PERLIALITE Mineral Details

Complete mineralogical data for PERLIALITE. Chemical Formula: K9NaCa[Si24Al12O72]·15H2O. Crystal System: Hexagonal. Learn about its geologic occurrence, habit, and identification.

PERLIALITE

K9NaCa[Si24Al12O72]·15H2O

Crystal System

Hexagonal

Crystal Class

Dihexagonal dipyramidal

Space Group

P6/mmm

Point Group

6/m 2/m 2/m

Structure & Data

Crystal Structure

Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O; with 14-sided cages of 2 6-membered rings, 3 8-membered rings & 12 4-membered rings, called “gmelinite-type” cages; cages occupied by Na, Ca & H2O.2 Framework topology (Artioli & Kvick (1990)) is same as synthetic Linde Type L (LTL) as determined by Barrer & Villiger (1969); 2 types of channels run || to c-axis; 1 is bounded by 12-membered rings of ltl cages, & other is bounded by strongly compressed 8-membered rings; T-O distances give no indication of (Si,Al) order; when comparing structural diagrams for mazzite & perlialite projected to c-axis, strong similarities are evident; in perlialite 6-membered double-rings connect sheets, whereas single rings occur in mazzite; in perlialite 6-membered rings (double 6-rings) connect 2 cancrinite-type cages (LTL) & in mazzite 6-membered rings connect 2 gmelinite cages.3 Cations in large channels bonded to 6 framework O of 8-membered rings & add’l H2O molecules which fill interior of 12-membered ring; notice diff array of cations & H2O in wide channels compared with mazzite; 2nd most preferred non-framework site (fully occupied) is in compressed 8-membered rings forming channels || to c-axis.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra framework positions; perlialite has same framework topology as synthetic zeolite—I; structural columns have alternating cancrinite-type cages & double 6-membered rings; no Si,Al order has been detected.5

Cell Data

a=18.49Å, c=7.51Å, Z=1

Geology & Identification

Geologic Occurrence

In nepheline-feldspar, sodalite-microcline pegmatites in differentiated alkalic massifPERLIALITEPERLIALITE

Habit

Acicular macro crystals; in fibrous aggregates, radiating

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Zeolite family

If you are fascinated by the hidden structures of our planet, you have likely come across PERLIALITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about PERLIALITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, PERLIALITE is defined by the chemical formula K9NaCa[Si24Al12O72]·15H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. PERLIALITE crystallizes in the Hexagonal system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Dihexagonal dipyramidal.
  • Point Group: 6/m 2/m 2/m
  • Space Group: P6/mmm
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For PERLIALITE, the dimensions of this microscopic building block are:
a=18.49Å, c=7.51Å, Z=1
The internal arrangement of these atoms is described as:
READ ALSO  CHATKALITE Mineral Details
Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O; with 14-sided cages of 2 6-membered rings, 3 8-membered rings & 12 4-membered rings, called “gmelinite-type” cages; cages occupied by Na, Ca & H2O.2 Framework topology (Artioli & Kvick (1990)) is same as synthetic Linde Type L (LTL) as determined by Barrer & Villiger (1969); 2 types of channels run || to c-axis; 1 is bounded by 12-membered rings of ltl cages, & other is bounded by strongly compressed 8-membered rings; T-O distances give no indication of (Si,Al) order; when comparing structural diagrams for mazzite & perlialite projected to c-axis, strong similarities are evident; in perlialite 6-membered double-rings connect sheets, whereas single rings occur in mazzite; in perlialite 6-membered rings (double 6-rings) connect 2 cancrinite-type cages (LTL) & in mazzite 6-membered rings connect 2 gmelinite cages.3 Cations in large channels bonded to 6 framework O of 8-membered rings & add’l H2O molecules which fill interior of 12-membered ring; notice diff array of cations & H2O in wide channels compared with mazzite; 2nd most preferred non-framework site (fully occupied) is in compressed 8-membered rings forming channels || to c-axis.4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra framework positions; perlialite has same framework topology as synthetic zeolite—I; structural columns have alternating cancrinite-type cages & double 6-membered rings; no Si,Al order has been detected.5This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
READ ALSO  Lechatelierite Mineral Details

Physical Appearance (Habit)

When you find PERLIALITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Acicular macro crystals; in fibrous aggregates, radiating
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PERLIALITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In nepheline-feldspar, sodalite-microcline pegmatites in differentiated alkalic massifKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. PERLIALITE is often related to other species, either through similar chemistry or structure.Relationship Data: Zeolite familyUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of PERLIALITE?The standard chemical formula for PERLIALITE is K9NaCa[Si24Al12O72]·15H2O. This defines its elemental composition.
READ ALSO  BUBNOVAITE Mineral Details
2. Which crystal system does PERLIALITE belong to?PERLIALITE crystallizes in the Hexagonal system. Its internal symmetry is further classified under the Dihexagonal dipyramidal class.3. How is PERLIALITE typically found in nature?The “habit” or typical appearance of PERLIALITE is described as Acicular macro crystals; in fibrous aggregates, radiating. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does PERLIALITE form?PERLIALITE is typically found in environments described as: In nepheline-feldspar, sodalite-microcline pegmatites in differentiated alkalic massif. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to PERLIALITE?Yes, it is often associated with or related to other minerals such as: Zeolite family.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of PERLIALITE, we recommend checking high-authority databases:

Final Thoughts

PERLIALITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of K9NaCa[Si24Al12O72]·15H2O and a structure defined by the Hexagonal system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
Scroll to Top