MURMANITE Mineral Details

Complete mineralogical data for MURMANITE. Chemical Formula: Na2Ti2Na2Ti2[Si2O7]2O4(H2O)4. Crystal System: Triclinic. Learn about its geologic occurrence, habit, and identification.

MURMANITE

Na2Ti2Na2Ti2[Si2O7]2O4(H2O)4

Crystal System

Triclinic

Crystal Class

Pedial

Space Group

P1

Point Group

1

Structure & Data

Crystal Structure

Sorosilicates: SiO4 tetrahedras combined mainly in pairs; in larger combos which form isolated grp; Si2O7 grp with add’l anions, cations in octahedral [6] &/or other coordination; central sheet of edge-sharing TiO6 octahedra connected into zigzag brookite-like chains // [100] share edges with Na polyhedra; adjoining sheet consists of edge- & corner-sharing TiO6 octahedra, Na(O, H2O)6 octahedra & Si2O7 grp; other adjoining sheet consists only of Si2O7 grp attached to octahedra & polyhedra of central sheet by sharing corners; multiple sheets linked by H—bonds of H2O molecules.2 Layered structures have not been examined in detail; gen structure of murmanite is typical layer structure entire analog to bafertisite; 3-layer packets diff only in composition of inner layer, which contains alterternating Na, Mn & Ti octahedra as well as Fe octahedra; ratio of Si2O7 grp to Ti octahedra in surrounding Ti—Si layers is 1:1, as in bafertisite, but outward-projecting 6 vertices of these Ti octahedra have O repl by H2O, which makes packet neutral; large holes btw packets contain not only these H2O molecules, also = # of free ones.3 See “Additional Structures” tab for entry(s).4-16 Structures of lamprophyllite-related minerals are based on HOH modules of central octahedral O sheet sandwiched btw 2 heteropolyhedral H sheets; xl GF for these minerals as [10-22]A2[6]M1[6]M22[6]M3X2][5]L2 (Si2O7)2O2], where contents of O & H sheets are given in [] brackets in this order & A = Ba,Sr,K,Na; M1 = Na, Mn2+; M2 = Na,Mn2+,Fe2+,Ca; M3 = Ti,Mn2+,Mg,Fe3+,Fe2+; L = Ti,Fe3+; X = OH,O,F; according to unit-cell parameters & symmetry, lamprophyllite-related minerals structure types: I (monocinic polytypes, C2/m); II (orthorhom-bic polytypes, Pnmn), III (nabalamprophyllite, BaNa (Na3Ti(OH)2][Ti2(Si2 O7)2O2], monoclinic, P2/m, with ordered array of interlayer Ba2+ & Na+ cations), IV (triclinic, P1) & V (triclinic, P1); triclinic members (IV & V) incl schüllerite & its analogs, which diff from lamprophyllite-grp minerals sensu stricto in their symmetry & topology & HOH modules; end-member formula of lamprophyllite-related minerals & position of schüllerite in ranks of heterophyllosilicates.17

Cell Data

a=5.38Å, b=7.05Å, c=12.17Å, α=93.2o, ß=107.8o, γ=90.1o, Z=1

Geology & Identification

Geologic Occurrence

In pegmatites, associated igneous rocks of alkalic complexes, as primary magmatic mineralMURMANITEMURMANITE

Habit

Rarely in well-formed macro crystals; as flaky and lamellar segregations; radial, fine-grained aggregations

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Analog of calciomurmanite (note: space group differs)

