LUDLOCKITE Mineral Details

Complete mineralogical data for LUDLOCKITE. Chemical Formula: PbFe3+4(As3+5O11)2. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

LUDLOCKITE

PbFe3+4(As3+5O11)2

Crystal System

Triclinic

Crystal Class

Pinacoidal

Space Group

A1

Point Group

1

Structure & Data

Crystal Structure

Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; arsenites, antimonites & bismuthites w/o add’l anions or H2O; 2 chains // [100] of edge-sharing FeO6 octahedra share edges along [010] to form strips along [100]; strips connected into sheets // (001) by PbO8 triangular dodecahedra; conrner-sharing AsO3 trig ∆ form convoluted linear As5O11 grp attached to both sides of sheets.1 Unit cell is A-centered; there is 1 unique Pb position that is [8]-coordinated by O in triangular dodecahedral array; there are 4 Fe3+ positions, each surrounded by distorted octahedral array of O atoms; there are 10 As3+ ∆ coordination with stereoative lone-pair of electrons; structural unit consists of sheet of edge-sharing FeO6 octahedra & PbO8 triangular dodecahedra embraced by convoluted but topologically linear [As3O11] grp; this sheet is || to (001), & adjacent sheets stack along [001]; there are no interstitial species, & interaction btw adjacent sheets is very weak, acct for prf cleavage.2

Cell Data

a=10.43Å, b=12.07Å, c=18.35Å, α=101.8o, ß=100.2o,γ =90.6o, Z=4

Geology & Identification

Geologic Occurrence

In sulfide ore from a complex polymetallic hydrothermal ore depositLUDLOCKITELUDLOCKITE

Habit

Simply terminated laths, elongated, flattened; rare macro prismatic; slightly twisted, divergent bundles, hairlike

Twinning

Lamellar twinning on {011}, common

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare karibibite

If you are fascinated by the hidden structures of our planet, you have likely come across LUDLOCKITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about LUDLOCKITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, LUDLOCKITE is defined by the chemical formula PbFe3+4(As3+5O11)2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. LUDLOCKITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pinacoidal.
  • Point Group: 1
  • Space Group: A1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For LUDLOCKITE, the dimensions of this microscopic building block are:
a=10.43Å, b=12.07Å, c=18.35Å, α=101.8o, ß=100.2o,γ =90.6o, Z=4
The internal arrangement of these atoms is described as:Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; arsenites, antimonites & bismuthites w/o add’l anions or H2O; 2 chains // [100] of edge-sharing FeO6 octahedra share edges along [010] to form strips along [100]; strips connected into sheets // (001) by PbO8 triangular dodecahedra; conrner-sharing AsO3 trig ∆ form convoluted linear As5O11 grp attached to both sides of sheets.1 Unit cell is A-centered; there is 1 unique Pb position that is [8]-coordinated by O in triangular dodecahedral array; there are 4 Fe3+ positions, each surrounded by distorted octahedral array of O atoms; there are 10 As3+ ∆ coordination with stereoative lone-pair of electrons; structural unit consists of sheet of edge-sharing FeO6 octahedra & PbO8 triangular dodecahedra embraced by convoluted but topologically linear [As3O11] grp; this sheet is || to (001), & adjacent sheets stack along [001]; there are no interstitial species, & interaction btw adjacent sheets is very weak, acct for prf cleavage.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find LUDLOCKITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Simply terminated laths, elongated, flattened; rare macro prismatic; slightly twisted, divergent bundles, hairlike
  • Twinning: Lamellar twinning on {011}, common
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If LUDLOCKITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In sulfide ore from a complex polymetallic hydrothermal ore depositKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. LUDLOCKITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare karibibiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of LUDLOCKITE?The standard chemical formula for LUDLOCKITE is PbFe3+4(As3+5O11)2. This defines its elemental composition.2. Which crystal system does LUDLOCKITE belong to?LUDLOCKITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pinacoidal class.
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3. How is LUDLOCKITE typically found in nature?The “habit” or typical appearance of LUDLOCKITE is described as Simply terminated laths, elongated, flattened; rare macro prismatic; slightly twisted, divergent bundles, hairlike. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does LUDLOCKITE form?LUDLOCKITE is typically found in environments described as: In sulfide ore from a complex polymetallic hydrothermal ore deposit. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to LUDLOCKITE?Yes, it is often associated with or related to other minerals such as: Compare karibibite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of LUDLOCKITE, we recommend checking high-authority databases:

Final Thoughts

LUDLOCKITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of PbFe3+4(As3+5O11)2 and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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