PLAGIONITE Mineral Details

Complete mineralogical data for PLAGIONITE. Chemical Formula: Pb5Sb8S17. Crystal System: Monoclinic. Learn about its geologic occurrence, habit, and identification.

PLAGIONITE

Pb5Sb8S17

Crystal System

Monoclinic

Crystal Class

Prismatic

Space Group

C2/c

Point Group

2/m

Structure & Data

Crystal Structure

Pb sulfosalts based on large 2-D fragments of PbS/SnS archetype.1 Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; this can be attributed to lone-elctron-pair effect of metalloid ions; SnS archetype, deformed (As,Sb,Bi)S6 octahedra with distinct (As,Sb,Bi)S3 ∆; slabs // (102) linked by Pb[8] & Pb[7]; a & b remain = ±, c increases from 16.93 to 24.49 Å.2 Cell parameters of heteromorphite are correlated with precise composition [1199].3 Asymmetric unit contains 16 atoms; 2 Pb atoms are coordinated by 6 & 7 S atoms, resp, in octahedral-like configuration; 1/3 Pb atom has irregular [8]-coordination which may be described either as □ antiprism, or as trig prism with neighbors along 2 face normals; 3 of 4 independent Sb atoms have □∆ coordination; 4th forms trig ∆ grp; of 9 independent S atoms, 4 have □∆ coordination, 3 have distorted tetrahedral coordination & 2 have [3]-coordination; structure is composed of slabs of PbS-like structures which are repeated by b; stacks of such slabs exist || to (112) & (112) alternately along c & extend indefinitely along [110] & [110] resp; it is postulated that structures of other members in homologous series contain similar slabs which diff in width of PbS-like unit.4 Consist of halite-like structure, 2 atoms in thickness, which were oriented || to (112) & (112) alternately along c; layers extended indefinitely along [110] & [110], resp, in directions corresponding to [310] in halite structure; asymmetric units in these minerals were linear chains of metal-S pairs lying (112) & extending along [110] of halite-like array; it seems probable that structures of successive members of plagionite grp diff only in addition of 1 Pb & 1 S atom to linear asymmetric unit which, in order to acct for common {112} cleavage, must be constrained to lie in (112); successive members would thus diff in width of halite slab.5a See “Additional Structures” tab for entry(s).5b

Cell Data

a=13.49Å, b=11.87Å, c=19.98Å, ß=107.2o, Z=4

Geology & Identification

Geologic Occurrence

Of hydrothermal originPLAGIONITEPLAGIONITE

Habit

Crystals short prismatic and pyramidal, striated; curved crystals common

Twinning

Relationships

RELATIONSHIP TO OTHER MINERALS

Plagionite group

If you are fascinated by the hidden structures of our planet, you have likely come across PLAGIONITE. This mineral is a compelling subject for study, offering a unique glimpse into the complex chemistry that shapes the Earth’s crust.Whether you are a student identifying a hand sample, a researcher looking for crystallographic data, or a collector curious about a new find, this guide breaks down everything you need to know about PLAGIONITE. From its precise chemical formula to the geological environments where it thrives, let’s explore what makes this mineral distinct.

The Chemistry Behind the Crystal

Every mineral tells a story through its chemistry. At its core, PLAGIONITE is defined by the chemical formula Pb5Sb8S17.This isn’t just a string of letters and numbers; it represents the precise recipe of elements that nature used to build this specimen. This specific chemical composition is what gives the mineral its stability and dictates how it reacts with acids, heat, or other minerals. It is the fundamental “DNA” that geologists use to classify it within the larger mineral kingdom.

Crystallography: Geometry in Nature

One of the most beautiful aspects of mineralogy is the hidden geometry within every stone. PLAGIONITE crystallizes in the Monoclinic system.Think of this as the mineral’s architectural blueprint. It dictates the symmetry and the angles at which the crystal faces grow. Digging deeper into its symmetry, it falls under the Prismatic.
  • Point Group: 2/m
  • Space Group: C2/c
Why does this matter? These crystallographic details are like a fingerprint. They influence optical properties—how light travels through the crystal—and physical traits like how it breaks or cleaves when struck.

