KRENNERITE Mineral Details

Complete mineralogical data for KRENNERITE. Chemical Formula: Au3AgTe8. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

KRENNERITE

Au3AgTe8

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Pma2

Point Group

m m 2

Structure & Data

Crystal Structure

Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); metal tellurides, M:X = 1:2; sheets of AuTe6 octahedra // (001) linked by Te3 grp, Te2 dumbbells & individual Te atoms.1 3 Au—Ag sites in structured are ordered, Ag=43% occupancy at Au1 (2a) position (point symmetry 2) & 59% at Au2 (2c) position (point symmetry m); Au3 (4d) position (point symmetry 1) is 100% Au.2 Submolecular with AuTe2 grp || to b axis & another 4 Te atoms much further way giving distorted octahedron around Au; environments of Te are 3Au + Te or 5Au + 1Te or 1Au + 5Te; mean interatomic distances are Au—Te6 = 2.65 Å & 3.02 Å (4); Te—Te = 3.02—3.54 Å.3 In krennerite & sylvanite compared with prototype structure of calaverite (incommensurately modulated at ambient conditions), neither krennerite nor sylvanite present any modulation; due to presence of relatively strong Te—Te bonds; in both tellurides, trivalent Au occurs in slightly distorted □ planar coordination, whereas monovalent gold, parly substituted by monovalent Ag, presents 2+2+2 coordination, corresponding to distorted rhombic bi-∆; differentiation btw bonding & non-bonding contacts is obtained by computation of Effective Coordination Number; charge distribution analysis is satisfactory for both tellurides but suggests that Te—Te bond in [Te3]2- anion is not entirely homopolar; both tellurides can be described as Madelung-type compounds.

Cell Data

a=16.58Å, b=8.85Å, c=4.46Å, Z=8

Geology & Identification

Geologic Occurrence

Found in hydrothermal veins with other telluridesKRENNERITEKRENNERITE

Habit

Short prismatic crystals, striated

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorphous with calaverite

If you are fascinated by the hidden structures of our planet, you have likely come across KRENNERITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about KRENNERITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, KRENNERITE is defined by the chemical formula Au3AgTe8.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. KRENNERITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Pma2
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For KRENNERITE, the dimensions of this microscopic building block are:
a=16.58Å, b=8.85Å, c=4.46Å, Z=8
The internal arrangement of these atoms is described as:Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); metal tellurides, M:X = 1:2; sheets of AuTe6 octahedra // (001) linked by Te3 grp, Te2 dumbbells & individual Te atoms.1 3 Au—Ag sites in structured are ordered, Ag=43% occupancy at Au1 (2a) position (point symmetry 2) & 59% at Au2 (2c) position (point symmetry m); Au3 (4d) position (point symmetry 1) is 100% Au.2 Submolecular with AuTe2 grp || to b axis & another 4 Te atoms much further way giving distorted octahedron around Au; environments of Te are 3Au + Te or 5Au + 1Te or 1Au + 5Te; mean interatomic distances are Au—Te6 = 2.65 Å & 3.02 Å (4); Te—Te = 3.02—3.54 Å.3 In krennerite & sylvanite compared with prototype structure of calaverite (incommensurately modulated at ambient conditions), neither krennerite nor sylvanite present any modulation; due to presence of relatively strong Te—Te bonds; in both tellurides, trivalent Au occurs in slightly distorted □ planar coordination, whereas monovalent gold, parly substituted by monovalent Ag, presents 2+2+2 coordination, corresponding to distorted rhombic bi-∆; differentiation btw bonding & non-bonding contacts is obtained by computation of Effective Coordination Number; charge distribution analysis is satisfactory for both tellurides but suggests that Te—Te bond in [Te3]2- anion is not entirely homopolar; both tellurides can be described as Madelung-type compounds.This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find KRENNERITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short prismatic crystals, striated
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If KRENNERITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Found in hydrothermal veins with other telluridesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. KRENNERITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorphous with calaveriteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of KRENNERITE?The standard chemical formula for KRENNERITE is Au3AgTe8. This defines its elemental composition.
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2. Which crystal system does KRENNERITE belong to?KRENNERITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is KRENNERITE typically found in nature?The “habit” or typical appearance of KRENNERITE is described as Short prismatic crystals, striated. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does KRENNERITE form?KRENNERITE is typically found in environments described as: Found in hydrothermal veins with other tellurides. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to KRENNERITE?Yes, it is often associated with or related to other minerals such as: Dimorphous with calaverite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of KRENNERITE, we recommend checking high-authority databases:

Final Thoughts

KRENNERITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Au3AgTe8 and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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