated by the hidden structures of our planet, you have likely come across FERROWYLLIEITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about FERROWYLLIEITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, FERROWYLLIEITE is defined by the chemical formula Na2Fe2+(Fe2+Al)(PO4)3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. FERROWYLLIEITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/n
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For FERROWYLLIEITE, the dimensions of this microscopic building block are:
a=11.87Å, b=12.38Å, c=6.35Å, ß=114.5o, Z=4
The internal arrangement of these atoms is described as:Phosphates, arsenate, vanadate: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with medium-sized & large cations; stepped chains of edge-sharing M22+M3+ octahedra // [101] share corners with PO4 or AsO4 tetrahedra to give pleated sheets // (010); chains of M[8] polyhedra // [001] interlink sheets.2 Ordered couple, Fe2+Al, occurs in xl & results in degradation of alluaudite symmetry; SF can be written X(1a)2X(1b)2X(2)4M(1)4M(2a)4M(2b)4[PO4]12 with following ± site occupancies: X(1a) = 1.82 Na + 0.18 hole, X(1b) = 1.0 Ca + 1.0 Mn2+, X(2) = 2.78 Na + 1.22 hole, M(1) = 3.0 Fe2+ + 1.0 Mg, M(2a) = 4.0 Fe2+, M(2b) = 3.0 Al + 1.0 Fe2+; avg polyhedral distances are X(1a)[8]—O 2.53, P(1)—O 2.21, X(2)[6]—O 2.72, M(1)[8]—O 2.23, M(2a)[6]—O 2.10, M(2b)[6]—O 1.97, P(1)— O 1.54, P(2a)—O 1.53, P(2b)— O 1.53; X(1) polyhedra are distorted cubes, X(2) distorted □ antiprism, M(1) bifurcated □∆, & M(2) are octahedra; conclusions drawn: that primary pegmatite phosphates xllize with Fe2+ valence state, that wyllieite (alluaudite) structure type is high temp dimorph of certain phospate analogs of garnet structure type, & that griphite is metasomatic product.This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find FERROWYLLIEITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Macro granular
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If FERROWYLLIEITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In zoned complex granite pegmatitesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. FERROWYLLIEITE is often related to other species, either through similar chemistry or structure.Relationship Data: Wyllieite group; forms series with wyllieite, rosemaryiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of FERROWYLLIEITE?The standard chemical formula for FERROWYLLIEITE is Na2Fe2+(Fe2+Al)(PO4)3. This defines its elemental composition.
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2. Which crystal system does FERROWYLLIEITE belong to?FERROWYLLIEITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is FERROWYLLIEITE typically found in nature?The “habit” or typical appearance of FERROWYLLIEITE is described as Macro granular. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does FERROWYLLIEITE form?FERROWYLLIEITE is typically found in environments described as: In zoned complex granite pegmatites. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to FERROWYLLIEITE?Yes, it is often associated with or related to other minerals such as: Wyllieite group; forms series with wyllieite, rosemaryite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of FERROWYLLIEITE, we recommend checking high-authority databases:

Final Thoughts

FERROWYLLIEITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na2Fe2+(Fe2+Al)(PO4)3 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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