LEGRANDITE Mineral Details

Complete mineralogical data for LEGRANDITE. Chemical Formula: Zn2(AsO4)(OH)·H2O. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

LEGRANDITE

Zn2(AsO4)(OH)·H2O

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/c

Point Group

2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with medium-sized cations, (OH, etc.):RO4 = 1:1 < 2:1; edge-sharing Zn[6] octahedra form chains // [100] linked by corner-sharing AsO4 tetrahedra & Zn[5] trig di-∆.1 Arsenate grp are tetrahedrally coordinated & Zn atoms are [4]- [6]-coordinated by O; structure contains infinite, undulating, edge-sharing chain of Zn polyhedra || to a axis which is weakened once per repeat unit by presence of 2.99 Å Zn—O bond; arsenate tetrahedra share apices with Zn polyhedra & serve to link chains together.2 Heteropolyhedral frameork of (AsO4) tetrahedra, (ZnΦ5) □-∆, & (ZnΦ6) octahedra [Φ = O,(OH), H2O with extensive H-bonding across its interstices]; all H positions were loc, all H—bonds were assigned, & H…O distances are in reasonable accord with published reaction btw O—H stretching frequencey & H….O bond length.3

Cell Data

a=12.80Å, b=7.93Å, c=10.21Å, ß=104.4o, Z=8

Geology & Identification

Geologic Occurrence

Secondary mineral in oxidized zone of Zn-As bearing deposits; granite pegmatiteLEGRANDITELEGRANDITE

Habit

As prismatic macro crystals, elongated, striated; typically in sprays or sheaflike aggregates

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across LEGRANDITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about LEGRANDITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, LEGRANDITE is defined by the chemical formula Zn2(AsO4)(OH)·H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. LEGRANDITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For LEGRANDITE, the dimensions of this microscopic building block are:
a=12.80Å, b=7.93Å, c=10.21Å, ß=104.4o, Z=8
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with medium-sized cations, (OH, etc.):RO4 = 1:1 < 2:1; edge-sharing Zn[6] octahedra form chains // [100] linked by corner-sharing AsO4 tetrahedra & Zn[5] trig di-∆.1 Arsenate grp are tetrahedrally coordinated & Zn atoms are [4]- [6]-coordinated by O; structure contains infinite, undulating, edge-sharing chain of Zn polyhedra || to a axis which is weakened once per repeat unit by presence of 2.99 Å Zn—O bond; arsenate tetrahedra share apices with Zn polyhedra & serve to link chains together.2 Heteropolyhedral frameork of (AsO4) tetrahedra, (ZnΦ5) □-∆, & (ZnΦ6) octahedra [Φ = O,(OH), H2O with extensive H-bonding across its interstices]; all H positions were loc, all H—bonds were assigned, & H…O distances are in reasonable accord with published reaction btw O—H stretching frequencey & H....O bond length.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find LEGRANDITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As prismatic macro crystals, elongated, striated; typically in sprays or sheaflike aggregates
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If LEGRANDITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary mineral in oxidized zone of Zn-As bearing deposits; granite pegmatiteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. LEGRANDITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of LEGRANDITE?The standard chemical formula for LEGRANDITE is Zn2(AsO4)(OH)·H2O. This defines its elemental composition.2. Which crystal system does LEGRANDITE belong to?LEGRANDITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.
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3. How is LEGRANDITE typically found in nature?The “habit” or typical appearance of LEGRANDITE is described as As prismatic macro crystals, elongated, striated; typically in sprays or sheaflike aggregates. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does LEGRANDITE form?LEGRANDITE is typically found in environments described as: Secondary mineral in oxidized zone of Zn-As bearing deposits; granite pegmatite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to LEGRANDITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of LEGRANDITE, we recommend checking high-authority databases:

Final Thoughts

LEGRANDITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Zn2(AsO4)(OH)·H2O and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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