PERHAMITE Mineral Details

Complete mineralogical data for PERHAMITE. Chemical Formula: Ca3Al7(PO4)4[SiO4]3(OH)3(H2O)8. Crystal System: Hexagonal-Trigonal. Learn about its geologic occurrence, habit, and identification.

PERHAMITE

Ca3Al7(PO4)4[SiO4]3(OH)3(H2O)8

Crystal System

Hexagonal-Trigonal

Crystal Class

Trigonal scalenohedral

Space Group

P3m1

Point Group

3 2/m

Structure & Data

Crystal Structure

Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with CO3, SO4, SiO4.1 Comprises ordered blocks of crandallite-type structure, centered at z = 0, intergrown || to (001) with disordered alumino-silicate structure blocks centered at z = ½ to form microporous structure containing large channels along [100]; channels bounded by 8-member rings of 6 tetrahedra (2 SiO4, 2 AlO4 & 2 PO4) & 2 AlO6 octahedra; Ca atoms & H2O molecules distributed in [100] channels; dominant contributors to local order are Si3O9 rings of corner-shared tetrahedra with Si2O pairs of tetrahedra; these units corner-link to (Al,Si)O4 tetrahedra above & below plane at z = ½ to form 4-member rings, which corner-share to PO4 tetrahedra in crandallite blocks to give 8-member rings.2

Cell Data

a=7.02Å, c=20.21Å, Z=1/2

Geology & Identification

Geologic Occurrence

Secondary post-mine mineral in limestone-hosted oxidized Pb-Zn oresPERHAMITEPERHAMITE

Habit

Submicro crystals are thin tabular blades elongate, aggregated in rosettes

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Compare crandallite

If you are fascinated by the hidden structures of our planet, you have likely come across PERHAMITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about PERHAMITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, PERHAMITE is defined by the chemical formula Ca3Al7(PO4)4[SiO4]3(OH)3(H2O)8.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. PERHAMITE crystallizes in the Hexagonal-Trigonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Trigonal scalenohedral.
  • Point Group: 3 2/m
  • Space Group: P3m1
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
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Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For PERHAMITE, the dimensions of this microscopic building block are:
a=7.02Å, c=20.21Å, Z=1/2
The internal arrangement of these atoms is described as:Phosphates, arsenates, vanadates: anions [PO4]3-, [AsO4]3-, [VO4]3- are usually insular; cations may be small with [4] coordination, medium-sized with [6] coordination, or large with [8] or higher coordination; medium-sized cations with octahedral [6] coordination may be insular, corner-, edge- or face-sharing & form major structural units with add’l anions with H2O with CO3, SO4, SiO4.1 Comprises ordered blocks of crandallite-type structure, centered at z = 0, intergrown || to (001) with disordered alumino-silicate structure blocks centered at z = ½ to form microporous structure containing large channels along [100]; channels bounded by 8-member rings of 6 tetrahedra (2 SiO4, 2 AlO4 & 2 PO4) & 2 AlO6 octahedra; Ca atoms & H2O molecules distributed in [100] channels; dominant contributors to local order are Si3O9 rings of corner-shared tetrahedra with Si2O pairs of tetrahedra; these units corner-link to (Al,Si)O4 tetrahedra above & below plane at z = ½ to form 4-member rings, which corner-share to PO4 tetrahedra in crandallite blocks to give 8-member rings.2This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.

Physical Appearance (Habit)

When you find PERHAMITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Submicro crystals are thin tabular blades elongate, aggregated in rosettes
  • Twinning: 
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Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PERHAMITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Secondary post-mine mineral in limestone-hosted oxidized Pb-Zn oresKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. PERHAMITE is often related to other species, either through similar chemistry or structure.Relationship Data: Compare crandalliteUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of PERHAMITE?The standard chemical formula for PERHAMITE is Ca3Al7(PO4)4[SiO4]3(OH)3(H2O)8. This defines its elemental composition.2. Which crystal system does PERHAMITE belong to?PERHAMITE crystallizes in the Hexagonal-Trigonal system. Its internal symmetry is further classified under the Trigonal scalenohedral class.
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3. How is PERHAMITE typically found in nature?The “habit” or typical appearance of PERHAMITE is described as Submicro crystals are thin tabular blades elongate, aggregated in rosettes. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does PERHAMITE form?PERHAMITE is typically found in environments described as: Secondary post-mine mineral in limestone-hosted oxidized Pb-Zn ores. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to PERHAMITE?Yes, it is often associated with or related to other minerals such as: Compare crandallite.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of PERHAMITE, we recommend checking high-authority databases:

Final Thoughts

PERHAMITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca3Al7(PO4)4[SiO4]3(OH)3(H2O)8 and a structure defined by the Hexagonal-Trigonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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