GALENOBISMUTITE Mineral Details

Complete mineralogical data for GALENOBISMUTITE. Chemical Formula: PbBi2S4. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

GALENOBISMUTITE

PbBi2S4

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pnam

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS arche-type, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; edge- & corner-sharing BiS3 trig ∆ form double chains // [001] which lie in sheets // (010) sheets are linked by chains of Pb[7] atoms // [001].1 Chain structure, but with rather less bond anisotropy than Bi2S3, which is due to higher coordination of Pb (to 7S, d = 3.04 Å) & of Bi (to 6S & 7S, d = 2.89 Å); Bi thus occurs in 2 types of polyhedron, 1 having 7 vertices (BiI) & other being distorted octahedron (BiII); BiS2 chains are joined into double Bi4S8 strips extending along c axis linked together by Pb atoms.2 In Ag-free lillianite trig prism M3 is occupied only by Pb, whereas both octahedrally coordinated M1 & M2 sites are mixed (Pb,Bi) positions; same octahedra incorporate both surplus of Bi & vacancies (□) created by substitution 3Pb2+—> 2Bi3++□, which allows for observed deviations from ideal composition, Pb3Bi2S6; Se is preferentially ordered at [6]- & [5]- coordinated anionic sites, whereas [4]- coordination site S3 remains free of Se; known structural array of galenobismutite was confirmed in this work; octahedrally coordinated M1gb site was found to be a full Bi position; some evidence of Pb—Bi disorder has been observed at both M2gb (Bi-dominated) & M3gb (Pb-dominated) positions; heterogeneous distribution of Se in anionic S sites was observed in galeobismutite; atoms of Se are mainly concentrated at site S1, & less so in other anionic sites.3

Cell Data

a=11.83Å, b=14.64Å, c=4.08Å, Z=4

Geology & Identification

Geologic Occurrence

Of hydrothermal originGALENOBISMUTITEGALENOBISMUTITE

Habit

Crystals lath-like, elongated, flattened, needle-like; crystalline, massive

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across GALENOBISMUTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GALENOBISMUTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GALENOBISMUTITE is defined by the chemical formula PbBi2S4.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GALENOBISMUTITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pnam
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GALENOBISMUTITE, the dimensions of this microscopic building block are:
a=11.83Å, b=14.64Å, c=4.08Å, Z=4
The internal arrangement of these atoms is described as:
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Typified by presence of trig ∆ of As, Sb, Bi represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS arche-type, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; edge- & corner-sharing BiS3 trig ∆ form double chains // [001] which lie in sheets // (010) sheets are linked by chains of Pb[7] atoms // [001].1 Chain structure, but with rather less bond anisotropy than Bi2S3, which is due to higher coordination of Pb (to 7S, d = 3.04 Å) & of Bi (to 6S & 7S, d = 2.89 Å); Bi thus occurs in 2 types of polyhedron, 1 having 7 vertices (BiI) & other being distorted octahedron (BiII); BiS2 chains are joined into double Bi4S8 strips extending along c axis linked together by Pb atoms.2 In Ag-free lillianite trig prism M3 is occupied only by Pb, whereas both octahedrally coordinated M1 & M2 sites are mixed (Pb,Bi) positions; same octahedra incorporate both surplus of Bi & vacancies (□) created by substitution 3Pb2+—> 2Bi3++□, which allows for observed deviations from ideal composition, Pb3Bi2S6; Se is preferentially ordered at [6]- & [5]- coordinated anionic sites, whereas [4]- coordination site S3 remains free of Se; known structural array of galenobismutite was confirmed in this work; octahedrally coordinated M1gb site was found to be a full Bi position; some evidence of Pb—Bi disorder has been observed at both M2gb (Bi-dominated) & M3gb (Pb-dominated) positions; heterogeneous distribution of Se in anionic S sites was observed in galeobismutite; atoms of Se are mainly concentrated at site S1, & less so in other anionic sites.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find GALENOBISMUTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals lath-like, elongated, flattened, needle-like; crystalline, massive
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GALENOBISMUTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Of hydrothermal originKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GALENOBISMUTITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of GALENOBISMUTITE?The standard chemical formula for GALENOBISMUTITE is PbBi2S4. This defines its elemental composition.2. Which crystal system does GALENOBISMUTITE belong to?GALENOBISMUTITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is GALENOBISMUTITE typically found in nature?The “habit” or typical appearance of GALENOBISMUTITE is described as Crystals lath-like, elongated, flattened, needle-like; crystalline, massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does GALENOBISMUTITE form?GALENOBISMUTITE is typically found in environments described as: Of hydrothermal origin. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GALENOBISMUTITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GALENOBISMUTITE, we recommend checking high-authority databases:

Final Thoughts

GALENOBISMUTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbBi2S4 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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