OWYHEEITE Mineral Details

Complete mineralogical data for OWYHEEITE. Chemical Formula: Pb10Ag3Sb11S28. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

OWYHEEITE

Pb10Ag3Sb11S28

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/c

Point Group

2/m

Structure & Data

Crystal Structure

Typified by presence of trig ∆ of As, Sb, Bi represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb,Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; galena-like slabs; Sb[3+2]S5 □∆ form chains // [001] with some chains also containing PbS6 octahedra.1 Contains 26 independent atoms: 4 Pb sites, 1 mixed Pb/Sb site, 5 Sb sites, 1 Ag site, 1 mixed Ag/Sb site & 14 S sites; all in gen Wyckoff position 4e of s.g. P21/c; no special positions are occupied; 3 types of aggregates of coordination polyhedra: [3]- columns of bicapped trig coordination prisms of Pb, 2-strand ribbons of Sb & 4-strand ribbons of 2 Sb atoms & 2 mixed sites Sb/Ag & Pb/Sb; ordering of Sb atoms to form lone electron pair micelles; owheeite belongs to broad family of rod-based sulfosalt structures with chessboard array of rods.2 Pb has CN = 8, while Ag & Sb have CN = 6; all polyhedra linked together, but stronger bond (by edges) occurs along c axis; c parameter is much similar.3 2 types of unit order-disorder (OD) layers with layer symmetries P(2/n) 2(1)/m 2(10m for thicker OD layer, & P(1) 1 2(1)/m for 3X thinner OD layer; these layers occur in 2 orientations, indexed as (021) & (021) of owyheeite lattice; ambiguity in orientation of thinner OD layer after thicker 1 leads to intimate twinning (stacking disorder); pseudohexagonality of lattice (b x √3/2≈σ with 2 alternate sets of OD layers further complicate twinning situation, which also can be described using rod representation of structure.4 Rod-polytype & twofold superstructure.5

Cell Data

a=4.104Å, b=27.314Å, c=22.937Å, ß=90.36o, Z=4

Geology & Identification

Geologic Occurrence

In fine-grained quartz in a vein of hydrothermal originOWYHEEITEOWYHEEITE

Habit

Crystals are long prismatic or thick lance-shaped

Twinning

Lamellar on (010); systematically twinned by reflection at (021).

Relationships

RELATIONSHIP TO OTHER MINERALS

If you are fascinated by the hidden structures of our planet, you have likely come across OWYHEEITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about OWYHEEITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, OWYHEEITE is defined by the chemical formula Pb10Ag3Sb11S28.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. OWYHEEITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For OWYHEEITE, the dimensions of this microscopic building block are:
a=4.104Å, b=27.314Å, c=22.937Å, ß=90.36o, Z=4
The internal arrangement of these atoms is described as:
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Typified by presence of trig ∆ of As, Sb, Bi represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb,Bi at apex; this can be attributed to lone-electron-pair effect of metalloid ions; PbS archetype, (As,Sb,Bi)S6 octahedra; sheets of AgS6 octahedra with pairs of BiS5 □∆ linked by (Bi,Ag)6 octahedra; galena-like slabs; Sb[3+2]S5 □∆ form chains // [001] with some chains also containing PbS6 octahedra.1 Contains 26 independent atoms: 4 Pb sites, 1 mixed Pb/Sb site, 5 Sb sites, 1 Ag site, 1 mixed Ag/Sb site & 14 S sites; all in gen Wyckoff position 4e of s.g. P21/c; no special positions are occupied; 3 types of aggregates of coordination polyhedra: [3]- columns of bicapped trig coordination prisms of Pb, 2-strand ribbons of Sb & 4-strand ribbons of 2 Sb atoms & 2 mixed sites Sb/Ag & Pb/Sb; ordering of Sb atoms to form lone electron pair micelles; owheeite belongs to broad family of rod-based sulfosalt structures with chessboard array of rods.2 Pb has CN = 8, while Ag & Sb have CN = 6; all polyhedra linked together, but stronger bond (by edges) occurs along c axis; c parameter is much similar.3 2 types of unit order-disorder (OD) layers with layer symmetries P(2/n) 2(1)/m 2(10m for thicker OD layer, & P(1) 1 2(1)/m for 3X thinner OD layer; these layers occur in 2 orientations, indexed as (021) & (021) of owyheeite lattice; ambiguity in orientation of thinner OD layer after thicker 1 leads to intimate twinning (stacking disorder); pseudohexagonality of lattice (b x √3/2≈σ with 2 alternate sets of OD layers further complicate twinning situation, which also can be described using rod representation of structure.4 Rod-polytype & twofold superstructure.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find OWYHEEITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals are long prismatic or thick lance-shaped
  • Twinning: Lamellar on (010); systematically twinned by reflection at (021).
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If OWYHEEITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In fine-grained quartz in a vein of hydrothermal originKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. OWYHEEITE is often related to other species, either through similar chemistry or structure.Relationship Data:Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of OWYHEEITE?The standard chemical formula for OWYHEEITE is Pb10Ag3Sb11S28. This defines its elemental composition.2. Which crystal system does OWYHEEITE belong to?OWYHEEITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is OWYHEEITE typically found in nature?The “habit” or typical appearance of OWYHEEITE is described as Crystals are long prismatic or thick lance-shaped. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does OWYHEEITE form?OWYHEEITE is typically found in environments described as: In fine-grained quartz in a vein of hydrothermal origin. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to OWYHEEITE?Yes, it is often associated with or related to other minerals such as: .

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of OWYHEEITE, we recommend checking high-authority databases:

Final Thoughts

OWYHEEITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb10Ag3Sb11S28 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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