If you are fascinated by the hidden structures of our planet, you have likely come across MURMANITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MURMANITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MURMANITE is defined by the chemical formula Na2Ti2Na2Ti2[Si2O7]2O4(H2O)4.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MURMANITE crystallizes in the Triclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pedial.
  • Point Group: 1
  • Space Group: P1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MURMANITE, the dimensions of this microscopic building block are:
a=5.38Å, b=7.05Å, c=12.17Å, α=93.2o, ß=107.8o, γ=90.1o, Z=1
The internal arrangement of these atoms is described as:
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Sorosilicates: SiO4 tetrahedras combined mainly in pairs; in larger combos which form isolated grp; Si2O7 grp with add’l anions, cations in octahedral [6] &/or other coordination; central sheet of edge-sharing TiO6 octahedra connected into zigzag brookite-like chains // [100] share edges with Na polyhedra; adjoining sheet consists of edge- & corner-sharing TiO6 octahedra, Na(O, H2O)6 octahedra & Si2O7 grp; other adjoining sheet consists only of Si2O7 grp attached to octahedra & polyhedra of central sheet by sharing corners; multiple sheets linked by H—bonds of H2O molecules.2 Layered structures have not been examined in detail; gen structure of murmanite is typical layer structure entire analog to bafertisite; 3-layer packets diff only in composition of inner layer, which contains alterternating Na, Mn & Ti octahedra as well as Fe octahedra; ratio of Si2O7 grp to Ti octahedra in surrounding Ti—Si layers is 1:1, as in bafertisite, but outward-projecting 6 vertices of these Ti octahedra have O repl by H2O, which makes packet neutral; large holes btw packets contain not only these H2O molecules, also = # of free ones.3 See “Additional Structures” tab for entry(s).4-16 Structures of lamprophyllite-related minerals are based on HOH modules of central octahedral O sheet sandwiched btw 2 heteropolyhedral H sheets; xl GF for these minerals as [10-22]A2[6]M1[6]M22[6]M3X2][5]L2 (Si2O7)2O2], where contents of O & H sheets are given in [] brackets in this order & A = Ba,Sr,K,Na; M1 = Na, Mn2+; M2 = Na,Mn2+,Fe2+,Ca; M3 = Ti,Mn2+,Mg,Fe3+,Fe2+; L = Ti,Fe3+; X = OH,O,F; according to unit-cell parameters & symmetry, lamprophyllite-related minerals structure types: I (monocinic polytypes, C2/m); II (orthorhom-bic polytypes, Pnmn), III (nabalamprophyllite, BaNa (Na3Ti(OH)2][Ti2(Si2 O7)2O2], monoclinic, P2/m, with ordered array of interlayer Ba2+ & Na+ cations), IV (triclinic, P1) & V (triclinic, P1); triclinic members (IV & V) incl schüllerite & its analogs, which diff from lamprophyllite-grp minerals sensu stricto in their symmetry & topology & HOH modules; end-member formula of lamprophyllite-related minerals & position of schüllerite in ranks of heterophyllosilicates.17This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find MURMANITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Rarely in well-formed macro crystals; as flaky and lamellar segregations; radial, fine-grained aggregations
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MURMANITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In pegmatites, associated igneous rocks of alkalic complexes, as primary magmatic mineralKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MURMANITE is often related to other species, either through similar chemistry or structure.Relationship Data: Analog of calciomurmanite (note: space group differs)Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of MURMANITE?The standard chemical formula for MURMANITE is Na2Ti2Na2Ti2[Si2O7]2O4(H2O)4. This defines its elemental composition.2. Which crystal system does MURMANITE belong to?MURMANITE crystallizes in the Triclinic system. Its internal symmetry is further classified under the Pedial class.3. How is MURMANITE typically found in nature?The “habit” or typical appearance of MURMANITE is described as Rarely in well-formed macro crystals; as flaky and lamellar segregations; radial, fine-grained aggregations. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MURMANITE form?MURMANITE is typically found in environments described as: In pegmatites, associated igneous rocks of alkalic complexes, as primary magmatic mineral. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MURMANITE?Yes, it is often associated with or related to other minerals such as: Analog of calciomurmanite (note: space group differs).

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MURMANITE, we recommend checking high-authority databases:

Final Thoughts

MURMANITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na2Ti2Na2Ti2[Si2O7]2O4(H2O)4 and a structure defined by the Triclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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