METAHEWETTITE Mineral Details

Complete mineralogical data for METAHEWETTITE. Chemical Formula: Ca(V5+6O16)(H2O)3. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

METAHEWETTITE

Ca(V5+6O16)(H2O)3

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/m

Point Group

2/m

Structure & Data

Crystal Structure

Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; V[5,6] vanadates, phyllo-vanadates; V[4+1] □∆ share edges to form [V2O6]2- chains, as in munirite; V[6] octahedra share edges & corners to form [V4O12] double chains, as in Ag3V4O12; chains share corners to form [V6O16] sheets // (001); shorter distances than hewetite; can become reconstituted.2 Ca occupy tetrahedral sites & there is trig bi-∆ coordination of O around each of 3 non-equivalent V instead of around only 1; trig bi-∆ share edges to form zigzag chains along direction of y, & chains along edges of unit cell are joined thru corners into spiral tubes about 21 axes prp to y = 0; cations (& H2O molecules in hydrated material) are situated btw chains of trig bi-∆ with z = ½ as median plane.3 V bronze minerals are divided into 3 categories: (1) hewettite grp with layer structure analog to synthetic Li3V6O16, incl hewettite, metahewettite, barnesite, hendersonite & grantsite; (2) straczekite grp with layer structures analog to synthetic Ag5.44V8O20, incl straczekite, corvusite, fernandite, bokite & bariandite; (3) other structure types incl navajoite, schubnelite, fervanite, shcherbinaite, bannermanite & melanovanadite; all known structures assoc with fibrous V bronzes (fiber spacing 3.6 Å) can be considered as var lateral linkages (into sheets or networks) of only 2 types of polyvanadate chains: (1) divanadate chains (V2O6)n consisting of alternating □∆; (2) tetravanadate chain (V4O12)n consisting of 4 highly condensed single octahedral chains.5

Cell Data

a=12.26Å, b=3.58Å, c=8.11Å, ß=92.50o, Z=1

Geology & Identification

Geologic Occurrence

Deposited from fumarolic gasses; in V-bearing sublimates in fumarolesMETAHEWETTITEMETAHEWETTITE

Habit

Fibrous aggregates of acicular crystals, lathlike, elongated and flattened

Twinning

Rotation about {100}, with {031} composition plane probable, simple, geniculated

Relationships

RELATIONSHIP TO OTHER MINERALS

Hewettite group; compare hewetite, barnesite

If you are fascinated by the hidden structures of our planet, you have likely come across METAHEWETTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about METAHEWETTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, METAHEWETTITE is defined by the chemical formula Ca(V5+6O16)(H2O)3.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. METAHEWETTITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For METAHEWETTITE, the dimensions of this microscopic building block are:
a=12.26Å, b=3.58Å, c=8.11Å, ß=92.50o, Z=1
The internal arrangement of these atoms is described as:
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Cation coordinations varying from [2] to [10] & polyhedra linked in var ways; V[5,6] vanadates, phyllo-vanadates; V[4+1] □∆ share edges to form [V2O6]2- chains, as in munirite; V[6] octahedra share edges & corners to form [V4O12] double chains, as in Ag3V4O12; chains share corners to form [V6O16] sheets // (001); shorter distances than hewetite; can become reconstituted.2 Ca occupy tetrahedral sites & there is trig bi-∆ coordination of O around each of 3 non-equivalent V instead of around only 1; trig bi-∆ share edges to form zigzag chains along direction of y, & chains along edges of unit cell are joined thru corners into spiral tubes about 21 axes prp to y = 0; cations (& H2O molecules in hydrated material) are situated btw chains of trig bi-∆ with z = ½ as median plane.3 V bronze minerals are divided into 3 categories: (1) hewettite grp with layer structure analog to synthetic Li3V6O16, incl hewettite, metahewettite, barnesite, hendersonite & grantsite; (2) straczekite grp with layer structures analog to synthetic Ag5.44V8O20, incl straczekite, corvusite, fernandite, bokite & bariandite; (3) other structure types incl navajoite, schubnelite, fervanite, shcherbinaite, bannermanite & melanovanadite; all known structures assoc with fibrous V bronzes (fiber spacing 3.6 Å) can be considered as var lateral linkages (into sheets or networks) of only 2 types of polyvanadate chains: (1) divanadate chains (V2O6)n consisting of alternating □∆; (2) tetravanadate chain (V4O12)n consisting of 4 highly condensed single octahedral chains.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find METAHEWETTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Fibrous aggregates of acicular crystals, lathlike, elongated and flattened
  • Twinning: Rotation about {100}, with {031} composition plane probable, simple, geniculated
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If METAHEWETTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Deposited from fumarolic gasses; in V-bearing sublimates in fumarolesKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. METAHEWETTITE is often related to other species, either through similar chemistry or structure.Relationship Data: Hewettite group; compare hewetite, barnesiteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of METAHEWETTITE?The standard chemical formula for METAHEWETTITE is Ca(V5+6O16)(H2O)3. This defines its elemental composition.
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2. Which crystal system does METAHEWETTITE belong to?METAHEWETTITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is METAHEWETTITE typically found in nature?The “habit” or typical appearance of METAHEWETTITE is described as Fibrous aggregates of acicular crystals, lathlike, elongated and flattened. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does METAHEWETTITE form?METAHEWETTITE is typically found in environments described as: Deposited from fumarolic gasses; in V-bearing sublimates in fumaroles. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to METAHEWETTITE?Yes, it is often associated with or related to other minerals such as: Hewettite group; compare hewetite, barnesite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of METAHEWETTITE, we recommend checking high-authority databases:

Final Thoughts

METAHEWETTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca(V5+6O16)(H2O)3 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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