MAUCHERITE Mineral Details

Complete mineralogical data for MAUCHERITE. Chemical Formula: Ni11As8. Crystal System: Tetragonal. Learn about its geologic occurrence, habit, and identification.

MAUCHERITE

Ni11As8

Crystal System

Tetragonal

Crystal Class

Tetragonal trapezohedral

Space Group

P41212

Point Group

4 2 2

Structure & Data

Crystal Structure

Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); alloys of metalloids; alloys of metalloids with Cu, Ag, Au; NiAs5 □∆ & NiAs6 octahedra share edges & faces to form framework with short Ni—Ni distances.1 OD (order-disorder) structure consisting of unit layers, which display stacking orientation disorder; simplest, uniform stacking of which can result either in tetragonal MDO1 structure with s.g. type P41212 or in monoclinic MDO2 structure with s.g. C2/c; polytypes with more complicated or disordered stacking sequences may form.2 Deficient in Ni (up to 8%) & has defect structure.3 Structure contains 6 non-equivalent Ni atoms per unit cell, 5 in □∆ coordination with As in equipoint position 8b & 1 in streched octahedral coordination in equipoint position 4a; As polyhedra form single chains of trig prisms arranged so prism faces contribute to □∆ Ni sites; alternate prisms share face with prism from adjacent chain; site which incl shared face is vacant to acct for unusual stoichiometry of maucherite; each Ni is [4]- & [5]-coordinated neighboring Ni atoms with Ni—Ni distances of 2.48 Å to 2.87 Å; shorter distances arise thru shared ∆ faces & shared As polyhedral prisms; longer one arise from shared ∆-octahedral faces & shared ∆ edges; it is suggested that 3-D electro σ bonding btw these related Ni atoms supplements Ni—As σ bonds; principal feature of maucherite structure have counterparts in xl structures of a-Ni7S6 & millerite (NiS).4

Cell Data

a=6.872Å, c=21.821Å, Z=4

Geology & Identification

Geologic Occurrence

In hydrothermal veins with other nickel arsenides and sulfidesMAUCHERITEMAUCHERITE

Habit

Frequently tabular; also pyramidal with faces striated; massive, granular, radiating fibrous

Twinning

On {203} and {106}

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across MAUCHERITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MAUCHERITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MAUCHERITE is defined by the chemical formula Ni11As8.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MAUCHERITE crystallizes in the Tetragonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Tetragonal trapezohedral.
  • Point Group: 4 2 2
  • Space Group: P41212
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MAUCHERITE, the dimensions of this microscopic building block are:
a=6.872Å, c=21.821Å, Z=4
The internal arrangement of these atoms is described as:
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Compounds of metals with S, Se, Te (chalcogens) & As, Sb, Bi (metalloids); alloys of metalloids; alloys of metalloids with Cu, Ag, Au; NiAs5 □∆ & NiAs6 octahedra share edges & faces to form framework with short Ni—Ni distances.1 OD (order-disorder) structure consisting of unit layers, which display stacking orientation disorder; simplest, uniform stacking of which can result either in tetragonal MDO1 structure with s.g. type P41212 or in monoclinic MDO2 structure with s.g. C2/c; polytypes with more complicated or disordered stacking sequences may form.2 Deficient in Ni (up to 8%) & has defect structure.3 Structure contains 6 non-equivalent Ni atoms per unit cell, 5 in □∆ coordination with As in equipoint position 8b & 1 in streched octahedral coordination in equipoint position 4a; As polyhedra form single chains of trig prisms arranged so prism faces contribute to □∆ Ni sites; alternate prisms share face with prism from adjacent chain; site which incl shared face is vacant to acct for unusual stoichiometry of maucherite; each Ni is [4]- & [5]-coordinated neighboring Ni atoms with Ni—Ni distances of 2.48 Å to 2.87 Å; shorter distances arise thru shared ∆ faces & shared As polyhedral prisms; longer one arise from shared ∆-octahedral faces & shared ∆ edges; it is suggested that 3-D electro σ bonding btw these related Ni atoms supplements Ni—As σ bonds; principal feature of maucherite structure have counterparts in xl structures of a-Ni7S6 & millerite (NiS).4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find MAUCHERITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Frequently tabular; also pyramidal with faces striated; massive, granular, radiating fibrous
  • Twinning: On {203} and {106}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MAUCHERITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In hydrothermal veins with other nickel arsenides and sulfidesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MAUCHERITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of MAUCHERITE?The standard chemical formula for MAUCHERITE is Ni11As8. This defines its elemental composition.
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2. Which crystal system does MAUCHERITE belong to?MAUCHERITE crystallizes in the Tetragonal system. Its internal symmetry is further classified under the Tetragonal trapezohedral class.3. How is MAUCHERITE typically found in nature?The “habit” or typical appearance of MAUCHERITE is described as Frequently tabular; also pyramidal with faces striated; massive, granular, radiating fibrous. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MAUCHERITE form?MAUCHERITE is typically found in environments described as: In hydrothermal veins with other nickel arsenides and sulfides. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MAUCHERITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MAUCHERITE, we recommend checking high-authority databases:

Final Thoughts

MAUCHERITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ni11As8 and a structure defined by the Tetragonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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