If you are fascinated by the hidden structures of our planet, you have likely come across
PHILLIPSITE-Na. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about
PHILLIPSITE-Na. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.
The Chemistry Behind the Crystal
Every mineral tells a story through its chemistry. At its core,
PHILLIPSITE-Na is defined by the chemical formula
Na6[Si10Al6O32]·12H2O.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.
Crystallography: Geometry in Nature
One of the most beautiful aspects of mineralogy is the hidden geometry within every stone.
PHILLIPSITE-Na crystallizes in the
Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the
Prismatic.
- Point Group: 2/m
- Space Group: P21/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.
Internal Structure and Unit Cell
If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For
PHILLIPSITE-Na, the dimensions of this microscopic building block are:
a=9.95Å, b=14.1Å, c=8.66Å, ß=124.8o, Z=2
The internal arrangement of these atoms is described as:
Tektosilicates: tetrahedra are linked into 3-D framework with zeolitic H2O with chains of doubly-connected layers of 4- & 8-membered rings // (100) ± linked vertically by 4-membered rings, forming intersecting channels // [100] & [010].2 Ca-free, 2-level rings; latter are not hexagonal but octagonal ones (Al,Si)16O40, which are linked together along a axis.3 Basic bldg unit of phillpsite framework is chain of doubly connected 4-rings, linking in UUDD order, gen known as double crankshaft (dcc in PHI); true s.g. of phillipsite series (& isostructural harmotome) is still under debate; recent X-ray & neutron single-xl structure refinements btw 15 & 293 K confirm centric s.g. P21/m harmotome (Stuckenschmidt et al (1990)) proposed by Rinaldi et al (1974); there are hints of acentricity (s.g. P21 or P1), indicated by piezo-electricity (Sadanga et al (1961)) & optical domains (Akizuki (1985)).4 Zeolites are alumino-silicate frameworks with usually loosely bonded alkali or alkali-earth cations, or both; molecules of H2O occupy extra-framework positions; phillipsite series incl K, Na, Ca, or Ba may be most abundant extra-framework cation, but name harmotome is retained for Ba-dominant member of series; 2 cation sites have been identified, one, with 2 atoms / formula unit fully occupied by K in phillipsite-K & by Ba in harmotome, is surrounded by 8 framework atoms of O & 4 molecules of H2O; other is partly occupied by Ca & Na in disorted octahedral coordination with 2 famework atoms of O & 4 molecules of H2O; framework Si,Al largely disordered; phillipsite-Ca has Ca as most abundant extra-framework cation.6 See “Additional Structures” tab for entry(s).5,7a,7b,8This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
Physical Appearance (Habit)
When you find
PHILLIPSITE-Na in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
- Common Habit: Bipyramidal macro crystals; in stellate or radiating spherulitic aggregates; powdery
- Twinning:
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PHILLIPSITE-Na exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.
Where is it Found? (Geologic Occurrence)
Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.
Geologic Occurrence:
In cavities in nepheline and olivine basalt and leucite tephriteKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the
U.S. Geological Survey (USGS) provide excellent maps and data.
Related Minerals
No mineral exists in a vacuum.
PHILLIPSITE-Na is often related to other species, either through similar chemistry or structure.
Relationship Data:
Zeolite family, phillipsite subgroup; forms series with phillipsite-Ca; forms series with phillipsite-KUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
Frequently Asked Questions (FAQs)
1. What is the chemical formula of PHILLIPSITE-Na?The standard chemical formula for PHILLIPSITE-Na is
Na6[Si10Al6O32]·12H2O. This defines its elemental composition.
2. Which crystal system does PHILLIPSITE-Na belong to?PHILLIPSITE-Na crystallizes in the
Monoclinic system. Its internal symmetry is further classified under the Prismatic class.
3. How is PHILLIPSITE-Na typically found in nature?The “habit” or typical appearance of PHILLIPSITE-Na is described as
Bipyramidal macro crystals; in stellate or radiating spherulitic aggregates; powdery. This refers to the shape the crystals take when they grow without obstruction.
4. In what geological environments does PHILLIPSITE-Na form?PHILLIPSITE-Na is typically found in environments described as:
In cavities in nepheline and olivine basalt and leucite tephrite. This gives clues to the geological history of the area where it is discovered.
5. Are there other minerals related to PHILLIPSITE-Na?Yes, it is often associated with or related to other minerals such as:
Zeolite family, phillipsite subgroup; forms series with phillipsite-Ca; forms series with phillipsite-K.
External Resources for Further Study
For those looking to dive deeper into the specific mineralogical data of
PHILLIPSITE-Na, we recommend checking high-authority databases:
Final Thoughts
PHILLIPSITE-Na is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of
Na6[Si10Al6O32]·12H2O and a structure defined by the
Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
