KRIVOVICHEVITE Mineral Details

Complete mineralogical data for KRIVOVICHEVITE. Chemical Formula: Pb3Al(SO4)(OH)7. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

KRIVOVICHEVITE

Pb3Al(SO4)(OH)7

Crystal System

Hexagonal-Trigonal

Crystal Class

Ditrigonal pyramidal

Space Group

R3c

Point Group

3 m

Structure & Data

Crystal Structure

Contains 1 symmetrically unique Pb position coordinated by [4] OH grp & [3] O atoms; coordination of Pb2+ cation is highly asymmetrical owing to localized 6s2 lone pairs of electrons; on 1 side Pb2+ cation is coordinated by [3] OH grp; form short Pb2+—OH bonds; resulting Pb(OH)3 configuration is complemented by 1 intermediate Pb2+-OH bonds & 3 longer Pb2+—Ø bonds (Ø = O,OH); 1 Al3+ cation coordinated by 6 OH grp to form isolated Al(OH)63- octahedra; 1 symmetrically independent S6+ cation is coordinated by [4] O2- anions to form SO42- sulfate tetrahedra; structure based upon layers of Pb2+ cations & OH- grp A separated by layers of Al(OH)63- octahedra & SO42- tetrahedra B; A layer is hexagonal array of Pb consisting of Pb3 triangles with every 6 triangle centered in OH- grp; sheets stacked in sequence …ABAB…; stacking sequence of Pb sheets corresponds to hexagonal close-packing sequence…ababab…; stacking sequence of Al sulfate sheets is cubic close-packing sequence …abcabc…; combination of these 2 stacking sequence to 12-layer sequence ….AaBaAbBbAaBcAbBaAaBbAbBc…, where Mn (M=A,B; n=a,b,c) corresonds to M sheet in n position.

Cell Data

a=7.69Å, c=31.57Å, Z=6

Geology & Identification

Geologic Occurrence

Low-temperature hydrothermal alteration product of galena; in natrolite-aegirine-orthoclase vein within lujavriteKRIVOVICHEVITEKRIVOVICHEVITE

Habit

Equant grains within galena aggregates

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare alunite group minerals

If you are fascinated by the hidden structures of our planet, you have likely come across KRIVOVICHEVITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about KRIVOVICHEVITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, KRIVOVICHEVITE is defined by the chemical formula Pb3Al(SO4)(OH)7.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. KRIVOVICHEVITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Ditrigonal pyramidal.
  • Point Group: 3 m
  • Space Group: R3c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For KRIVOVICHEVITE, the dimensions of this microscopic building block are:
a=7.69Å, c=31.57Å, Z=6
The internal arrangement of these atoms is described as:Contains 1 symmetrically unique Pb position coordinated by [4] OH grp & [3] O atoms; coordination of Pb2+ cation is highly asymmetrical owing to localized 6s2 lone pairs of electrons; on 1 side Pb2+ cation is coordinated by [3] OH grp; form short Pb2+—OH bonds; resulting Pb(OH)3 configuration is complemented by 1 intermediate Pb2+-OH bonds & 3 longer Pb2+—Ø bonds (Ø = O,OH); 1 Al3+ cation coordinated by 6 OH grp to form isolated Al(OH)63- octahedra; 1 symmetrically independent S6+ cation is coordinated by [4] O2- anions to form SO42- sulfate tetrahedra; structure based upon layers of Pb2+ cations & OH- grp A separated by layers of Al(OH)63- octahedra & SO42- tetrahedra B; A layer is hexagonal array of Pb consisting of Pb3 triangles with every 6 triangle centered in OH- grp; sheets stacked in sequence …ABAB…; stacking sequence of Pb sheets corresponds to hexagonal close-packing sequence…ababab…; stacking sequence of Al sulfate sheets is cubic close-packing sequence …abcabc…; combination of these 2 stacking sequence to 12-layer sequence ….AaBaAbBbAaBcAbBaAaBbAbBc…, where Mn (M=A,B; n=a,b,c) corresonds to M sheet in n position.This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find KRIVOVICHEVITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Equant grains within galena aggregates
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If KRIVOVICHEVITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Low-temperature hydrothermal alteration product of galena; in natrolite-aegirine-orthoclase vein within lujavriteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. KRIVOVICHEVITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare alunite group mineralsUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of KRIVOVICHEVITE?The standard chemical formula for KRIVOVICHEVITE is Pb3Al(SO4)(OH)7. This defines its elemental composition.2. Which crystal system does KRIVOVICHEVITE belong to?KRIVOVICHEVITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Ditrigonal pyramidal class.
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3. How is KRIVOVICHEVITE typically found in nature?The “habit” or typical appearance of KRIVOVICHEVITE is described as Equant grains within galena aggregates. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does KRIVOVICHEVITE form?KRIVOVICHEVITE is typically found in environments described as: Low-temperature hydrothermal alteration product of galena; in natrolite-aegirine-orthoclase vein within lujavrite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to KRIVOVICHEVITE?Yes, it is often associated with or related to other minerals such as: Compare alunite group minerals.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of KRIVOVICHEVITE, we recommend checking high-authority databases:

Final Thoughts

KRIVOVICHEVITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb3Al(SO4)(OH)7 and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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