GATEWAYITE Mineral Details

Complete mineralogical data for GATEWAYITE. Chemical Formula: Ca6[As3+V4+3V5+9As5+6O51](H2O)8·23H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

GATEWAYITE

Ca6[As3+V4+3V5+9As5+6O51](H2O)8·23H2O

Crystal System

Monoclinic

Crystal Class

Sphenoidal

Space Group

P21

Point Group

2

Structure & Data

Crystal Structure

Interstitial unit consists of 7 isolated H2O grp, 1 insular Na(H2O)6 octahedron, & 6 Ca—O polyhedra that are either [7]- or [8]-coordinated; Ca—O polyhedra share 2, 3, 4 of their verices with O atoms of VO6 octahedra &/or AsO4 tetrahedra of structural unit; remaining verices of Ca polyhedra are H2O grp; interstitial unit, [Na (H2O)6Ca12(H2O)58.[14H2O]25+, combines with 2 [As3+V5+8.5V4+3.5As5+6O51]12.5- polyanion structural units in formula unit.

Cell Data

a=11.1850Å, b=16.8528Å, c=20.7146Å, ß=91.166o, Z=2

Geology & Identification

Geologic Occurrence

Secondary mineralization on motroseite- and corvusite-bearing sandstoneGATEWAYITEGATEWAYITE

Habit

As blades and divergent intergrowths, also crude prisms, rounded faces; composite crystals of subparallel intergrowths.

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Related to vanarsite and packratite

If you are fascinated by the hidden structures of our planet, you have likely come across GATEWAYITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GATEWAYITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GATEWAYITE is defined by the chemical formula Ca6[As3+V4+3V5+9As5+6O51](H2O)8·23H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GATEWAYITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Sphenoidal.
  • Point Group: 2
  • Space Group: P21
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Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GATEWAYITE, the dimensions of this microscopic building block are:
a=11.1850Å, b=16.8528Å, c=20.7146Å, ß=91.166o, Z=2
The internal arrangement of these atoms is described as:Interstitial unit consists of 7 isolated H2O grp, 1 insular Na(H2O)6 octahedron, & 6 Ca—O polyhedra that are either [7]- or [8]-coordinated; Ca—O polyhedra share 2, 3, 4 of their verices with O atoms of VO6 octahedra &/or AsO4 tetrahedra of structural unit; remaining verices of Ca polyhedra are H2O grp; interstitial unit, [Na (H2O)6Ca12(H2O)58.[14H2O]25+, combines with 2 [As3+V5+8.5V4+3.5As5+6O51]12.5- polyanion structural units in formula unit.This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find GATEWAYITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As blades and divergent intergrowths, also crude prisms, rounded faces; composite crystals of subparallel intergrowths.
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GATEWAYITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.
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Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineralization on motroseite- and corvusite-bearing sandstoneKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GATEWAYITE is often related to other species, either through similar chemistry or structure.Relationship Data: Related to vanarsite and packratiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of GATEWAYITE?The standard chemical formula for GATEWAYITE is Ca6[As3+V4+3V5+9As5+6O51](H2O)8·23H2O. This defines its elemental composition.2. Which crystal system does GATEWAYITE belong to?GATEWAYITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Sphenoidal class.3. How is GATEWAYITE typically found in nature?The “habit” or typical appearance of GATEWAYITE is described as As blades and divergent intergrowths, also crude prisms, rounded faces; composite crystals of subparallel intergrowths.. This refers to the shape the crystals take when they grow without obstruction.
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4. In what geological environments does GATEWAYITE form?GATEWAYITE is typically found in environments described as: Secondary mineralization on motroseite- and corvusite-bearing sandstone. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GATEWAYITE?Yes, it is often associated with or related to other minerals such as: Related to vanarsite and packratite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GATEWAYITE, we recommend checking high-authority databases:

Final Thoughts

GATEWAYITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca6[As3+V4+3V5+9As5+6O51](H2O)8·23H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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