GUSTAVITE Mineral Details

Complete mineralogical data for GUSTAVITE. Chemical Formula: PbAgBi3S6. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

GUSTAVITE

PbAgBi3S6

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/c

Point Group

2/m

Structure & Data

Crystal Structure

Pb sulfosalts based on large 2-D fragments of PbS/SnS archetype.1 Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆ & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; galena-like slabs; Sb[3+2]S5 □∆ form chains // [001] with some chains also containing PbS6 octahedra.2 Structure contains 7 independent positions: 3 metal sites M1, M2, M3 & 4 S positions; xl structure consists of blocks of diagonal chains of 4 octahedra M1 (Bi/Ag/Sb) – M2 – M1 separated by Pb atoms in bicapped trig prismatic coordination of site M3; marginal octahedron of chains of 4 octahedra is formed by 1 mixed site M1 containing 52% Bi, 35.6% & 12.4% Sb while central M2 octahedron is mixed site containing 60.1% Sb, 25.9% Pb & 14% Bi; mixed population of M1 site results in orthorhombic symmetry, s.g. Cmcm with 4 Å a-repeat while in natural gustavite, alternating occupation of M1 site by Ag & Bi reduces symmetry to monoclinic, s.g. P21/c with 8 Å repeat; structure similar to Ag-free lillianite.3 Structure contains bicapped trig prismatic P site, [001] string of Ag & Bi1 octahedral sites & similar string of Bi2 & Bi3 coordination octahedra; Sb is concentrated in Bi3 site whereas Bi1 & Ag contain fraction of opposite species; latter is explained by prescence of twin lamellae or antiphase domains in xl; order-disorder structure that can be described by zigzag unit layers.4

Cell Data

a=7.08Å, b=19.57Å, c=8.27Å, ß=106.96o, Z=4

Geology & Identification

Geologic Occurrence

In fine-grained quartz in a vein of hydrothermal originGUSTAVITEGUSTAVITE

Habit

Crystals are long prismatic or thick lance-shaped

Twinning

Lamellar on (010)

Relationships

RELATIONSHIP TO OTHER MINERALS

Lillianite group; forms series with lillianite

If you are fascinated by the hidden structures of our planet, you have likely come across GUSTAVITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about GUSTAVITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, GUSTAVITE is defined by the chemical formula PbAgBi3S6.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. GUSTAVITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For GUSTAVITE, the dimensions of this microscopic building block are:
a=7.08Å, b=19.57Å, c=8.27Å, ß=106.96o, Z=4
The internal arrangement of these atoms is described as:
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Pb sulfosalts based on large 2-D fragments of PbS/SnS archetype.1 Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆ & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; galena-like slabs; Sb[3+2]S5 □∆ form chains // [001] with some chains also containing PbS6 octahedra.2 Structure contains 7 independent positions: 3 metal sites M1, M2, M3 & 4 S positions; xl structure consists of blocks of diagonal chains of 4 octahedra M1 (Bi/Ag/Sb) – M2 – M1 separated by Pb atoms in bicapped trig prismatic coordination of site M3; marginal octahedron of chains of 4 octahedra is formed by 1 mixed site M1 containing 52% Bi, 35.6% & 12.4% Sb while central M2 octahedron is mixed site containing 60.1% Sb, 25.9% Pb & 14% Bi; mixed population of M1 site results in orthorhombic symmetry, s.g. Cmcm with 4 Å a-repeat while in natural gustavite, alternating occupation of M1 site by Ag & Bi reduces symmetry to monoclinic, s.g. P21/c with 8 Å repeat; structure similar to Ag-free lillianite.3 Structure contains bicapped trig prismatic P site, [001] string of Ag & Bi1 octahedral sites & similar string of Bi2 & Bi3 coordination octahedra; Sb is concentrated in Bi3 site whereas Bi1 & Ag contain fraction of opposite species; latter is explained by prescence of twin lamellae or antiphase domains in xl; order-disorder structure that can be described by zigzag unit layers.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find GUSTAVITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals are long prismatic or thick lance-shaped
  • Twinning: Lamellar on (010)
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If GUSTAVITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In fine-grained quartz in a vein of hydrothermal originKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. GUSTAVITE is often related to other species, either through similar chemistry or structure.Relationship Data: Lillianite group; forms series with lillianiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of GUSTAVITE?The standard chemical formula for GUSTAVITE is PbAgBi3S6. This defines its elemental composition.
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2. Which crystal system does GUSTAVITE belong to?GUSTAVITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is GUSTAVITE typically found in nature?The “habit” or typical appearance of GUSTAVITE is described as Crystals are long prismatic or thick lance-shaped. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does GUSTAVITE form?GUSTAVITE is typically found in environments described as: In fine-grained quartz in a vein of hydrothermal origin. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to GUSTAVITE?Yes, it is often associated with or related to other minerals such as: Lillianite group; forms series with lillianite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of GUSTAVITE, we recommend checking high-authority databases:

Final Thoughts

GUSTAVITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbAgBi3S6 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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