MARICOPAITE Mineral Details

Complete mineralogical data for MARICOPAITE. Chemical Formula: (Pb3.5□0.5)Ca[(Si18Al6)O48]O2·16H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

MARICOPAITE

(Pb3.5□0.5)Ca[(Si18Al6)O48]O2·16H2O

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Cm2m

Point Group

m m 2

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O; which has interrupted mordenite-like framework with cruciform 12-membered channels contain Pb4(O,OH)4 clusters.2 Structure exhibits random (Si,Al) distribution & is closely related to that of mordenite; it has interupted framework in which 17% of TO4 grp are [3] connected (Rouse & Peacor (1994)); this diff has several consequences; in maricopaite there are no 4 & 8 membered-rings || to (001); strongly compressed channel apparently bonded by 8-membered rings still appears in projection || to c-axis; apparent rings are actually composed of staggered ½ rings, ½ at z = 0 & other at z = ½; voids are considerably larger than in mordenite; elongation of compressed channels is || to a-axis in mordenite but is || to b-axis in maricopaite.3 See “Additional Structures” tab for entry(s).4 Framework in which 17% of TO4 grp are [3]-connected, diff from that of mordenite in following resp: (1) 4- & 8-membered rings in mordenite do not exist in maricopaite due to framework interruptions; (2) elliptical 8-membered-ring channels || c in mordenite become cruciform 12-membered-ring channels in maricopaite; (3) short channels || b in mordenite are absent in maricopaite; (4) elliptical 12-membered-ring channels || c in mordenite also exist in maricopaite, but access btw them & cruciform channels in b direction is thru single 8-membered-ring ports, rather than thru short connecting channels || b, as in mordenite; cruciform channels are obstructed by Pb4(O,OH)4 clusters in which Pb atoms form Pb4 tetrahedra, each tetrahedron face being capped by O or OH ligand; all Pb sites are partially occupied, & there are 2 alternative sites for each Pb4 tetrahedron, sites cannot be simultaneously occupied due to short Pb—Pb distances.5 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; maricopaite has interupted, mordenite-like framework; Pb atoms form Pb4(O,OH)4 clusters with Pb4 tetrahedra within channels.6

Cell Data

a=19.43Å, b=19.72Å, c=7.54Å, Z=1

Geology & Identification

Geologic Occurrence

In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sedimentsMARICOPAITEMARICOPAITE

Habit

Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family

If you are fascinated by the hidden structures of our planet, you have likely come across MARICOPAITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MARICOPAITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MARICOPAITE is defined by the chemical formula (Pb3.5□0.5)Ca[(Si18Al6)O48]O2·16H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MARICOPAITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Cm2m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MARICOPAITE, the dimensions of this microscopic building block are:
a=19.43Å, b=19.72Å, c=7.54Å, Z=1
The internal arrangement of these atoms is described as:
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Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O; which has interrupted mordenite-like framework with cruciform 12-membered channels contain Pb4(O,OH)4 clusters.2 Structure exhibits random (Si,Al) distribution & is closely related to that of mordenite; it has interupted framework in which 17% of TO4 grp are [3] connected (Rouse & Peacor (1994)); this diff has several consequences; in maricopaite there are no 4 & 8 membered-rings || to (001); strongly compressed channel apparently bonded by 8-membered rings still appears in projection || to c-axis; apparent rings are actually composed of staggered ½ rings, ½ at z = 0 & other at z = ½; voids are considerably larger than in mordenite; elongation of compressed channels is || to a-axis in mordenite but is || to b-axis in maricopaite.3 See “Additional Structures” tab for entry(s).4 Framework in which 17% of TO4 grp are [3]-connected, diff from that of mordenite in following resp: (1) 4- & 8-membered rings in mordenite do not exist in maricopaite due to framework interruptions; (2) elliptical 8-membered-ring channels || c in mordenite become cruciform 12-membered-ring channels in maricopaite; (3) short channels || b in mordenite are absent in maricopaite; (4) elliptical 12-membered-ring channels || c in mordenite also exist in maricopaite, but access btw them & cruciform channels in b direction is thru single 8-membered-ring ports, rather than thru short connecting channels || b, as in mordenite; cruciform channels are obstructed by Pb4(O,OH)4 clusters in which Pb atoms form Pb4 tetrahedra, each tetrahedron face being capped by O or OH ligand; all Pb sites are partially occupied, & there are 2 alternative sites for each Pb4 tetrahedron, sites cannot be simultaneously occupied due to short Pb—Pb distances.5 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; maricopaite has interupted, mordenite-like framework; Pb atoms form Pb4(O,OH)4 clusters with Pb4 tetrahedra within channels.6This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find MARICOPAITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MARICOPAITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sedimentsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MARICOPAITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite familyUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of MARICOPAITE?The standard chemical formula for MARICOPAITE is (Pb3.5□0.5)Ca[(Si18Al6)O48]O2·16H2O. This defines its elemental composition.2. Which crystal system does MARICOPAITE belong to?MARICOPAITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is MARICOPAITE typically found in nature?The “habit” or typical appearance of MARICOPAITE is described as Prismatic macro crystals, striated lengthwise; acicular to fine fibrous; in radiating groups, cotton like. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MARICOPAITE form?MARICOPAITE is typically found in environments described as: In veins and amygdules in various igneous rocks; hydration product of volcanic gasses; authigenic mineral in sediments. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MARICOPAITE?Yes, it is often associated with or related to other minerals such as: Zeolite family.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MARICOPAITE, we recommend checking high-authority databases:

Final Thoughts

MARICOPAITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of (Pb3.5□0.5)Ca[(Si18Al6)O48]O2·16H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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