KATAYAMALITE Mineral Details

Complete mineralogical data for KATAYAMALITE. Chemical Formula: KLi3Ca7Ti2[Si6O18]2(OH)2. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

KATAYAMALITE

KLi3Ca7Ti2[Si6O18]2(OH)2

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/c

Point Group

2/m

Structure & Data

Crystal Structure

Cyclosilicates: tetrahedra are connected into rings; [Si6O18]12- 6-membered single rings w/o insular complex anions; 2 layers of Si6O18 rings // (001) connected into double layer by dense layer of Ca[6] octahedra; btw these double layers deformed K[12] polyhedron, 2 Ti[6] octahedra & 3 deformed Li[4] tetrahedra.2 Ring silicate with 2-layered structure || to (001), & consists of Si6O18 rings connected with Ca—(O,OH) octahedral sheets, & with Ti—O octahedra, Li—O tetrahedra & [12]-K polyhedra; xl structure is similar to that of baratovite; distortion in katayamalite structure results in lower symmetry of triclinic system.3 Contains set of 6-membered silicate rings interconnected by sheets of Ca atoms on 1 side & by ordered mixture of Li, Ti , K atoms on other side, forming layers which are stacked normal (001); from 8 diff metal sites, 3 are loc on special positions, viz. 1 K & 1 Li atom on [2] rotation axes & 1 Ca atom on inversion center; no or very weak H— bonding.4 Typified by layers of close-packed 6-membered rings of SiO4 tetrahedra; there are 6 non-equivalent Si atoms in structure; silicate layers (T) are connected by sheets of Ca atoms on 1 side & by ordered mixture of Li, Ti & K on other side, forming sandwich of T-Ca-T-(Li,Ti,K) layers; sandwiches in turn, are stacked in ABAC packing scheme; layer of Ca atoms is similar to brucite layer with its dangling H atoms; silicate rings are centered by K atom in 1 layer, & by H atom in other; Ca1, Ca2 & Ca3 atoms are [8]-coordinated loc on gen positions while atom Ca4 is [8]-coordinated & has 1 symmetry; Li1 lies on [2] roation axis & Li2 is at gen position; both are tetrahedrally coordinated; Ti atom is [6]-coordinated in form of octahedron & lies on gen position; K atom is loc on special position with [2] rotation symmetry; it is [12]-coordinated within distorted coordination environment.5

Cell Data

a=16.92Å, b=9.72Å, c=20.91Å, ß=112.4o, Z=4

Geology & Identification

Geologic Occurrence

In aegirine syenite with albite, aegirine, pectoliteKATAYAMALITEKATAYAMALITE

Habit

As tabular crystals

Twinning

Frequent on {001}

Relationships

RELATIONSHIP TO OTHER MINERALS

(OH) – analog of baratovite

If you are fascinated by the hidden structures of our planet, you have likely come across KATAYAMALITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about KATAYAMALITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, KATAYAMALITE is defined by the chemical formula KLi3Ca7Ti2[Si6O18]2(OH)2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. KATAYAMALITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For KATAYAMALITE, the dimensions of this microscopic building block are:
a=16.92Å, b=9.72Å, c=20.91Å, ß=112.4o, Z=4
The internal arrangement of these atoms is described as:
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Cyclosilicates: tetrahedra are connected into rings; [Si6O18]12- 6-membered single rings w/o insular complex anions; 2 layers of Si6O18 rings // (001) connected into double layer by dense layer of Ca[6] octahedra; btw these double layers deformed K[12] polyhedron, 2 Ti[6] octahedra & 3 deformed Li[4] tetrahedra.2 Ring silicate with 2-layered structure || to (001), & consists of Si6O18 rings connected with Ca—(O,OH) octahedral sheets, & with Ti—O octahedra, Li—O tetrahedra & [12]-K polyhedra; xl structure is similar to that of baratovite; distortion in katayamalite structure results in lower symmetry of triclinic system.3 Contains set of 6-membered silicate rings interconnected by sheets of Ca atoms on 1 side & by ordered mixture of Li, Ti , K atoms on other side, forming layers which are stacked normal (001); from 8 diff metal sites, 3 are loc on special positions, viz. 1 K & 1 Li atom on [2] rotation axes & 1 Ca atom on inversion center; no or very weak H— bonding.4 Typified by layers of close-packed 6-membered rings of SiO4 tetrahedra; there are 6 non-equivalent Si atoms in structure; silicate layers (T) are connected by sheets of Ca atoms on 1 side & by ordered mixture of Li, Ti & K on other side, forming sandwich of T-Ca-T-(Li,Ti,K) layers; sandwiches in turn, are stacked in ABAC packing scheme; layer of Ca atoms is similar to brucite layer with its dangling H atoms; silicate rings are centered by K atom in 1 layer, & by H atom in other; Ca1, Ca2 & Ca3 atoms are [8]-coordinated loc on gen positions while atom Ca4 is [8]-coordinated & has 1 symmetry; Li1 lies on [2] roation axis & Li2 is at gen position; both are tetrahedrally coordinated; Ti atom is [6]-coordinated in form of octahedron & lies on gen position; K atom is loc on special position with [2] rotation symmetry; it is [12]-coordinated within distorted coordination environment.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find KATAYAMALITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As tabular crystals
  • Twinning: Frequent on {001}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If KATAYAMALITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In aegirine syenite with albite, aegirine, pectoliteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. KATAYAMALITE is often related to other species, either through similar chemistry or structure.Relationship Data: (OH) – analog of baratoviteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of KATAYAMALITE?The standard chemical formula for KATAYAMALITE is KLi3Ca7Ti2[Si6O18]2(OH)2. This defines its elemental composition.2. Which crystal system does KATAYAMALITE belong to?KATAYAMALITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is KATAYAMALITE typically found in nature?The “habit” or typical appearance of KATAYAMALITE is described as As tabular crystals. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does KATAYAMALITE form?KATAYAMALITE is typically found in environments described as: In aegirine syenite with albite, aegirine, pectolite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to KATAYAMALITE?Yes, it is often associated with or related to other minerals such as: (OH) – analog of baratovite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of KATAYAMALITE, we recommend checking high-authority databases:

Final Thoughts

KATAYAMALITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of KLi3Ca7Ti2[Si6O18]2(OH)2 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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