MARIĆITE Mineral Details

Complete mineralogical data for MARIĆITE. Chemical Formula: NaFe2+(PO4). Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

MARIĆITE

NaFe2+(PO4)

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pmnb

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with medium-sized & large cations; lattice as natrophilite, but with Na coordinated by 10 O atoms.2 Na is surrounded by 10 O atoms within 3 Å, in irregular coordination; distorted octahedron about Fe is of (2+2+2) type; phosphate tetrahedron is nearly regular; ½ of O atoms are coordinated to 2 Na+, 2 Fe2+ & 1 P5+ ions, & other ½ to 3 Na+, 1 Fe2+, & 1 P5+ ions; packing efficiency is 70%.3

Cell Data

a=6.861Å, b=8.987Å, c=5.045Å, Z=4

Geology & Identification

Geologic Occurrence

In phosphatic nodules in sideritic ironstonesMARIĆITEMARIĆITE

Habit

Crudely formed macro crystals, elongated, usually radial to subparallel in nodules

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Triphylite group

If you are fascinated by the hidden structures of our planet, you have likely come across MARIĆITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MARIĆITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MARIĆITE is defined by the chemical formula NaFe2+(PO4).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MARIĆITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pmnb
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MARIĆITE, the dimensions of this microscopic building block are:
a=6.861Å, b=8.987Å, c=5.045Å, Z=4
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with medium-sized & large cations; lattice as natrophilite, but with Na coordinated by 10 O atoms.2 Na is surrounded by 10 O atoms within 3 Å, in irregular coordination; distorted octahedron about Fe is of (2+2+2) type; phosphate tetrahedron is nearly regular; ½ of O atoms are coordinated to 2 Na+, 2 Fe2+ & 1 P5+ ions, & other ½ to 3 Na+, 1 Fe2+, & 1 P5+ ions; packing efficiency is 70%.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find MARIĆITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crudely formed macro crystals, elongated, usually radial to subparallel in nodules
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MARIĆITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In phosphatic nodules in sideritic ironstonesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MARIĆITE is often related to other species, either through similar chemistry or structure.Relationship Data: Triphylite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of MARIĆITE?The standard chemical formula for MARIĆITE is NaFe2+(PO4). This defines its elemental composition.2. Which crystal system does MARIĆITE belong to?MARIĆITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.
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3. How is MARIĆITE typically found in nature?The “habit” or typical appearance of MARIĆITE is described as Crudely formed macro crystals, elongated, usually radial to subparallel in nodules. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MARIĆITE form?MARIĆITE is typically found in environments described as: In phosphatic nodules in sideritic ironstones. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MARIĆITE?Yes, it is often associated with or related to other minerals such as: Triphylite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MARIĆITE, we recommend checking high-authority databases:

Final Thoughts

MARIĆITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of NaFe2+(PO4) and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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