GMELINITE-Na Mineral Details

Complete mineralogical data for GMELINITE-Na. Chemical Formula: Na8[Si16Al8O48]·22H2O. Crystal System: Hexagonal. Learn about its geologic occurrence, habit, and identification.

GMELINITE-Na

Na8[Si16Al8O48]·22H2O

Crystal System

Hexagonal

Crystal Class

Dihexagonal dipyramidal

Space Group

P63/mmc

Point Group

6/m 2/m 2/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with 14-sided cages of 2 6-membered rings, 3 8-membered rings & 12 4-membered rings, called “gmelinite-type” cages; cages occupied by Na, Ca & H2O.2 Cavities & exit holes are large on acct of array of Al & Si tetrahedra; there are 2 level milarite type rings of composition (Al,Si)12 O30, which are linked together in line with rhombohedral law, result being hexagonal Si—O rings lodged by large octagonal rings; has large hexagonal channel || to c axis.3 Framework topology is based on stacking of 6-membered rings in sequence AABB….; btw like pairs of double 6-rings is gmelinite cage (GME); 6 columns of double 6-membered rings & gmelinite cages || to c-axis surround 12-member ring channel; analyses of T—O bond lengths show that there is no (Si,Al) order in 6-rings; stacking faults, interruptions of AABB…. sequence, are likely with this structure, & will disrupt channel structure; rotation of double 6-ring set by 60o gives unit of cell of chabazite (AABBCC…), which is why chabazite-Na & gmelinite-Na so commonly form intergrowths & epitaxial over-growths.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; gmelinite structure is similar to that of chabazite with which it is commonly intergrown, but gmelinite has diff stacking of double 6-membered rings; Si,Al are disordered; Ca is most abundant single extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7a,7b,8

Cell Data

a=13.756Å, c=10.048Å, Z=1

Geology & Identification

Geologic Occurrence

GMELINITE-NaGMELINITE-Na

Habit

As euhedral macro crystals: pyramidal, tabular, striated; radiating aggregates, granular (original)

Twinning

Penetration twins on {1011}, common (original)

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family, gmelinite subgroup

If you are fascinated by the hidden structures of our planet, you have likely come across GMELINITE-Na. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GMELINITE-Na. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GMELINITE-Na is defined by the chemical formula Na8[Si16Al8O48]·22H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GMELINITE-Na crystallizes in the Hexagonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dihexagonal dipyramidal.
  • Point Group: 6/m 2/m 2/m
  • Space Group: P63/mmc
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GMELINITE-Na, the dimensions of this microscopic building block are:
a=13.756Å, c=10.048Å, Z=1
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with 14-sided cages of 2 6-membered rings, 3 8-membered rings & 12 4-membered rings, called “gmelinite-type” cages; cages occupied by Na, Ca & H2O.2 Cavities & exit holes are large on acct of array of Al & Si tetrahedra; there are 2 level milarite type rings of composition (Al,Si)12 O30, which are linked together in line with rhombohedral law, result being hexagonal Si—O rings lodged by large octagonal rings; has large hexagonal channel || to c axis.3 Framework topology is based on stacking of 6-membered rings in sequence AABB….; btw like pairs of double 6-rings is gmelinite cage (GME); 6 columns of double 6-membered rings & gmelinite cages || to c-axis surround 12-member ring channel; analyses of T—O bond lengths show that there is no (Si,Al) order in 6-rings; stacking faults, interruptions of AABB…. sequence, are likely with this structure, & will disrupt channel structure; rotation of double 6-ring set by 60o gives unit of cell of chabazite (AABBCC…), which is why chabazite-Na & gmelinite-Na so commonly form intergrowths & epitaxial over-growths.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; gmelinite structure is similar to that of chabazite with which it is commonly intergrown, but gmelinite has diff stacking of double 6-membered rings; Si,Al are disordered; Ca is most abundant single extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7a,7b,8This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find GMELINITE-Na in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As euhedral macro crystals: pyramidal, tabular, striated; radiating aggregates, granular (original)
  • Twinning: Penetration twins on {1011}, common (original)
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GMELINITE-Na exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence:Knowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GMELINITE-Na is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family, gmelinite subgroupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of GMELINITE-Na?The standard chemical formula for GMELINITE-Na is Na8[Si16Al8O48]·22H2O. This defines its elemental composition.
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2. Which crystal system does GMELINITE-Na belong to?GMELINITE-Na crystallizes in the Hexagonal system. Its internal symmetry is further classified under the Dihexagonal dipyramidal class.3. How is GMELINITE-Na typically found in nature?The “habit” or typical appearance of GMELINITE-Na is described as As euhedral macro crystals: pyramidal, tabular, striated; radiating aggregates, granular (original). This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does GMELINITE-Na form?GMELINITE-Na is typically found in environments described as: . This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GMELINITE-Na?Yes, it is often associated with or related to other minerals such as: Zeolite family, gmelinite subgroup.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GMELINITE-Na, we recommend checking high-authority databases:

Final Thoughts

GMELINITE-Na is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na8[Si16Al8O48]·22H2O and a structure defined by the Hexagonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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