HOPEITE Mineral Details

Complete mineralogical data for HOPEITE. Chemical Formula: Zn3(PO4)2(H2O)4. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

HOPEITE

Zn3(PO4)2(H2O)4

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pnma

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with small & large/medium cations; Zn(O,H2O)4 tetrahedra & PO4 tetrahedra share corners to form sheets of 3- & 4-membered rings // (010).2 Has 2 Zn atoms (CN = 4) & 1 Zn atom (Fe) (CN = 6, 2 O + 4 H2O; each O atom around ZnI belongs to diff PO4 tetrahedron; at 2 vertices of ZnO4 there are also 2 ZnO4 tetrahedra, which together give rise to [(Zn2O6]∞ chains along c axis; 2-layer close packing produces similarity to diaspore-goethite structure.3 Consists of ZnO3(H2O)4 octahedra, ZnO4 tetrahedra & PO4 tetrahedra, none of which are regular; these polyhedra share corners & edges.4

Cell Data

a=10.62Å, b=18.43Å, c=5.02Å, Z=4

Geology & Identification

Geologic Occurrence

Late-stage mineral in some hydrothermal Zn-deposits and complex granite pegmatites; incrusting boneHOPEITEHOPEITE

Habit

Prismatic, tabular; in divergent aggregates or as crusts; compact reinform

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Hopeite group; dimorphous with parahopeite; compare ludlamite, sterlinghillite, switzerite

If you are fascinated by the hidden structures of our planet, you have likely come across HOPEITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about HOPEITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, HOPEITE is defined by the chemical formula Zn3(PO4)2(H2O)4.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. HOPEITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pnma
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For HOPEITE, the dimensions of this microscopic building block are:
a=10.62Å, b=18.43Å, c=5.02Å, Z=4
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units w/o add’l anions with H2O with small & large/medium cations; Zn(O,H2O)4 tetrahedra & PO4 tetrahedra share corners to form sheets of 3- & 4-membered rings // (010).2 Has 2 Zn atoms (CN = 4) & 1 Zn atom (Fe) (CN = 6, 2 O + 4 H2O; each O atom around ZnI belongs to diff PO4 tetrahedron; at 2 vertices of ZnO4 there are also 2 ZnO4 tetrahedra, which together give rise to [(Zn2O6]∞ chains along c axis; 2-layer close packing produces similarity to diaspore-goethite structure.3 Consists of ZnO3(H2O)4 octahedra, ZnO4 tetrahedra & PO4 tetrahedra, none of which are regular; these polyhedra share corners & edges.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find HOPEITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic, tabular; in divergent aggregates or as crusts; compact reinform
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If HOPEITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Late-stage mineral in some hydrothermal Zn-deposits and complex granite pegmatites; incrusting boneKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. HOPEITE is often related to other species, either through similar chemistry or structure.Relationship Data: Hopeite group; dimorphous with parahopeite; compare ludlamite, sterlinghillite, switzeriteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of HOPEITE?The standard chemical formula for HOPEITE is Zn3(PO4)2(H2O)4. This defines its elemental composition.2. Which crystal system does HOPEITE belong to?HOPEITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.
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3. How is HOPEITE typically found in nature?The “habit” or typical appearance of HOPEITE is described as Prismatic, tabular; in divergent aggregates or as crusts; compact reinform. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does HOPEITE form?HOPEITE is typically found in environments described as: Late-stage mineral in some hydrothermal Zn-deposits and complex granite pegmatites; incrusting bone. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to HOPEITE?Yes, it is often associated with or related to other minerals such as: Hopeite group; dimorphous with parahopeite; compare ludlamite, sterlinghillite, switzerite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of HOPEITE, we recommend checking high-authority databases:

Final Thoughts

HOPEITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Zn3(PO4)2(H2O)4 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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