GRAESERITE Mineral Details

Complete mineralogical data for GRAESERITE. Chemical Formula: Fe3+4Ti3As3+O13(OH). Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

GRAESERITE

Fe3+4Ti3As3+O13(OH)

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/m

Point Group

2/m

Structure & Data

Crystal Structure

Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; arsenites, antimonites & bismuthites with add’l anions w/o H2O; zigzag chains of edge-sharing (Fe,Ti)O6 octahedra // [001] share corners with adjacent chains to form framework with cubo-octahedral cavities that lodge insular As3+O3 trig ∆; cavities are aligned // [001].2 Derbylite grp GF M3+xM4+yTO13(OH); cation site M3+ is occupied by Fe3+ & V3+ (with occasionally some Fe2+, Pb2+ & Ti4+), & M4+ site by Ti4+; both M3+ & M4+ sites are octahedrally coordinated; tetrahedrally coordinated T site is occupied by Sb3+, As3+ & occasionally Ba2+ in barian tomichite; values for stoichiometric coefficient x:y are commonly 4:3 (derbylite, tomichite & graeserite), but may also amt to 5:2 (barian tomichite).3

Cell Data

a=7.0225Å, b=14.3114Å, c=7.17431Å, ß=105.123o, Z=2

Geology & Identification

Geologic Occurrence

In cinnabar-bearing placer gravels; in microcrystalline barite and in cavities within metasomatically mineralized dolostonesGRAESERITEGRAESERITE

Habit

As prismatic crystals; in small grains

Twinning

On {011} or {153}, commonly as cruciform twins and trillings

Relationships

RELATIONSHIP TO OTHER MINERALS

Derbylite group; Fe3+ – dominant analog of tomichite; As3+ dominant analog of derbylite

If you are fascinated by the hidden structures of our planet, you have likely come across GRAESERITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GRAESERITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GRAESERITE is defined by the chemical formula Fe3+4Ti3As3+O13(OH).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GRAESERITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GRAESERITE, the dimensions of this microscopic building block are:
a=7.0225Å, b=14.3114Å, c=7.17431Å, ß=105.123o, Z=2
The internal arrangement of these atoms is described as:Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; arsenites, antimonites & bismuthites with add’l anions w/o H2O; zigzag chains of edge-sharing (Fe,Ti)O6 octahedra // [001] share corners with adjacent chains to form framework with cubo-octahedral cavities that lodge insular As3+O3 trig ∆; cavities are aligned // [001].2 Derbylite grp GF M3+xM4+yTO13(OH); cation site M3+ is occupied by Fe3+ & V3+ (with occasionally some Fe2+, Pb2+ & Ti4+), & M4+ site by Ti4+; both M3+ & M4+ sites are octahedrally coordinated; tetrahedrally coordinated T site is occupied by Sb3+, As3+ & occasionally Ba2+ in barian tomichite; values for stoichiometric coefficient x:y are commonly 4:3 (derbylite, tomichite & graeserite), but may also amt to 5:2 (barian tomichite).3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find GRAESERITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As prismatic crystals; in small grains
  • Twinning: On {011} or {153}, commonly as cruciform twins and trillings
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GRAESERITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In cinnabar-bearing placer gravels; in microcrystalline barite and in cavities within metasomatically mineralized dolostonesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GRAESERITE is often related to other species, either through similar chemistry or structure.Relationship Data: Derbylite group; Fe3+ – dominant analog of tomichite; As3+ dominant analog of derbyliteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of GRAESERITE?The standard chemical formula for GRAESERITE is Fe3+4Ti3As3+O13(OH). This defines its elemental composition.2. Which crystal system does GRAESERITE belong to?GRAESERITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.
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3. How is GRAESERITE typically found in nature?The “habit” or typical appearance of GRAESERITE is described as As prismatic crystals; in small grains. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does GRAESERITE form?GRAESERITE is typically found in environments described as: In cinnabar-bearing placer gravels; in microcrystalline barite and in cavities within metasomatically mineralized dolostones. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GRAESERITE?Yes, it is often associated with or related to other minerals such as: Derbylite group; Fe3+ – dominant analog of tomichite; As3+ dominant analog of derbylite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GRAESERITE, we recommend checking high-authority databases:

Final Thoughts

GRAESERITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Fe3+4Ti3As3+O13(OH) and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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