MERWINITE Mineral Details

Complete mineralogical data for MERWINITE. Chemical Formula: Ca3Mg[SiO4]2. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

MERWINITE

Ca3Mg[SiO4]2

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/a

Point Group

2/m

Structure & Data

Crystal Structure

Nesosilicates: insular SiO4 tetrahedra w/o add’l anions, cations in octahedral [6] &/or greater coordination; corner-sharing MgO6 octahedra & SiO4 tetrahedra form pseudo-hexagonal sheets // (100); each octahedron linked to 6 SiO4 in pinwheel-like array; Ca[12] & Ca2[10] lodged btw adjoining sheets; as in glaserite.1 Atomic structure is extreme example of dense-packing where both O2- & Ca2+ions comprise dense-packed layers; [MgO6] octahedra are linked at every corner by [SiO4] tetrahedra, defining “pinwheel” of 3 point pseudo-symmetry; pinwheels link indefinitely to form slabs || to {100}; geometrically idealized merwinite array incl Ca(1) in [12]-coordination by O2- anions defining polyhedron with point pseudosymmetry 3m, Ca(2) & Ca(3) each in [1]-coordination whose polyhedra have point pseudosymmetry 3m; its idealized array is glaseritre structure type; distortions in real structure lead to lower coordination #, btw 8 & 9 for Ca2+; structure is also related to other numerous Ca2[SiO4] & alkali sulfate polymorphs.2 Glaserite (aphthitalite), K8Na[SO4]2 & its high temp isotype “silico-glaserite”, α-Ca2[SiO4]; merwinite, Ca3Mg[SiO4]2; larnite, ß-Ca2[SiO4]; room temp ß-K2[SO4]; bredigite, ± Ca7Mg {SiO4]4; K[LiSO4]; & palmierite, K2Pb[SO4]2 are bases of atomic array for over 100 compounds; glaserite structure type consists of 1 large alkali cation of [12]-coordinated by O atoms, 6 of which define vertices of elongate trig antiprism & 6 of which reside in hexagonal ring in plane of large alkali; tetrahedral grp around antiprism defines “pinwheel” where apical O point either up (u) or down (d); bracelet is mathematical object, loop with n nodes involving m symbols, where m < n; for pinwheel, n = 6 (hexagonal ring) & m = 2 (u or d); # of distinct bracelets is 13; for any bracelet there is pinwheel which, idealized defines max CN of central large alkali; max CN is 12-p where 0 ≤ p ≤ 6 & where p are # of tetrahedral apical O coordinating to alkali; bracelets can be used to construct, by condensation, ideals of real & hypothetic atomic arrays found in Ca2[SiO4] polymorphs & many of alkali sulfates; coordination polyhedra of interest incl T (tetrahedron); M (octahedron, = p = 6); X[12-p] (which, for p = 0, has ideal symmetry 32/m); Y[10] (PS 3m) & F[12] (cuboctahedron); condensation of bracelets & their assoc pinwheels defines max CN for all polyhedra in ideal model; corresponds to bredigite.3

Cell Data

a=13.25Å, b=5.29Å, c=9.33Å, ß=91.9o, Z=4

Geology & Identification

Geologic Occurrence

In siliceous dolomitic limestone in contact metamorphic zones, at elevated temperaturesMERWINITEMERWINITE

Habit

Crystals are rare and inevitable pitted and rounded; massive

Twinning

Polysynthetic on {100}, twin axis [013], common

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare bredigite, brianite

If you are fascinated by the hidden structures of our planet, you have likely come across MERWINITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MERWINITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MERWINITE is defined by the chemical formula Ca3Mg[SiO4]2.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MERWINITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/a
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MERWINITE, the dimensions of this microscopic building block are:
a=13.25Å, b=5.29Å, c=9.33Å, ß=91.9o, Z=4
The internal arrangement of these atoms is described as:
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Nesosilicates: insular SiO4 tetrahedra w/o add’l anions, cations in octahedral [6] &/or greater coordination; corner-sharing MgO6 octahedra & SiO4 tetrahedra form pseudo-hexagonal sheets // (100); each octahedron linked to 6 SiO4 in pinwheel-like array; Ca[12] & Ca2[10] lodged btw adjoining sheets; as in glaserite.1 Atomic structure is extreme example of dense-packing where both O2- & Ca2+ions comprise dense-packed layers; [MgO6] octahedra are linked at every corner by [SiO4] tetrahedra, defining “pinwheel” of 3 point pseudo-symmetry; pinwheels link indefinitely to form slabs || to {100}; geometrically idealized merwinite array incl Ca(1) in [12]-coordination by O2- anions defining polyhedron with point pseudosymmetry 3m, Ca(2) & Ca(3) each in [1]-coordination whose polyhedra have point pseudosymmetry 3m; its idealized array is glaseritre structure type; distortions in real structure lead to lower coordination #, btw 8 & 9 for Ca2+; structure is also related to other numerous Ca2[SiO4] & alkali sulfate polymorphs.2 Glaserite (aphthitalite), K8Na[SO4]2 & its high temp isotype “silico-glaserite”, α-Ca2[SiO4]; merwinite, Ca3Mg[SiO4]2; larnite, ß-Ca2[SiO4]; room temp ß-K2[SO4]; bredigite, ± Ca7Mg {SiO4]4; K[LiSO4]; & palmierite, K2Pb[SO4]2 are bases of atomic array for over 100 compounds; glaserite structure type consists of 1 large alkali cation of [12]-coordinated by O atoms, 6 of which define vertices of elongate trig antiprism & 6 of which reside in hexagonal ring in plane of large alkali; tetrahedral grp around antiprism defines “pinwheel” where apical O point either up (u) or down (d); bracelet is mathematical object, loop with n nodes involving m symbols, where m < n; for pinwheel, n = 6 (hexagonal ring) & m = 2 (u or d); # of distinct bracelets is 13; for any bracelet there is pinwheel which, idealized defines max CN of central large alkali; max CN is 12-p where 0 ≤ p ≤ 6 & where p are # of tetrahedral apical O coordinating to alkali; bracelets can be used to construct, by condensation, ideals of real & hypothetic atomic arrays found in Ca2[SiO4] polymorphs & many of alkali sulfates; coordination polyhedra of interest incl T (tetrahedron); M (octahedron, = p = 6); X[12-p] (which, for p = 0, has ideal symmetry 32/m); Y[10] (PS 3m) & F[12] (cuboctahedron); condensation of bracelets & their assoc pinwheels defines max CN for all polyhedra in ideal model; corresponds to bredigite.3This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find MERWINITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals are rare and inevitable pitted and rounded; massive
  • Twinning: Polysynthetic on {100}, twin axis [013], common
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MERWINITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In siliceous dolomitic limestone in contact metamorphic zones, at elevated temperaturesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MERWINITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare bredigite, brianiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of MERWINITE?The standard chemical formula for MERWINITE is Ca3Mg[SiO4]2. This defines its elemental composition.2. Which crystal system does MERWINITE belong to?MERWINITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is MERWINITE typically found in nature?The “habit” or typical appearance of MERWINITE is described as Crystals are rare and inevitable pitted and rounded; massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MERWINITE form?MERWINITE is typically found in environments described as: In siliceous dolomitic limestone in contact metamorphic zones, at elevated temperatures. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MERWINITE?Yes, it is often associated with or related to other minerals such as: Compare bredigite, brianite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MERWINITE, we recommend checking high-authority databases:

Final Thoughts

MERWINITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca3Mg[SiO4]2 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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