GAULTITE Mineral Details

Complete mineralogical data for GAULTITE. Chemical Formula: Na4[Si7Zn2O18]·5H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

GAULTITE

Na4[Si7Zn2O18]·5H2O

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

F2dd

Point Group

m m 2

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with single 4-membered ring & 5 tetrahedra in 2 3-membered rings share tetrahedron (spiro-5).2 Has framework structure (VSV) consisting of ordered ZnO4 & SiO4 tetrahedra forming strongly deformed 8- & 9-membered ring channels along [101] Ercit & Van Velthuizen (1994); 8-membered ring channel is filled with chains of edge-sharing NaO6 octahedra built by framework O & H2O molecules; 9-membered ring channels host disordered Na & H2O; framework can be constructed from stacks along b of 2-D nets composed of 4- & 8-membered rings with periodic insertions of tetrahedra btw sheets; framework also has characteristic 3 membered rings formed by 2 SiO4 & on ZnO4 tetrahedra.3 There are 5 tetrahedral sites: 4 of these are occupied by Si, & 1 by Zn; polymerization of tetrahedra results in framework based on complex 3-D stacking of 4.82 Schläfli nets; Na occurs in 2 sites that represent voids in framework of tetrahedra; Na1 is [6]-coordinated & positionally ordered; Na2 is positionally disordered, split into [5]- & [6]-coordinated sites; bond-valence analysis unambiguously show 3 H2O grp, 2 of which are ordered, with ordered portions, 1 of which is disordered in agreement with results of IR spectroscopy; structure is similar to lovarite.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; gaultite zincosilicate framework of tetrahedra is typified by stacked sheets of edge-sharing 4- & 8- membered rings; sheets are cross-linked by tetrahedra; isostructural with synthetic zeolite VP1-7 & similar in structure to lovdarite.5

Cell Data

a=10.21Å, b=39.88Å, c=10.30Å, Z=8

Geology & Identification

Geologic Occurrence

A late hydrothermal mineral in alkalic pegmatites in a differentiated alkalic massifGAULTITEGAULTITE

Habit

Crystals prismatic; radial fibrous; compact, porcelaneous massive

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family

If you are fascinated by the hidden structures of our planet, you have likely come across GAULTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GAULTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GAULTITE is defined by the chemical formula Na4[Si7Zn2O18]·5H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GAULTITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: F2dd
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GAULTITE, the dimensions of this microscopic building block are:
a=10.21Å, b=39.88Å, c=10.30Å, Z=8
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with single 4-membered ring & 5 tetrahedra in 2 3-membered rings share tetrahedron (spiro-5).2 Has framework structure (VSV) consisting of ordered ZnO4 & SiO4 tetrahedra forming strongly deformed 8- & 9-membered ring channels along [101] Ercit & Van Velthuizen (1994); 8-membered ring channel is filled with chains of edge-sharing NaO6 octahedra built by framework O & H2O molecules; 9-membered ring channels host disordered Na & H2O; framework can be constructed from stacks along b of 2-D nets composed of 4- & 8-membered rings with periodic insertions of tetrahedra btw sheets; framework also has characteristic 3 membered rings formed by 2 SiO4 & on ZnO4 tetrahedra.3 There are 5 tetrahedral sites: 4 of these are occupied by Si, & 1 by Zn; polymerization of tetrahedra results in framework based on complex 3-D stacking of 4.82 Schläfli nets; Na occurs in 2 sites that represent voids in framework of tetrahedra; Na1 is [6]-coordinated & positionally ordered; Na2 is positionally disordered, split into [5]- & [6]-coordinated sites; bond-valence analysis unambiguously show 3 H2O grp, 2 of which are ordered, with ordered portions, 1 of which is disordered in agreement with results of IR spectroscopy; structure is similar to lovarite.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; gaultite zincosilicate framework of tetrahedra is typified by stacked sheets of edge-sharing 4- & 8- membered rings; sheets are cross-linked by tetrahedra; isostructural with synthetic zeolite VP1-7 & similar in structure to lovdarite.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find GAULTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals prismatic; radial fibrous; compact, porcelaneous massive
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GAULTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: A late hydrothermal mineral in alkalic pegmatites in a differentiated alkalic massifKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GAULTITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite familyUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of GAULTITE?The standard chemical formula for GAULTITE is Na4[Si7Zn2O18]·5H2O. This defines its elemental composition.
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2. Which crystal system does GAULTITE belong to?GAULTITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is GAULTITE typically found in nature?The “habit” or typical appearance of GAULTITE is described as Crystals prismatic; radial fibrous; compact, porcelaneous massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does GAULTITE form?GAULTITE is typically found in environments described as: A late hydrothermal mineral in alkalic pegmatites in a differentiated alkalic massif. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GAULTITE?Yes, it is often associated with or related to other minerals such as: Zeolite family.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GAULTITE, we recommend checking high-authority databases:

Final Thoughts

GAULTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na4[Si7Zn2O18]·5H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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