GEMINITE Mineral Details

Complete mineralogical data for GEMINITE. Chemical Formula: Cu(AsO3OH)(H2O). Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

GEMINITE

Cu(AsO3OH)(H2O)

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

C1

Point Group

1

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with medium-sized cations, RO4 :H2O = 1:1; edge sharing chains of M[6] octahedra // [001] are linked into sheets // (100) by As[4] tetrahedra.1 There are 4 unique Cu2+ sites, each coordinated by 6 anions in [4 + 2]-distorted octahedral array; this distortion of coordination polyhedra is assoc with Jahn-Teller effect; there are 4 unique As5+ sites, each coordinated by [3] O atoms OH grp in distorted tetrahedral array; 3 As—O distances are shorter than As—OH distance in each tetrahedron, in accord with prediction of bond-valence theory; CuΦ6 polyhedra share edges to form [CuΦ4] chains || to [010]; AsΦ4 tetrahedra cross-link these chains into sheets || to (001), & 2 symmetrically distinct but topologically identical sheets in structure are linked into 3-D structure by network of H—bonds, accting for prf cleavage & plate habit of geminite.2

Cell Data

a=9.84Å, b=10.82Å, c=15.73Å, α=95.71o, ß=90.94o, γ=103.11o, Z=16

Geology & Identification

Geologic Occurrence

Arsenic contamination; found on museum specimens from Nagyag and Cavnic, RomaniaGEMINITEGEMINITE

Habit

As thin lamellae; in fan-shaped aggregates

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorphous with pushcharovskite

If you are fascinated by the hidden structures of our planet, you have likely come across GEMINITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GEMINITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GEMINITE is defined by the chemical formula Cu(AsO3OH)(H2O).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GEMINITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: C1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GEMINITE, the dimensions of this microscopic building block are:
a=9.84Å, b=10.82Å, c=15.73Å, α=95.71o, ß=90.94o, γ=103.11o, Z=16
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with medium-sized cations, RO4 :H2O = 1:1; edge sharing chains of M[6] octahedra // [001] are linked into sheets // (100) by As[4] tetrahedra.1 There are 4 unique Cu2+ sites, each coordinated by 6 anions in [4 + 2]-distorted octahedral array; this distortion of coordination polyhedra is assoc with Jahn-Teller effect; there are 4 unique As5+ sites, each coordinated by [3] O atoms OH grp in distorted tetrahedral array; 3 As—O distances are shorter than As—OH distance in each tetrahedron, in accord with prediction of bond-valence theory; CuΦ6 polyhedra share edges to form [CuΦ4] chains || to [010]; AsΦ4 tetrahedra cross-link these chains into sheets || to (001), & 2 symmetrically distinct but topologically identical sheets in structure are linked into 3-D structure by network of H—bonds, accting for prf cleavage & plate habit of geminite.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find GEMINITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As thin lamellae; in fan-shaped aggregates
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GEMINITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Arsenic contamination; found on museum specimens from Nagyag and Cavnic, RomaniaKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GEMINITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorphous with pushcharovskiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of GEMINITE?The standard chemical formula for GEMINITE is Cu(AsO3OH)(H2O). This defines its elemental composition.
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2. Which crystal system does GEMINITE belong to?GEMINITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.3. How is GEMINITE typically found in nature?The “habit” or typical appearance of GEMINITE is described as As thin lamellae; in fan-shaped aggregates. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does GEMINITE form?GEMINITE is typically found in environments described as: Arsenic contamination; found on museum specimens from Nagyag and Cavnic, Romania. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GEMINITE?Yes, it is often associated with or related to other minerals such as: Dimorphous with pushcharovskite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GEMINITE, we recommend checking high-authority databases:

Final Thoughts

GEMINITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Cu(AsO3OH)(H2O) and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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