PIEMONTITE Mineral Details

Complete mineralogical data for PIEMONTITE. Chemical Formula: Ca2(Al2Mn3+)[Si2O7][SiO4]O(OH). Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

PIEMONTITE

Ca2(Al2Mn3+)[Si2O7][SiO4]O(OH)

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

P21/m

Point Group

2/m

Structure & Data

Crystal Structure

Sorosilicates: SiO4 tetrahedras combined mainly in pairs, also in larger combos which form isolated grp with mixed SiO4 & Si2O7 grp, cations in octahedral [6] & greater coordination; edge-sharing Al[6] octahedra form linear chains // [010] linked into sheets // (100) by insular SiO4 tetrahedra & Si2O7 grp; sheets weakly bonded prp to (100) by Fe[6] & Ca[8].2 Similar to zoisite except Ca has CN of 6 & 9, so ½ of Ca can be repl isomorphously by Ce & other REE; these atoms lie at center of cell at 2 levels; Al octahedra form 2 types of column along b axis, while single Al octahedra of zoisite are repl by Fe3+ octahedra; Ce isomorphism is accompanied by compensating Fe3+—> Fe2+.3 For xl composition Cz65Pm24 Ps11 (resp ideal end member compositions commonly given mnemonics, Strens, 1964), refinement of occupancies of 2 large, nominally Ca sites & 3 non-equivalent sites, gives (Ca1.00)(Ca0.87Sr0.13)(Al0.80M0.20) (Al1.00) (Al0.17M0.83) Si3O12OH, where M = Mn0.7 Fe0.3; all of (Mn,Fe) substitution for Al occurs in 1 of 2 non-equivalent chains of edge-sharing octahedra; in substituted chain, which is topologically identical with that found in olivine structure, larger M(3) site (symmetry-m) lying on edge of chain, contains most of (Mn,Fe) with lesser amt in smaller M(1) site (symmetry-1) which forms core of chain.4 See “Additional Structures” tab for entry(s).7

Cell Data

a=8.89Å, b=5.68Å, c=10.20Å, ß=115.2o, Z=2

Geology & Identification

Geologic Occurrence

In metamorphosed rocks, felsic igneous rocks; in contact zones of igneous and calc sedimentaries; from alteration of plagioclasePIEMONTITEPIEMONTITE

Habit

Prismatic, elongated, striated macro crystals; fibrous, coarse to fine granular massive

Twinning

On {100}, contact, lamellar, common

Relationships

RELATIONSHIP TO OTHER MINERALS

Epidote group, clinozoisite subgroup; analog of piemontite-(Sr)

If you are fascinated by the hidden structures of our planet, you have likely come across PIEMONTITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about PIEMONTITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, PIEMONTITE is defined by the chemical formula Ca2(Al2Mn3+)[Si2O7][SiO4]O(OH).This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. PIEMONTITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: P21/m
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For PIEMONTITE, the dimensions of this microscopic building block are:
a=8.89Å, b=5.68Å, c=10.20Å, ß=115.2o, Z=2
The internal arrangement of these atoms is described as:
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Sorosilicates: SiO4 tetrahedras combined mainly in pairs, also in larger combos which form isolated grp with mixed SiO4 & Si2O7 grp, cations in octahedral [6] & greater coordination; edge-sharing Al[6] octahedra form linear chains // [010] linked into sheets // (100) by insular SiO4 tetrahedra & Si2O7 grp; sheets weakly bonded prp to (100) by Fe[6] & Ca[8].2 Similar to zoisite except Ca has CN of 6 & 9, so ½ of Ca can be repl isomorphously by Ce & other REE; these atoms lie at center of cell at 2 levels; Al octahedra form 2 types of column along b axis, while single Al octahedra of zoisite are repl by Fe3+ octahedra; Ce isomorphism is accompanied by compensating Fe3+—> Fe2+.3 For xl composition Cz65Pm24 Ps11 (resp ideal end member compositions commonly given mnemonics, Strens, 1964), refinement of occupancies of 2 large, nominally Ca sites & 3 non-equivalent sites, gives (Ca1.00)(Ca0.87Sr0.13)(Al0.80M0.20) (Al1.00) (Al0.17M0.83) Si3O12OH, where M = Mn0.7 Fe0.3; all of (Mn,Fe) substitution for Al occurs in 1 of 2 non-equivalent chains of edge-sharing octahedra; in substituted chain, which is topologically identical with that found in olivine structure, larger M(3) site (symmetry-m) lying on edge of chain, contains most of (Mn,Fe) with lesser amt in smaller M(1) site (symmetry-1) which forms core of chain.4 See “Additional Structures” tab for entry(s).7This internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find PIEMONTITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Prismatic, elongated, striated macro crystals; fibrous, coarse to fine granular massive
  • Twinning: On {100}, contact, lamellar, common
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PIEMONTITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: In metamorphosed rocks, felsic igneous rocks; in contact zones of igneous and calc sedimentaries; from alteration of plagioclaseKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. PIEMONTITE is often related to other species, either through similar chemistry or structure.Relationship Data: Epidote group, clinozoisite subgroup; analog of piemontite-(Sr)Understanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.

Frequently Asked Questions (FAQs)

1. What is the chemical formula of PIEMONTITE?The standard chemical formula for PIEMONTITE is Ca2(Al2Mn3+)[Si2O7][SiO4]O(OH). This defines its elemental composition.
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2. Which crystal system does PIEMONTITE belong to?PIEMONTITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is PIEMONTITE typically found in nature?The “habit” or typical appearance of PIEMONTITE is described as Prismatic, elongated, striated macro crystals; fibrous, coarse to fine granular massive. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does PIEMONTITE form?PIEMONTITE is typically found in environments described as: In metamorphosed rocks, felsic igneous rocks; in contact zones of igneous and calc sedimentaries; from alteration of plagioclase. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to PIEMONTITE?Yes, it is often associated with or related to other minerals such as: Epidote group, clinozoisite subgroup; analog of piemontite-(Sr).

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of PIEMONTITE, we recommend checking high-authority databases:

Final Thoughts

PIEMONTITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Ca2(Al2Mn3+)[Si2O7][SiO4]O(OH) and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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