LIVINGSTONITE Mineral Details

Complete mineralogical data for LIVINGSTONITE. Chemical Formula: HgSb4S6(S2). Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

LIVINGSTONITE

HgSb4S6(S2)

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

A2/a

Point Group

2/m

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi represent FBB in structure with 3 S atoms forming base of ∆ & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; SnS archetype, deformed (As, Sb, Bi)S6 octahedra with distinct (As, Sb, Bi)S3 ∆; [Sb2S4]10 chains anlog [010]; 2 kinds of sheets // (001); in 1 sheet chains are linked by Hg[6] in order by covalent S—S bonding.1 Corrugated layers involving ∆ SbS2 grp; very distorted HgS8 octahedra, & S2 radicals; layers are of 2 types: in one paired SbS3 grp alternate with HgS5 octahedra & form layers of composition HgSb2S4; while in other these same grp alternate with S2 radicals & form layer of composition Sb2S2(S2).2 There are 2 kinds of layers, both running || to (001); 2 Sb2S4 double chains are joined together by S—S bond to form S2 grp; in other 2 Sb2S4 double chains are cemented togethr by Hg atoms; each Sb atom has 3 closest neighboring S atoms, & 4 add’l ones at greater distances; coordination of Hg atom is distorted octahedron of 6 S atoms, of which 2 are strongly bonded & are arranged in linear way as found in cinnabar.3 Structure redetermined based on HgSb4S8; there is S2 grp with S—S, which gives rise to add’l S atom in new formula; there are 2 kinds of layers running || to c axis; S—S bonds joins 2 Sb2S4 double chains; other Sb2S4 double chains are joined together by Hg atoms; bonds between these 2 double chains are weak & explain presence of prf cleavage || (001); coordination of Hg atoms is octahedral; 2 of S atoms are strongly & linearly bonded, as in cinnabar; there are 4 independent Sb atoms in structure; 2 of them have coordination of 4 S atoms which could be described as distorted trig ∆ plus 1 add’l S atom; other 2 Sb atoms have □∆ coordination & familiar trig ∆ coordination.4 Belongs to rod-layers structures; in type of layer, 2 double Sb2S4 chains are bound by disulfide grp [S2]2-(S—S 2.078(2) Å; in other type these chains are bound via Hg2+ cations; xllographic analysis con-firmed existaenc of independent pseudotranslational ordering in cation & anion matrices, which is character-istic of lozenge-like structures of sulfides & sulfosalts.5

Cell Data

a=30.57Å, b=4.00Å, c=21.47Å, ß=103.4o, Z=8

Geology & Identification

Geologic Occurrence

In low-temperature hydrothermal veinsLIVINGSTONITELIVINGSTONITE

Habit

As elongated macro needles; fibrous, massive, columnar, globular masses, interlaced needles

Twinning

Gliding postulated; polysynthetic, polished section

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across LIVINGSTONITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about LIVINGSTONITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, LIVINGSTONITE is defined by the chemical formula HgSb4S6(S2).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. LIVINGSTONITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: A2/a
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For LIVINGSTONITE, the dimensions of this microscopic building block are:
a=30.57Å, b=4.00Å, c=21.47Å, ß=103.4o, Z=8
The internal arrangement of these atoms is described as:
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Typified by presence of trig ∆ of As, Sb, Bi represent FBB in structure with 3 S atoms forming base of ∆ & metalloids As, Sb, Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; SnS archetype, deformed (As, Sb, Bi)S6 octahedra with distinct (As, Sb, Bi)S3 ∆; [Sb2S4]10 chains anlog [010]; 2 kinds of sheets // (001); in 1 sheet chains are linked by Hg[6] in order by covalent S—S bonding.1 Corrugated layers involving ∆ SbS2 grp; very distorted HgS8 octahedra, & S2 radicals; layers are of 2 types: in one paired SbS3 grp alternate with HgS5 octahedra & form layers of composition HgSb2S4; while in other these same grp alternate with S2 radicals & form layer of composition Sb2S2(S2).2 There are 2 kinds of layers, both running || to (001); 2 Sb2S4 double chains are joined together by S—S bond to form S2 grp; in other 2 Sb2S4 double chains are cemented togethr by Hg atoms; each Sb atom has 3 closest neighboring S atoms, & 4 add’l ones at greater distances; coordination of Hg atom is distorted octahedron of 6 S atoms, of which 2 are strongly bonded & are arranged in linear way as found in cinnabar.3 Structure redetermined based on HgSb4S8; there is S2 grp with S—S, which gives rise to add’l S atom in new formula; there are 2 kinds of layers running || to c axis; S—S bonds joins 2 Sb2S4 double chains; other Sb2S4 double chains are joined together by Hg atoms; bonds between these 2 double chains are weak & explain presence of prf cleavage || (001); coordination of Hg atoms is octahedral; 2 of S atoms are strongly & linearly bonded, as in cinnabar; there are 4 independent Sb atoms in structure; 2 of them have coordination of 4 S atoms which could be described as distorted trig ∆ plus 1 add’l S atom; other 2 Sb atoms have □∆ coordination & familiar trig ∆ coordination.4 Belongs to rod-layers structures; in type of layer, 2 double Sb2S4 chains are bound by disulfide grp [S2]2-(S—S 2.078(2) Å; in other type these chains are bound via Hg2+ cations; xllographic analysis con-firmed existaenc of independent pseudotranslational ordering in cation & anion matrices, which is character-istic of lozenge-like structures of sulfides & sulfosalts.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find LIVINGSTONITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: As elongated macro needles; fibrous, massive, columnar, globular masses, interlaced needles
  • Twinning: Gliding postulated; polysynthetic, polished section
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If LIVINGSTONITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In low-temperature hydrothermal veinsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. LIVINGSTONITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of LIVINGSTONITE?The standard chemical formula for LIVINGSTONITE is HgSb4S6(S2). This defines its elemental composition.2. Which crystal system does LIVINGSTONITE belong to?LIVINGSTONITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is LIVINGSTONITE typically found in nature?The “habit” or typical appearance of LIVINGSTONITE is described as As elongated macro needles; fibrous, massive, columnar, globular masses, interlaced needles. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does LIVINGSTONITE form?LIVINGSTONITE is typically found in environments described as: In low-temperature hydrothermal veins. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to LIVINGSTONITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of LIVINGSTONITE, we recommend checking high-authority databases:

Final Thoughts

LIVINGSTONITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of HgSb4S6(S2) and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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