LAUTITE Mineral Details

Complete mineralogical data for LAUTITE. Chemical Formula: CuAsS. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

LAUTITE

CuAsS

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Pna21

Point Group

m m 2

Structure & Data

Crystal Structure

Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); metal sulfides, M:X = 1:1; sphalerite-like linking of Cu[AsS3], As[CuAs2S] & S[Cu3As] tetrahedra, but with distinct zigzag As—As chains along [100].1 Derived from sphalerite structure, on acct of [4]-coordination, there is prominent pattern of As—Cu—S zigzag chains along a axis; stronger covalent As—S bonds indicate As2S2 anions in these chains.2 Centrosymmetric structural model reported previously was confirmed, with atomic coordinates inter-atomic distances; lautite shows sphalerite-derivtive structure [(3)], As[CuAs(2)S] & S[Cu(3)As] tetrahedra; all atoms lie on special positions (Wyckoff position).5 Consisting of chains of 2 diff alternating motifs: 1 is [Fe(1)O4 (OH)]6-, other [Fe(2)O2(OH)(OH2)2]2-; chains are linked by phosphate grp into sheets || to (010); sheets of composition [FePO4(OH)(OH2)]1- are connected by coordination octa-hedra around Mn2+ atoms & form 3-D framework of composition MnFe23+ (PO4)2(OH)2 (OH2)6; remaining H2O molecules are not coordinated to cation so that chemical formula is same as for pseudolaueite: MnFe23+(PO4)2 (OH)(OH2)6. 2H2O.4 Pseudo-laueite & laeite Xl structures have as common feature infinite chains of corner-linked Fe-coordination octahedra; way in which these chains are linked by phospate grp & Mn-coordination octahedra into 3-D frameworks are topologically distance; details of distortions of coordination octahedra can be acct for by extended electrostatic valence rule, provided 1 considers contributions of H atoms; it is proposed that pseudolaueite & laueite are not true polymorphs because laueite contains appreciable amt of Mn3+ in Mn-site.5

Cell Data

a=11.35Å, b=5.46Å, c=3.75Å, Z=4

Geology & Identification

Geologic Occurrence

In hydrothermal veins formed at moderate temperaturesLAUTITELAUTITE

Habit

As crystals, short prismatic, tabular, striated; massive, fine granular, radiating

Twinning

On {110}

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across LAUTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about LAUTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, LAUTITE is defined by the chemical formula CuAsS.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. LAUTITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Pna21
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For LAUTITE, the dimensions of this microscopic building block are:
a=11.35Å, b=5.46Å, c=3.75Å, Z=4
The internal arrangement of these atoms is described as:
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Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); metal sulfides, M:X = 1:1; sphalerite-like linking of Cu[AsS3], As[CuAs2S] & S[Cu3As] tetrahedra, but with distinct zigzag As—As chains along [100].1 Derived from sphalerite structure, on acct of [4]-coordination, there is prominent pattern of As—Cu—S zigzag chains along a axis; stronger covalent As—S bonds indicate As2S2 anions in these chains.2 Centrosymmetric structural model reported previously was confirmed, with atomic coordinates inter-atomic distances; lautite shows sphalerite-derivtive structure [(3)], As[CuAs(2)S] & S[Cu(3)As] tetrahedra; all atoms lie on special positions (Wyckoff position).5 Consisting of chains of 2 diff alternating motifs: 1 is [Fe(1)O4 (OH)]6-, other [Fe(2)O2(OH)(OH2)2]2-; chains are linked by phosphate grp into sheets || to (010); sheets of composition [FePO4(OH)(OH2)]1- are connected by coordination octa-hedra around Mn2+ atoms & form 3-D framework of composition MnFe23+ (PO4)2(OH)2 (OH2)6; remaining H2O molecules are not coordinated to cation so that chemical formula is same as for pseudolaueite: MnFe23+(PO4)2 (OH)(OH2)6. 2H2O.4 Pseudo-laueite & laeite Xl structures have as common feature infinite chains of corner-linked Fe-coordination octahedra; way in which these chains are linked by phospate grp & Mn-coordination octahedra into 3-D frameworks are topologically distance; details of distortions of coordination octahedra can be acct for by extended electrostatic valence rule, provided 1 considers contributions of H atoms; it is proposed that pseudolaueite & laueite are not true polymorphs because laueite contains appreciable amt of Mn3+ in Mn-site.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find LAUTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As crystals, short prismatic, tabular, striated; massive, fine granular, radiating
  • Twinning: On {110}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If LAUTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In hydrothermal veins formed at moderate temperaturesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. LAUTITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of LAUTITE?The standard chemical formula for LAUTITE is CuAsS. This defines its elemental composition.
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2. Which crystal system does LAUTITE belong to?LAUTITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is LAUTITE typically found in nature?The “habit” or typical appearance of LAUTITE is described as As crystals, short prismatic, tabular, striated; massive, fine granular, radiating. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does LAUTITE form?LAUTITE is typically found in environments described as: In hydrothermal veins formed at moderate temperatures. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to LAUTITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of LAUTITE, we recommend checking high-authority databases:

Final Thoughts

LAUTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of CuAsS and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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