HYDROCALUMITE Mineral Details

Complete mineralogical data for HYDROCALUMITE. Chemical Formula: Ca4Al2(OH)12(Cl,CO3,OH)2·4H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

HYDROCALUMITE

Ca4Al2(OH)12(Cl,CO3,OH)2·4H2O

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P2/c

Point Group

2/m

Structure & Data

Crystal Structure

Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; OH with H2O; sheets of edge-sharing octahedra; brucite-like layers of edge-sharing Al(OH)6 & Ca(OH)6 octahedra // (001) alternate with layers containing H2O, CO3 & Cl.2 Layered structure is composed on nets of Al & Ca polyhedra; consists of OH grp & H2O molecules; these nets alternate along c axis; ½ of Al atoms have [4]-coordinations, while ½ have [6]; OH—H bonds link layers.3 3 grp of double OH minerals are typified by pyroaurite & sjögrenite (now as pyroaurite-2H), hydrocalcumite, & ettringite; all show interesting structural features; in pyroaurite-sjögrenite grp (now hydrotalcite grp), brucite-like layers carrying net + charge alternate with layers in which O atoms of carbonate grp & H2O molecules are statistically distributed on single set of sites; hydrocalumite also have layer structures in which + charged main layers alternate with intermediate layers containing anions & H2O molecules; anions occur in cavities & their nature can again vary widely (previous grp are now members of Hydrotalcite SG); in ettringite grp, structures are based on + charged columns, btw which occur channels containing anions & sometimes also H2O molecules; this grp incl thaumasite, only natural mineral known to contain Si 6-coordinated by O that is not high-pressure phase.4

Cell Data

a=10.02Å, b=11.50Å, c=16.29Å, ß=104.2o, Z=4

Geology & Identification

Geologic Occurrence

Late-stage hydrothermal mineral in skarns, from contact metamorphism of limestone, in xenoliths in lavaHYDROCALUMITEHYDROCALUMITE

Habit

Pseudoexagonal crystals, tabular; massive

Twinning

Common on {322} as contact twins

Relationships

RELATIONSHIP TO OTHER MINERALS

Hydrotalcite supergroup, hydrocalumite

If you are fascinated by the hidden structures of our planet, you have likely come across HYDROCALUMITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about HYDROCALUMITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, HYDROCALUMITE is defined by the chemical formula Ca4Al2(OH)12(Cl,CO3,OH)2·4H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. HYDROCALUMITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For HYDROCALUMITE, the dimensions of this microscopic building block are:
a=10.02Å, b=11.50Å, c=16.29Å, ß=104.2o, Z=4
The internal arrangement of these atoms is described as:
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Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; OH with H2O; sheets of edge-sharing octahedra; brucite-like layers of edge-sharing Al(OH)6 & Ca(OH)6 octahedra // (001) alternate with layers containing H2O, CO3 & Cl.2 Layered structure is composed on nets of Al & Ca polyhedra; consists of OH grp & H2O molecules; these nets alternate along c axis; ½ of Al atoms have [4]-coordinations, while ½ have [6]; OH—H bonds link layers.3 3 grp of double OH minerals are typified by pyroaurite & sjögrenite (now as pyroaurite-2H), hydrocalcumite, & ettringite; all show interesting structural features; in pyroaurite-sjögrenite grp (now hydrotalcite grp), brucite-like layers carrying net + charge alternate with layers in which O atoms of carbonate grp & H2O molecules are statistically distributed on single set of sites; hydrocalumite also have layer structures in which + charged main layers alternate with intermediate layers containing anions & H2O molecules; anions occur in cavities & their nature can again vary widely (previous grp are now members of Hydrotalcite SG); in ettringite grp, structures are based on + charged columns, btw which occur channels containing anions & sometimes also H2O molecules; this grp incl thaumasite, only natural mineral known to contain Si 6-coordinated by O that is not high-pressure phase.4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find HYDROCALUMITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Pseudoexagonal crystals, tabular; massive
  • Twinning: Common on {322} as contact twins
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If HYDROCALUMITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Late-stage hydrothermal mineral in skarns, from contact metamorphism of limestone, in xenoliths in lavaKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. HYDROCALUMITE is often related to other species, either through similar chemistry or structure.Relationship Data: Hydrotalcite supergroup, hydrocalumiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of HYDROCALUMITE?The standard chemical formula for HYDROCALUMITE is Ca4Al2(OH)12(Cl,CO3,OH)2·4H2O. This defines its elemental composition.
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2. Which crystal system does HYDROCALUMITE belong to?HYDROCALUMITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is HYDROCALUMITE typically found in nature?The “habit” or typical appearance of HYDROCALUMITE is described as Pseudoexagonal crystals, tabular; massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does HYDROCALUMITE form?HYDROCALUMITE is typically found in environments described as: Late-stage hydrothermal mineral in skarns, from contact metamorphism of limestone, in xenoliths in lava. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to HYDROCALUMITE?Yes, it is often associated with or related to other minerals such as: Hydrotalcite supergroup, hydrocalumite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of HYDROCALUMITE, we recommend checking high-authority databases:

Final Thoughts

HYDROCALUMITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca4Al2(OH)12(Cl,CO3,OH)2·4H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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