NATROLITE Mineral Details

Complete mineralogical data for NATROLITE. Chemical Formula: Na2[Si3Al2O10]·2H2O. Crystal System: Orthorhombic. Learn about its geologic occurrence, habit, and identification.

NATROLITE

Na2[Si3Al2O10]·2H2O

Crystal System

Orthorhombic

Crystal Class

Pyramidal

Space Group

Fdd2

Point Group

m m 2

Structure & Data

Crystal Structure

Tektosilicates, tetrahedra are linked into 3-D framework with zeolitic H2O with chains of 4-membered rings, Al2Si2O10, connected by 5th Si; corner-sharing tetrahedra form chains // [001] spirally linked by extra SiO4 tetrahedra to form 3-D framework of 4- & 8-membered rings with large channels that lodge Na & H2O.2 Framework consisting of 4-sided Al2Si2O10 rings, which are linked by 5th (Si) atom into chains || to c axis; chains are cross-linked via tetrahedra of adjacent rings (via Al—O—Si bonds), & bond strength within chain is about 2x that btw chains; lengthwise cavities btw chains contain Na atoms & H2O molecules.3 Structure of natrolite was stulated by Pauling (1930) & was soon confirmed by X-ray diffraction methods (Taylor et al (1933)); Meier (1960) also confirmed structure & refined atomic positions; framework of natrolite & other fibrous zeolites consist of linked T5O10 chains (NAT); in natrolite chains have composition Al2Si3O10 & were highly ordered, repeat distance along chain, c-axis, is 6.6 Å.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; natrolite has Si,Al partly to highly ordered.6 See “Additional Structures” tab for entry(s).5,7a,7b,8,9a,9b

Cell Data

a=18.29Å, b=18.64Å, c=6.59Å, Z=8

Geology & Identification

Geologic Occurrence

In cavities in amygdaloidal basalts, related igneous rocks, late forming; in granite, gneiss, syeniteNATROLITENATROLITE

Habit

Short to long prismatic macro crystals, striated; in stellate, interlacing groups; radiating fibrous, granular

Twinning

On {110}, {011}, {031}

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family; dimorphic with gonnardite

If you are fascinated by the hidden structures of our planet, you have likely come across NATROLITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about NATROLITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, NATROLITE is defined by the chemical formula Na2[Si3Al2O10]·2H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. NATROLITE crystallizes in the Orthorhombic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Pyramidal.
  • Point Group: m m 2
  • Space Group: Fdd2
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For NATROLITE, the dimensions of this microscopic building block are:
a=18.29Å, b=18.64Å, c=6.59Å, Z=8
The internal arrangement of these atoms is described as:
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Tektosilicates, tetrahedra are linked into 3-D framework with zeolitic H2O with chains of 4-membered rings, Al2Si2O10, connected by 5th Si; corner-sharing tetrahedra form chains // [001] spirally linked by extra SiO4 tetrahedra to form 3-D framework of 4- & 8-membered rings with large channels that lodge Na & H2O.2 Framework consisting of 4-sided Al2Si2O10 rings, which are linked by 5th (Si) atom into chains || to c axis; chains are cross-linked via tetrahedra of adjacent rings (via Al—O—Si bonds), & bond strength within chain is about 2x that btw chains; lengthwise cavities btw chains contain Na atoms & H2O molecules.3 Structure of natrolite was stulated by Pauling (1930) & was soon confirmed by X-ray diffraction methods (Taylor et al (1933)); Meier (1960) also confirmed structure & refined atomic positions; framework of natrolite & other fibrous zeolites consist of linked T5O10 chains (NAT); in natrolite chains have composition Al2Si3O10 & were highly ordered, repeat distance along chain, c-axis, is 6.6 Å.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; natrolite has Si,Al partly to highly ordered.6 See “Additional Structures” tab for entry(s).5,7a,7b,8,9a,9bThis internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find NATROLITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Short to long prismatic macro crystals, striated; in stellate, interlacing groups; radiating fibrous, granular
  • Twinning: On {110}, {011}, {031}
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If NATROLITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In cavities in amygdaloidal basalts, related igneous rocks, late forming; in granite, gneiss, syeniteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. NATROLITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite family; dimorphic with gonnarditeUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of NATROLITE?The standard chemical formula for NATROLITE is Na2[Si3Al2O10]·2H2O. This defines its elemental composition.
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2. Which crystal system does NATROLITE belong to?NATROLITE crystallizes in the Orthorhombic system. Its internal symmetry is further classified under the Pyramidal class.3. How is NATROLITE typically found in nature?The “habit” or typical appearance of NATROLITE is described as Short to long prismatic macro crystals, striated; in stellate, interlacing groups; radiating fibrous, granular. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does NATROLITE form?NATROLITE is typically found in environments described as: In cavities in amygdaloidal basalts, related igneous rocks, late forming; in granite, gneiss, syenite. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to NATROLITE?Yes, it is often associated with or related to other minerals such as: Zeolite family; dimorphic with gonnardite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of NATROLITE, we recommend checking high-authority databases:

Final Thoughts

NATROLITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Na2[Si3Al2O10]·2H2O and a structure defined by the Orthorhombic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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