Internal Structure and Unit Cell

If we could zoom in to the atomic level, we would see the “Unit Cell”—the smallest repeating box of atoms that builds up the entire crystal. For PLAGIONITE, the dimensions of this microscopic building block are:
a=13.49Å, b=11.87Å, c=19.98Å, ß=107.2o, Z=4
The internal arrangement of these atoms is described as:
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Pb sulfosalts based on large 2-D fragments of PbS/SnS archetype.1 Typified by presence of trig ∆ of As, Sb, Bi that represent FBB in structure with 3 S atoms forming base of ∆, & metalloids As, Sb, Bi at apex; this can be attributed to lone-elctron-pair effect of metalloid ions; SnS archetype, deformed (As,Sb,Bi)S6 octahedra with distinct (As,Sb,Bi)S3 ∆; slabs // (102) linked by Pb[8] & Pb[7]; a & b remain = ±, c increases from 16.93 to 24.49 Å.2 Cell parameters of heteromorphite are correlated with precise composition [1199].3 Asymmetric unit contains 16 atoms; 2 Pb atoms are coordinated by 6 & 7 S atoms, resp, in octahedral-like configuration; 1/3 Pb atom has irregular [8]-coordination which may be described either as □ antiprism, or as trig prism with neighbors along 2 face normals; 3 of 4 independent Sb atoms have □∆ coordination; 4th forms trig ∆ grp; of 9 independent S atoms, 4 have □∆ coordination, 3 have distorted tetrahedral coordination & 2 have [3]-coordination; structure is composed of slabs of PbS-like structures which are repeated by b; stacks of such slabs exist || to (112) & (112) alternately along c & extend indefinitely along [110] & [110] resp; it is postulated that structures of other members in homologous series contain similar slabs which diff in width of PbS-like unit.4 Consist of halite-like structure, 2 atoms in thickness, which were oriented || to (112) & (112) alternately along c; layers extended indefinitely along [110] & [110], resp, in directions corresponding to [310] in halite structure; asymmetric units in these minerals were linear chains of metal-S pairs lying (112) & extending along [110] of halite-like array; it seems probable that structures of successive members of plagionite grp diff only in addition of 1 Pb & 1 S atom to linear asymmetric unit which, in order to acct for common {112} cleavage, must be constrained to lie in (112); successive members would thus diff in width of halite slab.5a See “Additional Structures” tab for entry(s).5bThis internal structure is the invisible framework that supports everything we see on the outside, from the mineral’s density to its hardness.
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Physical Appearance (Habit)

When you find PLAGIONITE in the field, what does it actually look like? A mineral’s “habit” describes its typical shape and growth pattern.
  • Common Habit: Crystals short prismatic and pyramidal, striated; curved crystals common
  • Twinning: 
Twinning is a fascinating phenomenon where two or more crystals grow interlocked in a specific symmetrical pattern. If PLAGIONITE exhibits twinning, it can be a dead giveaway for identification, distinguishing it from look-alike minerals.

Where is it Found? (Geologic Occurrence)

Minerals are the products of their environment. They don’t just appear anywhere; they need specific conditions—pressure, temperature, and chemical ingredients—to form.Geologic Occurrence: Of hydrothermal originKnowing this context helps geologists reconstruct the history of a rock formation. It tells us whether the rock was born from cooling magma, settled in an ancient ocean, or was transformed by the intense heat and pressure of metamorphism. For more broad geological context, resources like the U.S. Geological Survey (USGS) provide excellent maps and data.

Related Minerals

No mineral exists in a vacuum. PLAGIONITE is often related to other species, either through similar chemistry or structure.Relationship Data: Plagionite groupUnderstanding these relationships is key. It helps us see the “family tree” of the mineral world, showing how different elements can substitute for one another to create an entirely new species with similar properties.
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Frequently Asked Questions (FAQs)

1. What is the chemical formula of PLAGIONITE?The standard chemical formula for PLAGIONITE is Pb5Sb8S17. This defines its elemental composition.2. Which crystal system does PLAGIONITE belong to?PLAGIONITE crystallizes in the Monoclinic system. Its internal symmetry is further classified under the Prismatic class.3. How is PLAGIONITE typically found in nature?The “habit” or typical appearance of PLAGIONITE is described as Crystals short prismatic and pyramidal, striated; curved crystals common. This refers to the shape the crystals take when they grow without obstruction.4. In what geological environments does PLAGIONITE form?PLAGIONITE is typically found in environments described as: Of hydrothermal origin. This gives clues to the geological history of the area where it is discovered.5. Are there other minerals related to PLAGIONITE?Yes, it is often associated with or related to other minerals such as: Plagionite group.

External Resources for Further Study

For those looking to dive deeper into the specific mineralogical data of PLAGIONITE, we recommend checking high-authority databases:

Final Thoughts

PLAGIONITE is more than just a name on a list; it is a testament to the orderly and beautiful laws of nature. With a chemical backbone of Pb5Sb8S17 and a structure defined by the Monoclinic system, it holds a specific and important place in the study of mineralogy.We hope this overview has helped clarify the essential data points for this specimen. Whether for academic study or personal interest, understanding these properties brings us one step closer to understanding the Earth itself.
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