PARACOQUIMBITE Mineral Details

Complete mineralogical data for PARACOQUIMBITE. Chemical Formula: Fe3+4(SO4)6(H2O)12·6H2O. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

PARACOQUIMBITE

Fe3+4(SO4)6(H2O)12·6H2O

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal rhombohedral

Space Group

R3

Point Group

3

Structure & Data

Crystal Structure

Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing w/o add’l anions with H2O with medium-sized cations; diff from coquimbite do to stacking sequence along [001].1 Main features are: (1) polyhedral clusters of 3 Fe octahedra & 6 S tetrahedra, (2) isolated Fe octahedra, & (3) 6 H2O molecules forming very distorted octahedra which contain no cations; 3 structural units are interconnected by H-bonds only; structure can be descibed as 6-layer stack with repeat distance of 8.5 Å along c axis; each individual layer within stack contains all 3 of main structural features described above.2 There are 5 non-equivalent octahedrally coordinated metal sites for Fe in structure; range of Fe[6]—O interatomic distances (1.966—2.016 Å) can well be compared with those found in var sulfate minerals of ferric iron.3 Both minerals are typified by complex system of H bonds involving 3 types of H2O molecules, resp: those of [Fe3(SO4)6(H2O)6]3- clusters of isolated [Fe(H2O)6]3+ or [Al(H2O)6]3+ octahedra & further interstitial (H2O) grp; interstitial H2O molecules resemble cyclohexane-like chair & are held in structure solely by H-bonding; in coquimbite H2OW(2) is disordered with 2 alternative orientations (H2B1 & H2B2), in paracoquimbite interstitial H2O consists of 2 H2O molecules; H2OW(3) & H2OW(4).4

Cell Data

a=10.93Å, c=51.30Å, Z=12, Z=6

Geology & Identification

Geologic Occurrence

Formed in oxidized zone of pyritic hydrothermal orebodies in arid regionsPARACOQUIMBITEPARACOQUIMBITE

Habit

Small rhombohedral crystals, equant, pseudocubic or prismatic; may be sceptered on coquimbite; massive

Twinning

On {0001}, common

Relationships

RELATIONSHIP TO OTHER MINERALS

Dimorphous with coquimbite; homeotypic structures

If you are fascinated by the hidden structures of our planet, you have likely come across PARACOQUIMBITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about PARACOQUIMBITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, PARACOQUIMBITE is defined by the chemical formula Fe3+4(SO4)6(H2O)12·6H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. PARACOQUIMBITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal rhombohedral.
  • Point Group: 3
  • Space Group: R3
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For PARACOQUIMBITE, the dimensions of this microscopic building block are:
a=10.93Å, c=51.30Å, Z=12, Z=6
The internal arrangement of these atoms is described as:
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Sulfates, selenates, tellurates: typified by SO4, SeO4, TeO4 tetrahedra, octahedrally coordinated cations can be insular, corner-sharing, or edge sharing w/o add’l anions with H2O with medium-sized cations; diff from coquimbite do to stacking sequence along [001].1 Main features are: (1) polyhedral clusters of 3 Fe octahedra & 6 S tetrahedra, (2) isolated Fe octahedra, & (3) 6 H2O molecules forming very distorted octahedra which contain no cations; 3 structural units are interconnected by H-bonds only; structure can be descibed as 6-layer stack with repeat distance of 8.5 Å along c axis; each individual layer within stack contains all 3 of main structural features described above.2 There are 5 non-equivalent octahedrally coordinated metal sites for Fe in structure; range of Fe[6]—O interatomic distances (1.966—2.016 Å) can well be compared with those found in var sulfate minerals of ferric iron.3 Both minerals are typified by complex system of H bonds involving 3 types of H2O molecules, resp: those of [Fe3(SO4)6(H2O)6]3- clusters of isolated [Fe(H2O)6]3+ or [Al(H2O)6]3+ octahedra & further interstitial (H2O) grp; interstitial H2O molecules resemble cyclohexane-like chair & are held in structure solely by H-bonding; in coquimbite H2OW(2) is disordered with 2 alternative orientations (H2B1 & H2B2), in paracoquimbite interstitial H2O consists of 2 H2O molecules; H2OW(3) & H2OW(4).4This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find PARACOQUIMBITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Small rhombohedral crystals, equant, pseudocubic or prismatic; may be sceptered on coquimbite; massive
  • Twinning: On {0001}, common
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PARACOQUIMBITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Formed in oxidized zone of pyritic hydrothermal orebodies in arid regionsKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. PARACOQUIMBITE is often related to other species, either through similar chemistry or structure.Relationship Data: Dimorphous with coquimbite; homeotypic structuresUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of PARACOQUIMBITE?The standard chemical formula for PARACOQUIMBITE is Fe3+4(SO4)6(H2O)12·6H2O. This defines its elemental composition.
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2. Which crystal system does PARACOQUIMBITE belong to?PARACOQUIMBITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal rhombohedral class.3. How is PARACOQUIMBITE typically found in nature?The “habit” or typical appearance of PARACOQUIMBITE is described as Small rhombohedral crystals, equant, pseudocubic or prismatic; may be sceptered on coquimbite; massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does PARACOQUIMBITE form?PARACOQUIMBITE is typically found in environments described as: Formed in oxidized zone of pyritic hydrothermal orebodies in arid regions. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to PARACOQUIMBITE?Yes, it is often associated with or related to other minerals such as: Dimorphous with coquimbite; homeotypic structures.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of PARACOQUIMBITE, we recommend checking high-authority databases:

Final Thoughts

PARACOQUIMBITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Fe3+4(SO4)6(H2O)12·6H2O and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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