KHADEMITE Mineral Details

Complete mineralogical data for KHADEMITE. Chemical Formula: Al(SO4)F(H2O)4·H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

KHADEMITE

Al(SO4)F(H2O)4·H2O

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pcab

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing with add’l anions with H2O with medium-sized cations, insular octahedra & finite grps of octahedra; insular Al(H2O)6 & Al(H2O)4F2 octahedra & insular SO4 tetrahedra linked by network of H—bonds.1 Xl structure is typified by alternation, along b, of 2 distinct kinds of {010} layers, 1 formed by [001] rows of isolated Al-centered octahedra, connected to each other thru H—bonds, & other showing isolated SO4 grp; along b, O atoms belonging to SO4 grp act as acceptor of H—bonds from H2O grp coordinating Al atoms; new data improved depscription of H— bonds in khademite leads to possible existence of its (OH)-analog, rostite.2

Cell Data

a=11.18Å, b=13.05Å, c=10.89Å, Z=8

Geology & Identification

Geologic Occurrence

Formed in oxidized zone of hydrothermal base-metal depositsKHADEMITEKHADEMITE

Habit

Tabular crystals; may form thick crusts

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

F-analog of rostite

If you are fascinated by the hidden structures of our planet, you have likely come across KHADEMITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about KHADEMITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, KHADEMITE is defined by the chemical formula Al(SO4)F(H2O)4·H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. KHADEMITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pcab
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For KHADEMITE, the dimensions of this microscopic building block are:
a=11.18Å, b=13.05Å, c=10.89Å, Z=8
The internal arrangement of these atoms is described as:Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing with add’l anions with H2O with medium-sized cations, insular octahedra & finite grps of octahedra; insular Al(H2O)6 & Al(H2O)4F2 octahedra & insular SO4 tetrahedra linked by network of H—bonds.1 Xl structure is typified by alternation, along b, of 2 distinct kinds of {010} layers, 1 formed by [001] rows of isolated Al-centered octahedra, connected to each other thru H—bonds, & other showing isolated SO4 grp; along b, O atoms belonging to SO4 grp act as acceptor of H—bonds from H2O grp coordinating Al atoms; new data improved depscription of H— bonds in khademite leads to possible existence of its (OH)-analog, rostite.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find KHADEMITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Tabular crystals; may form thick crusts
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If KHADEMITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Formed in oxidized zone of hydrothermal base-metal depositsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. KHADEMITE is often related to other species, either through similar chemistry or structure.Relationship Data: F-analog of rostiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of KHADEMITE?The standard chemical formula for KHADEMITE is Al(SO4)F(H2O)4·H2O. This defines its elemental composition.2. Which crystal system does KHADEMITE belong to?KHADEMITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.
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3. How is KHADEMITE typically found in nature?The “habit” or typical appearance of KHADEMITE is described as Tabular crystals; may form thick crusts. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does KHADEMITE form?KHADEMITE is typically found in environments described as: Formed in oxidized zone of hydrothermal base-metal deposits. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to KHADEMITE?Yes, it is often associated with or related to other minerals such as: F-analog of rostite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of KHADEMITE, we recommend checking high-authority databases:

Final Thoughts

KHADEMITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Al(SO4)F(H2O)4·H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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