MACDONALDITE Mineral Details

Complete mineralogical data for MACDONALDITE. Chemical Formula: BaCa4[Si16O36(OH)2](H2O)6·4H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

MACDONALDITE

BaCa4[Si16O36(OH)2](H2O)6·4H2O

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Cmcm

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Phyllosilicates: rings of tetrahedra are linked into continuous sheets; single nets of tetrahedra; double apophyllite-like silicate sheet with 4- & 8-membered rings alternates along [010] with open sheet composed of H—bonded chains of edge-sharing Ca octahedra; Ba[10] & 6H2O modules lodged in large channels formed by 8-membered rings.1 Layer pattern consists of 4-sided & 8-sided rings of SiO4 tetrahedra which are doubled & give [Si8O19] radical (each Si—O net is close to apophyllite net); these double Si—O nets are connected with each other by sheets of Ca polyhedra, bound at edges & H—bonds; in large holes are Ba ions & part of H2O molecules, which have zeolite nature.2

Cell Data

a=14.08Å, b=13.11Å, c=23.56Å, Z=4

Geology & Identification

Geologic Occurrence

In miarolitic cavities, metamorphosed inclusions in intrusive alkalic gabbro-syenite complexMACDONALDITEMACDONALDITE

Habit

Needlelike macro crystals, flattedned; as irregular micaceous masses, radiating clusters, parallel groups

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare delhayeite, hydrodelhayelite, monteregianite-(Y), mountainite, rhodesite

If you are fascinated by the hidden structures of our planet, you have likely come across MACDONALDITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MACDONALDITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MACDONALDITE is defined by the chemical formula BaCa4[Si16O36(OH)2](H2O)6·4H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MACDONALDITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Cmcm
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MACDONALDITE, the dimensions of this microscopic building block are:
a=14.08Å, b=13.11Å, c=23.56Å, Z=4
The internal arrangement of these atoms is described as:Phyllosilicates: rings of tetrahedra are linked into continuous sheets; single nets of tetrahedra; double apophyllite-like silicate sheet with 4- & 8-membered rings alternates along [010] with open sheet composed of H—bonded chains of edge-sharing Ca octahedra; Ba[10] & 6H2O modules lodged in large channels formed by 8-membered rings.1 Layer pattern consists of 4-sided & 8-sided rings of SiO4 tetrahedra which are doubled & give [Si8O19] radical (each Si—O net is close to apophyllite net); these double Si—O nets are connected with each other by sheets of Ca polyhedra, bound at edges & H—bonds; in large holes are Ba ions & part of H2O molecules, which have zeolite nature.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find MACDONALDITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Needlelike macro crystals, flattedned; as irregular micaceous masses, radiating clusters, parallel groups
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MACDONALDITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In miarolitic cavities, metamorphosed inclusions in intrusive alkalic gabbro-syenite complexKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MACDONALDITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare delhayeite, hydrodelhayelite, monteregianite-(Y), mountainite, rhodesiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of MACDONALDITE?The standard chemical formula for MACDONALDITE is BaCa4[Si16O36(OH)2](H2O)6·4H2O. This defines its elemental composition.2. Which crystal system does MACDONALDITE belong to?MACDONALDITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.
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3. How is MACDONALDITE typically found in nature?The “habit” or typical appearance of MACDONALDITE is described as Needlelike macro crystals, flattedned; as irregular micaceous masses, radiating clusters, parallel groups. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MACDONALDITE form?MACDONALDITE is typically found in environments described as: In miarolitic cavities, metamorphosed inclusions in intrusive alkalic gabbro-syenite complex. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MACDONALDITE?Yes, it is often associated with or related to other minerals such as: Compare delhayeite, hydrodelhayelite, monteregianite-(Y), mountainite, rhodesite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MACDONALDITE, we recommend checking high-authority databases:

Final Thoughts

MACDONALDITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of BaCa4[Si16O36(OH)2](H2O)6·4H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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