MUTNOVSKITE Mineral Details

Complete mineralogical data for MUTNOVSKITE. Chemical Formula: Pb2AsS3(I,Cl,Br). Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

MUTNOVSKITE

Pb2AsS3(I,Cl,Br)

Crystal System

Orthorhombic

Crystal Class

Dipyramidal

Space Group

Pnma

Point Group

2/m 2/m 2/m

Structure & Data

Crystal Structure

3 independent cation positions: Pb1 & Pb2 have tricapped trig prismatic coordinations with S & 1 atom; while As has [3]-coordination with S atoms, which form base of trig ∆ with As at apex; pairs of Pb1-Pb2 prisms connected in columns which extend along c; AsS2 coordinations isolated from each other; S atoms & ½ of Pb atoms form wavy close-packed layers; 2 kinds of channels || to b occur btw layers; smaller channels host As atoms close to channel walls with their lone-electron pairs occupying median part, while larger ones lodge rows of alternating halogen & Pb atoms.1 Centrosymmetric structure-type, s.g. Pnma at room temp (RT0) at low temp (110 K) non-centrosymmetric structure-type, s.g. Pnm21; mutnovskite reverts to centrosymmetric-type upon returning to RT, thus reversible in character; changes occurring during phase trasition Pnma —> Pnm21 are mainly restricted to coordination polyhedra around Pb; structure solution revealed that I & Cl are ordered into 2 specific sites; unique mixed (I,Cl) position in RT-structure (Wyckoff position 4c) transforms into 2 2a Wyckoff positions in LT-structure hosting I & Cl, respectively.2

Cell Data

a=11.543Å, b=6.676Å, c=9.359Å, Z=4

Geology & Identification

Geologic Occurrence

High temperature fumaroleMUTNOVSKITEMUTNOVSKITE

Habit

Short-prismatic submicro crystals

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across MUTNOVSKITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about MUTNOVSKITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, MUTNOVSKITE is defined by the chemical formula Pb2AsS3(I,Cl,Br).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. MUTNOVSKITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dipyramidal.
  • Point Group: 2/m 2/m 2/m
  • Space Group: Pnma
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For MUTNOVSKITE, the dimensions of this microscopic building block are:
a=11.543Å, b=6.676Å, c=9.359Å, Z=4
The internal arrangement of these atoms is described as:3 independent cation positions: Pb1 & Pb2 have tricapped trig prismatic coordinations with S & 1 atom; while As has [3]-coordination with S atoms, which form base of trig ∆ with As at apex; pairs of Pb1-Pb2 prisms connected in columns which extend along c; AsS2 coordinations isolated from each other; S atoms & ½ of Pb atoms form wavy close-packed layers; 2 kinds of channels || to b occur btw layers; smaller channels host As atoms close to channel walls with their lone-electron pairs occupying median part, while larger ones lodge rows of alternating halogen & Pb atoms.1 Centrosymmetric structure-type, s.g. Pnma at room temp (RT0) at low temp (110 K) non-centrosymmetric structure-type, s.g. Pnm21; mutnovskite reverts to centrosymmetric-type upon returning to RT, thus reversible in character; changes occurring during phase trasition Pnma —> Pnm21 are mainly restricted to coordination polyhedra around Pb; structure solution revealed that I & Cl are ordered into 2 specific sites; unique mixed (I,Cl) position in RT-structure (Wyckoff position 4c) transforms into 2 2a Wyckoff positions in LT-structure hosting I & Cl, respectively.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find MUTNOVSKITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short-prismatic submicro crystals
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If MUTNOVSKITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: High temperature fumaroleKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. MUTNOVSKITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of MUTNOVSKITE?The standard chemical formula for MUTNOVSKITE is Pb2AsS3(I,Cl,Br). This defines its elemental composition.
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2. Which crystal system does MUTNOVSKITE belong to?MUTNOVSKITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Dipyramidal class.3. How is MUTNOVSKITE typically found in nature?The “habit” or typical appearance of MUTNOVSKITE is described as Short-prismatic submicro crystals. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does MUTNOVSKITE form?MUTNOVSKITE is typically found in environments described as: High temperature fumarole. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to MUTNOVSKITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of MUTNOVSKITE, we recommend checking high-authority databases:

Final Thoughts

MUTNOVSKITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb2AsS3(I,Cl,Br) and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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